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91.
92.
本项目以哈尔滨啤酒(沈阳)有限公司啤酒厂为设计对象,其啤酒废水处理规模为1500m3/d,进水CODCr2000~2800mg/L。采用预处理-预酸化-IC反应器-活性污泥法-过滤为主体工艺,出水达到《辽宁省污水与废气排放标准》(DB21-60-89中一级标准)。为啤酒行业废水综合治理提供了较好的工艺途径。 相似文献
93.
总量控制是控制污染源发展趋势、改善环境质量、实现经济社会可持续发展的重要途径,如何在适度公平的基础上寻求环境、经济、技术、资源等整体最优是环境科学领域的研究课题。本文以工业城市苏州市为例,研究其工业化学需氧量的排放特征,以基尼系数法分行业对其工业化学需氧量排放量的公平性进行评价,并将总量控制与资源、社会和经济相联系,以行业经济效益最大化和增加治理投资费用最小化为目标,利用多目标行业总量优化分配模型对苏州市的工业化学需氧量排放总量进行优化分配。研究结果表明,纺织业、化学原料及化学制品制造业、能源和水的生产与供应业、造纸及木材加工、医药制造业等行业是苏州市的化学需氧量重点排放行业,经优化分配后,COD排放总量削减了10%,新鲜用水量减少了41.81%,行业年总产值增幅达到214.69%,资源和水环境容量在满足一定的经济增长速度的条件下实现优化配置,总量控制制度在市场经济体制下发挥出尽可能大的环境效益和经济效益。 相似文献
94.
Few studies have evaluated how effectively environmental contamination may reduce genetic diversity of a population. Here, we chose a laboratory approach in order to test if tributyltin (TBT) exposure at environmentally relevant concentrations leads to reduced genetic variation in the midge Chironomus riparius. Two TBT-exposed and two unexposed experimental populations were reared simultaneously in the laboratory for 12 generations. We recorded several life-history traits in each generation and monitored genetic variation over time using five variable microsatellite markers. TBT-exposed strains showed increased larval mortality (treatments: 43.8%; controls: 27.8%), slightly reduced reproductive output, and delayed larval development. Reduction of genetic variation was strongest and only significant in the TBT-exposed strains (treatments: −45.9%, controls: −24.4% of initial heterozygosity) after 12 generations. Our findings document that chemical pollution may lead to a rapid decrease in genetic diversity, which has important implications for conservation strategies and ecological management in polluted environments. 相似文献
95.
Washing aggregate sludge from a gravel pit, sewage sludge from a wastewater treatment plant (WWTP) and a clay-rich sediment have been physically, chemically and mineralogically characterized. They were mixed, milled and formed into pellets, pre-heated for 5 min and sintered in a rotary kiln at 1150 °C, 1175 °C, 1200 °C and 1225 °C for 10 and 15 min at each temperature. The effects of the raw material characteristics, heating temperatures and dwell times on the loss on ignition (LOI), bloating index (BI), bulk density (ρb), apparent and dry particle densities (ρa, ρd), voids (H), water absorption (WA24h) and compressive strength (S) were determined. All the mixtures presented a bloating potential taking into consideration the gases released at high temperatures. The products obtained were lightweight aggregates (LWAs) in accordance with Standard UNE-EN-13055-1 (ρb ≤ 1.20 g/cm3 or particle density ≤ 2.00 g/cm3). LWAs manufactured with 50% washing aggregate sludge and 50% clay-rich sediment were expanded LWAs (BI > 0) and showed the lowest apparent particle density, the lowest water absorption and the highest compressive strength. It was possible to establish three groups of LWAs on the basis of their properties in comparison to Arlita G3, F3 and F5, commercially available lightweight aggregates manufactured in Spain. Our LWAs may have the same or similar applications as these commercial products, such as horticulture, prefabricated lightweight structures and building structures. 相似文献
96.
The hydrolysis/precipitation behaviors of Al3+, Al13 and Al30 under conditions typical for flocculation in water treatment were investigated by studying the particulates' size development, charge characteristics, chemical species and speciation transformation of coagulant hydrolysis precipitates. The optimal pH conditions for hydrolysis precipitates formation for AlCl3, PACAl13 and PACAl30 were 6.5–7.5, 8.5–9.5, and 7.5–9.5, respectively. The precipitates' formation rate increased with the increase in dosage, and the relative rates were AlCl3 ? PACAl30 > PACAl13. The precipitates' size increased when the dosage increased from 50 μM to 200 μM, but it decreased when the dosage increased to 800 μM. The Zeta potential of coagulant hydrolysis precipitates decreased with the increase in pH for the three coagulants. The iso-electric points of the freshly formed precipitates for AlCl3, PACAl13 and PACAl30 were 7.3, 9.6 and 9.2, respectively. The Zeta potentials of AlCl3 hydrolysis precipitates were lower than those of PACAl13 and PACAl30 when pH > 5.0. The Zeta potential of PACAl30 hydrolysis precipitates was higher than that of PACAl13 at the acidic side, but lower at the alkaline side. The dosage had no obvious effect on the Zeta potential of hydrolysis precipitates under fixed pH conditions. The increase in Zeta potential with the increase in dosage under uncontrolled pH conditions was due to the pH depression caused by coagulant addition. Al–Ferron research indicated that the hydrolysis precipitates of AlCl3 were composed of amorphous Al(OH)3 precipitates, but those of PACAl13 and PACAl30 were composed of aggregates of Al13 and Al30, respectively. Al3+ was the most un-stable species in coagulants, and its hydrolysis was remarkably influenced by solution pH. Al13 and Al30 species were very stable, and solution pH and aging had little effect on the chemical species of their hydrolysis products. The research method involving coagulant hydrolysis precipitates based on Al–Ferron reaction kinetics was studied in detail. The Al species classification based on complex reaction kinetic of hydrolysis precipitates and Ferron reagent was different from that measured in a conventional coagulant assay using the Al–Ferron method. The chemical composition of Ala, Alb and Alc depended on coagulant and solution pH. The Alb measured in the current case was different from Keggin Al13, and the high Alb content in the AlCl3 hydrolysis precipitates could not used as testimony that most of the Al3+ was converted to highly charged Al13 species during AlCl3 coagulation. 相似文献
97.
Thomas Schwartz Christina Jungfer Stefan Heißler Frank Friedrich Werner Faubel Ursula Obst 《Chemosphere》2009,77(2):249-257
DNA-based population analysis was applied in combination with Raman spectrometry and Environmental Scanning Electron Microscopy for the characterisation of natural biofilms from sand and activated carbon filters operated for a long term at a municipal waterworks. Whereas the molecular biology polymerase chain reaction combined with denaturing gradient gel electrophoresis approach provides a deeper insight into the bacterial biofilm diversities, Raman spectrometry analyses the chemical composition of the extracellular polymer substances (EPS), microorganisms embedded in EPS as well as other substances inside biofilm (inorganic compounds and humic substances). Microscopy images the spatial distribution of biofilms on the two different filter materials. In addition, bacterial bulk water populations were compared with biofilm consortia using the molecular fingerprint technique mentioned.Population analysis demonstrated the presence of more diverse bacterial species embedded in a matrix of EPS (polysaccharides, peptides, and nucleic acids) on the sand filter materials. In contrast to this, activated carbon granules were colonised by reduced numbers of bacterial species in biofilms. Besides α-, β-, and γ-Proteobacteria, a noticeable specific colonisation with Actinobacteria was found on activated carbon particles. Here, the reduced biofilm formation came along with a decreased EPS synthesis. The taxonomy profiles of the different biofilms revealed up to 60% similarity on the same filter materials and 32% similarity of different materials. Similarity of adherent communities from filter materials and bulk water populations from the filter effluent varied between 36% and 58% in sand filters and 6–40% in granular activated carbon filters.The biofilm investigation protocols are most crucial to subsequent acquisition of knowledge on biofilm dynamics and bacterial contributions to transformation or adsorption processes in waterworks facilities. 相似文献
98.
Jussi Kosonen Leif Kronberg 《Environmental science and pollution research international》2009,16(5):555-564
Background, aim and scope Each year, large quantities of pharmaceuticals are consumed worldwide for the treatment and prevention of human and animal
diseases. Although the drugs and the metabolites observed in the wastewaters and in the environment are present at concentrations
several orders of magnitude lower than the concentrations required to exert their effects in humans or animals, their long-term
impact on the environment is commonly not known. In this study, the occurrence of six antihistamines, which are used for the
relief of allergic reactions such as hay fever, was determined in sewage treatment plants wastewaters and in recipient river
waters.
Materials and methods The occurrence of the antihistamines cetirizine, acrivastine, fexofenadine, loratadine, desloratadine and ebastine in sewage
treatment plants wastewaters and in recipient river waters was studied. The analytical procedure consisted of solid-phase
extraction of the water samples followed by liquid chromatography separation and detection by a triple-quadrupole mass spectrometer
in the multiple reaction mode.
Results Cetirizine, acrivastine and fexofenadine were detected in both influent and effluent wastewater samples at concentration levels
ranging from about 80 to 220 ng/L, while loratadine, desloratadine and ebastine could not be detected in any samples. During
sewage treatment, the concentration of the antihistamines dropped by an average of 16–36%. Furthermore, elevated concentrations
of antihistamines were observed in samples collected during the season of most intensive plant pollen production, i.e. in
May. In the river water samples, the relative pattern of occurrence of cetirizine, acrivastine and fexofenadine was similar
to that in the wastewater samples; although the concentration of the compounds was substantially lower (4–11 ng/L). The highest
concentrations of the studied drugs were observed near the discharging point of the sewage treatment plant.
Discussion The highest concentrations of antihistamines in STP wastewaters correlate with the outbreak of allergic reaction caused by
high amounts of plant pollens in the air. The analysis results of the river water samples show that the antihistamines are
carried far away from the effluent discharge points. They may account for a part of the mix of pharmaceuticals and of pharmaceutical
metabolites that occur downstream of STPs.
Conclusions Antihistamines are poorly degraded/eliminated under the biological treatment processes applied in the wastewater treatment
plants and, consequently, they are continuously being discharged along with other drugs to the aquatic environment.
Recommendations and perspectives As a huge quantity and variety of drugs and their metabolites are continuously discharged to rivers and the sea, the compounds
should be considered as contaminants that may possess risks to the aquatic ecosystem. Further studies are urgently needed
on the environmental fate of the antihistamines and other pharmaceuticals in the aquatic environment. These studies should
be concerned with the stability of the compounds, their transformation reactions and the identity of the transformation products,
the distribution of drugs and their uptake and effects in organisms. On the basis of these studies, the possible environmental
hazards of pharmaceuticals may be assessed. 相似文献
99.
Effects of acute γ-irradiation on the aquatic microbial microcosm in comparison with chemicals 总被引:1,自引:1,他引:0
Shoichi Fuma Nobuyoshi Ishii Hiroshi Takeda Kiriko Miyamoto Kei Yanagisawa Kazutaka Doi Isao Kawaguchi Nobuyuki Tanaka Yuhei Inamori Gennady G. Polikarpov 《Journal of environmental radioactivity》2009,100(12):1027-1033
Effects of acute γ-irradiation were investigated in the aquatic microcosm consisting of green algae (Chlorella sp. and Scenedesmus sp.) and a blue–green alga (Tolypothrix sp.) as producers; an oligochaete (Aeolosoma hemprichi), rotifers (Lecane sp. and Philodina sp.) and a ciliate protozoan (Cyclidium glaucoma) as consumers; and more than four species of bacteria as decomposers. At 100 Gy, populations were not affected in any taxa. At 500–5000 Gy, one or three taxa died out and populations of two or three taxa decreased over time, while that of Tolypothrix sp. increased. This Tolypothrix sp. increase was likely an indirect effect due to interspecies interactions. The principal response curve analysis revealed that the main trend of the effects was a dose-dependent population decrease. For a better understanding of radiation risks in aquatic microbial communities, effect doses of γ-rays compared with copper, herbicides and detergents were evaluated using the radiochemoecological conceptual model and the effect index for microcosm. 相似文献
100.
F. Boudrahem F. Aissani-Benissad H. Aït-Amar 《Journal of environmental management》2009,90(10):3031-3039
Lignocellulosic materials are good precursors for the production of activated carbon. In this work, coffee residue has been used as raw material in the preparation of powder activated carbon by the method of chemical activation with zinc chloride for the sorption of Pb(II) from dilute aqueous solutions.The influence of impregnation ratio (ZnCl2/coffee residue) on the physical and chemical properties of the prepared carbons was studied in order to optimize this parameter. The optimum experimental condition for preparing predominantly microporous activated carbons with high pore surface area (890 m2/g) and micropore volume (0.772 cm3/g) is an impregnation ratio of 100%. The developed activated carbon shows substantial capability to sorb lead(II) ions from aqueous solutions and for relative impregnation ratios of 75 and 100%, the maximum uptake is practically the same. Thus, 75% represents the optimal impregnation ratio.Batch experiments were conducted to study the effects of the main parameters such as contact time, initial concentration of Pb(II), solution pH, ionic strength and temperature. The maximum uptake of lead(II) at 25 °C was about 63 mg/g of adsorbent at pH 5.8, initial Pb(II) concentration of 10 mg/L, agitation speed of 200 rpm and ionic strength of 0.005 M. The kinetic data were fitted to the models of pseudo-first order and pseudo-second order, and follow closely the pseudo-second order model. Equilibrium sorption isotherms of Pb(II) were analyzed by the Langmuir, Freundlich and Temkin isotherm models. The Freundlich model gives a better fit than the others.Results from this study suggest that activated carbon produced from coffee residue is an effective adsorbent for the removal of lead from aqueous solutions and that ZnCl2 is a suitable activating agent for the preparation of high-porosity carbons. 相似文献