Cyclohexane oxidation and carbon deposition over metal oxide catalysts

Catalytic activity of V, Mn, Ni, Cu, Zn, Mo, Zr and Ce oxides over an -alumina support was evaluated for cyclohexane oxidation under oxygen deficient conditions in order to understand the relation between carbon deposition and catalytic activity/selectivity. Carbon formation over the catalysts during the oxidation reaction was measured by means of Fourier transformed infrared spectroscopy (FTIR). Catalysts Mn/Al₂O₃ and Ce/Al₂O₃, which are selective for deep oxidation of cyclohexane, possessed relatively carbon free surfaces. The catalysts with relatively high carbon deposition (V, Ni, Cu, Zn, Mo and Zr) produced CO in addition to CO₂. Traces of formaldehyde were produced over the catalysts Mo and V.     

A new environmental chamber for evaluation of gas-phase chemical mechanisms and secondary aerosol formation

A new state-of-the-art indoor environmental chamber facility for the study of atmospheric processes leading to the formation of ozone and secondary organic aerosol (SOA) has been constructed and characterized. The chamber is designed for atmospheric chemical mechanism evaluation at low reactant concentrations under well-controlled environmental conditions. It consists of two collapsible 90 m³ FEP Teflon film reactors on pressure-controlled moveable frameworks inside a temperature-controlled enclosure flushed with purified air. Solar radiation is simulated with either a 200 kW Argon arc lamp or multiple blacklamps. Results of initial characterization experiments, all carried out at 300–305 K under dry conditions, concerning NO_x and formaldehyde offgasing, radical sources, particle loss rates, and background PM formation are described. Results of initial single organic–NO_x and simplified ambient surrogate–NO_x experiments to demonstrate the utility of the facility for mechanism evaluation under low NO_x conditions are summarized and compared with the predictions of the SAPRC-99 chemical mechanism. Overall, the results of the initial characterization and evaluation indicate that this new environmental chamber can provide high quality mechanism evaluation data for experiments with NO_x levels as low as 2 ppb, though the results indicate some problems with the gas-phase mechanism that need further study. Initial evaluation experiments for SOA formation, also carried out under dry conditions, indicate that the chamber can provide high quality secondary aerosol formation data at relatively low hydrocarbon concentrations.     

试论酸雨问题及控制对策

本文论述了酸雨的形成、分布特点、变化规律、危害及控制措施等问题．     

淀山湖湿地及其生态功能与利用

淀山湖是上海市唯一的淡水湖泊，面积约６２ｋｍ２。淀山湖湿地的形成主要是地质、地貌、气候、水文等自然因素和人类活动影响长期相互作用的结果。本文着重讨论了淀山湖湿地的生产功能和环境生态功能，并对湖泊湿地的利用与保护提供了建议。     

扁刺栲-华木荷群系次生林林下物种多样性分析

对四川中亚热带扁刺栲(Castanopsis platyacantha)—华木荷(Schima sinensis)群系人工杉木林、水杉林、日本落叶松林和天然次生林林下植物进行了群落调查和物种多样性分析。结果表明：(1)杉木林、水杉林、日本落叶松林和次生扁刺栲—华木荷林(20a)的物种丰富度分别为62，59，53和32；Simpson多样性指数分别为7．95，7．08，9．24和5．38；Shannon—Wiener多样性指数分别为3．67，3．3l，3．64和2．46。(2)人工林林下植物群落之间的群落系数和相似度系数分别为0．45～0．60和0．62～0．82；人工林林下植物群落与次生阔叶林林下植物群落之间的群落系数和相似度系数分别为0．19～0．53和0．55～0．77。(3)人工林林下物种多样性比次生林高的主要原因可能是风倒木和站干死木导致人工林乔木层郁闭度减小，增加了林下的光照，从而改蛮了林下的微生境。表6参19。     

New particle formation observed from a rain shadow region of the Western Ghats,India

Abstract

This study reports on new particle formation (NPF) and characteristic features observed from a rural site falling in the rainshadow of the Western Ghats in peninsular India. A total of 35 NPF events observed during August 2018 - January 2019 are classified and analyzed here. The apparent formation rates ranged from 0.2 to 10.0?cm^–3 s^–1, while the growth rates of nucleation mode particles ranged from 1.2 to 13.8?nm h^–1. The frequency of occurrence was least during August (core monsoon) and highest during post-monsoon. The local winds were calm and southeasterly to easterly (from the urban centre) supplying the essential precursor gases during October and November, leading to a frequent occurrence of nucleation events. Observations suggest that an increased condensation sink could limit the NPF while promoting Aitken mode growth. The newly formed particles accounted for about 10–80% of the total aerosol concentration. These newly formed particles were able to act as cloud condensation nuclei after growing to approximately 50?nm with an average activation fraction of 0.4.     

赣州高级技工学校滑坡成因分析及稳定性评价

本文从地形地貌、岩性、降水等方面综合分析了赣州高级技工学校滑坡的成因,并通过定量计算,分析了滑坡在天然及饱和状态下的稳定性,提出了滑坡的治理方案。     

天祝县地震监测网点建设及地质构造断层划分的探讨

地震监测网点建设与地质构造断层划分是地震观测和预报技术的一个重要组成部分。必须按照中国地震局地震台网前兆标准和甘肃省地震局台网建设规定，统一布设网点，打破行政区域界线，根据地震活动背景，从地震活动性、灵敏性、密集性，重要性构造差异，人口密度等因素布局设立地震监测网点。地震监测网点布局必须服从地震科研和预报的需要，有目地、有组织、有限度、有预测。本文以天祝县地震监测网点建设为实例，探讨了以上问题。     

内蒙古托克托县地下水水质现状及成因分析

本文在现状调查分析的基础上，通过典型地区的探孔取样资料论述了该地区的水质状况，并就其成因进行了分析，对水质不良地区今后解决人畜饮水提供参考依据。     

基于突变理论的建筑工人不安全行为研究

为有效减少建筑工人的不安全行为,在分析不安全行为各影响因素的基础上,结合不安全行为形成机理图,从突变理论的全新视角构建建筑工人不安全行为尖点突变模型,验证了该模型诠释建筑工人不安全行为形成规律的合理性,并利用该模型对建筑工人不安全行为形成过程进行分析,解释建筑工人在个体心理和准环境因素交互作用下行为的渐变-突变过程。最后提出了建筑工人不安全行为的防御措施、靶向干预点和补救策略。