丙二酸二(2-(2,3-二羟基苯甲酰胺)乙基)酯的合成与螯合性能研究

用2,3-二羟基苯甲酸经羟基保护、酰胺化、酯化和去保护4步反应,生成一种新型的四齿丙二酸二(2-(2,3-二羟基苯甲酰胺)乙基)酯配体.采用傅里叶变换红外光谱(FT-IR)、紫外-可见光谱(UV-Vis)、核磁共振氢谱(1H NMR)、核磁共振碳谱(13C NMR)和质谱(MS)对其结构进行了表征.在中性pH值条件下,研究了这种配体对铀酰离子的络合能力.结果表明,丙二酸二(2-(2,3-二羟基苯甲酰胺)乙基)酯配体与铀酰离子的螯合常数为23.2.     

复采残采煤层小煤矿开采技术研究

平顶山市新华区为全国重点产煤县 (区 ) ,区内煤矿以乡镇小煤矿为主 ;小煤矿井田多位于平顶山煤业集团大型矿井浅部报废水平内 ,主要开采残留煤柱和采后剩余底部煤层。笔者根据新华区小煤矿生产的特点 ,总结、规范了复采残采煤层小煤矿井田开拓、采煤方法 ,重点研究了房柱式采煤法采准巷道布置和采煤工艺 ,特别是保持煤房稳定、提高采煤工作面安全生产的特殊支护问题 ;同时结合小煤矿生产中存在的主要问题 ,依据煤炭行业的法律、法规 ,提出了小煤矿采煤方法改进的技术措施。上述研究成果 ,对规范我国小煤矿的采煤方法、提高小煤矿的安全生产能力、推动小煤矿由数量型向质量效益型转化、发展地方经济都具有重要的现实意义。     

全面质量管理在煤矿安全管理中的应用

叙述了在煤矿安全管理中运用全面质量管理的方法,如实行全员、全方位、全过程的管理等。提出了搞好全面质量管理的措施。     

空调车间的通风除尘设计

针对空调车间的通风除尘,阐述了确定系统风量的方法。     

卧式水、火管快装锅炉烟管渗漏及预防

掌握卧式水、火管快装锅炉烟管渗漏原因 ,预防烟管渗漏 ,减少或杜绝锅炉事故发生。     

张集矿综采工作面瓦斯治理措施及效果分析

张集矿属于煤与瓦斯突出矿井,针对目前所开采的17266工作面地质构造条件复杂、瓦斯涌出量大、处于突出危险区等瓦斯治理难题,采取"风排瓦斯、高抽巷穿层钻孔抽采、运输巷、回风巷顺层钻孔抽采和上隅角埋管抽采"等瓦斯综合治理措施,用分源预测法得出工作面绝对瓦斯涌出量为30.3 m3/min。结果表明,工作面的主要瓦斯涌出来源为本煤层瓦斯涌出。工作面风排瓦斯量11.0 m3/min,工作面瓦斯抽采率达63.0%以上。     

BLEVE: The case of water and a historical survey

After a short update of the current more accepted definition of BLEVE, the special features of water BLEVEs are analyzed. The stronger overpressure wave generated in the case of water as compared to that of other substances is justified in terms of volume change. Through a comparison with liquefied pressurized propane, three possibilities are analyzed: the simultaneous contribution of both the liquid and the preexisting vapor, the contribution of the liquid flash vaporization, and the contribution of the pre-existing vapor. Also a historical survey on a set of 202 BLEVE accidents –the largest sample of BLEVE accidents surveyed until now– is presented. LPG was the most common substances in this set of accidents. However, water and LNG (11% of water and 4% of LNG in the studied cases) have also been involved. Impact failure (44.8%) and human factor (30.3%) were the most common causes of BLEVEs. Transport, storage, process plants, and transfer were the activities in which more accidents occurred.     

Mercury emissions and partitioning from Indian coal-fired power plants

In India coal combustion is the single largest source of emission of mercury which is a wide-spread persistent global toxicant, travelling across international borders through air and water. As a party to the Minamata convention, India aims to monitor and reduce Hg emissions and stricter norms are introduced for mercury emissions from power plants (30 μg/Nm³for flue gas in stack).This paper presents the results obtained during the experimental studies performed on mercury emissions at four coal-fired and one lignite-fired power plants in India. The mercury concentration in the feed coal varied between 0.12–0.27 mg/Kg. In the mercury mass balance, significant proportion of feed coal mercury has been found to be associated with fly ash, whereas bottom ash contained very low mercury. 80%–90% of mercury was released to air through stack gas. However, for circulating fluidised bed boiler burning lignite, about 64.8% of feed mercury was found to get captured in the fly ash and only 32.4% was released to air. The mercury emission factor was found to lie in the range of 4.7–15.7 mg/GJ.     

Quantitative structure - activity study on the reductivedehalogenation potency of the halogenated aromatics

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兴文石林地质地貌景观的脆弱化趋势研究

兴文石林是喀斯特岩溶地质风景名胜区兴文石海的中心景区,喀斯特岩溶山地的生态环境具有一定脆弱特性,随着旅游业的不断发展,景区加大了开发力度,可能导致景区脆弱性的加剧,为了保证在旅游开发中能对景区重要的地质资源进行更好地保护,采用生态脆弱区评级指标及权重值评分法对兴文石林的10个主景点进行了研究,分析得出,兴文石林存在轻生态脆弱性、中生态脆弱性和强生态脆弱性三种梯度趋向,其中,脆弱性最强区域面积达到2平方公里的面积,这些区域分布在景区的边缘地带,因此,要实现旅游资源的可持续利用,必须对强生态脆弱性区域实行禁游和实行退耕还林等措施,以防止脆弱区域的扩大和脆弱性加剧.