全文获取类型
收费全文 | 1596篇 |
免费 | 133篇 |
国内免费 | 173篇 |
专业分类
安全科学 | 733篇 |
废物处理 | 35篇 |
环保管理 | 116篇 |
综合类 | 684篇 |
基础理论 | 112篇 |
污染及防治 | 104篇 |
评价与监测 | 66篇 |
社会与环境 | 29篇 |
灾害及防治 | 23篇 |
出版年
2024年 | 3篇 |
2023年 | 27篇 |
2022年 | 47篇 |
2021年 | 47篇 |
2020年 | 40篇 |
2019年 | 35篇 |
2018年 | 29篇 |
2017年 | 52篇 |
2016年 | 47篇 |
2015年 | 88篇 |
2014年 | 84篇 |
2013年 | 79篇 |
2012年 | 166篇 |
2011年 | 137篇 |
2010年 | 77篇 |
2009年 | 108篇 |
2008年 | 74篇 |
2007年 | 88篇 |
2006年 | 100篇 |
2005年 | 70篇 |
2004年 | 60篇 |
2003年 | 69篇 |
2002年 | 48篇 |
2001年 | 51篇 |
2000年 | 54篇 |
1999年 | 59篇 |
1998年 | 54篇 |
1997年 | 36篇 |
1996年 | 16篇 |
1995年 | 6篇 |
1994年 | 13篇 |
1993年 | 13篇 |
1992年 | 5篇 |
1991年 | 4篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 3篇 |
1981年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1973年 | 1篇 |
排序方式: 共有1902条查询结果,搜索用时 705 毫秒
81.
利用粉煤灰合成Linde type F(K)沸石吸附重金属Zn2+,考察吸附剂量、pH值、反应温度对Zn 2+吸附效果影响,研究沸石吸附Zn2+的等温线与动力学,得到了相应的模型。结果表明:吸附剂量、pH值、反应温度均对Zn2+去除效果影响显著。随着吸附剂量增大,Zn 2+去除效果不断提高,饱和吸附量逐渐减小。初始pH值为3~7时,沸石对Zn2+去除率随pH值升高迅速提高。反应温度越高,沸石吸附Zn2+到达平衡时间越短。沸石对Zn2+吸附过程符合Langmuir吸附等温式,其吸附为单分子层吸附;准二级反应动力学方程能很好描述沸石对Zn2+的吸附行为。 相似文献
82.
83.
本文介绍了氮氧化物产生的机理以及低氮燃烧技术在火电厂大型燃煤锅炉的应用,简述其技术特点和改造措施,并通过试验测试了改造后的效果。 相似文献
84.
氧化亚铁硫杆菌对黄铜矿的生物氧化研究 总被引:1,自引:0,他引:1
针对矿区硫化矿氧化产生的酸性矿山废水(AMD)对生态环境造成严重影响的问题,以矿区常见的黄铜矿(CuFeS2)为研究对象,采用已筛选的氧化亚铁硫杆菌(Acidithiobacillus ferrooxidans,简称A.f菌)为实验菌株,探讨在A.f菌作用下黄铜矿的氧化过程。实验结果表明,A.f菌可显著促进黄铜矿的氧化,第18天有菌体系中的铜离子浓度是无菌体系中的5倍;同时细菌可促进溶液中Fe2+氧化为Fe3+,使氧化还原电位升高,从而对黄铜矿保持较高的氧化速率,并导致体系的pH值降低;还发现黄铜矿的氧化过程中可形成中间产物方黄铜矿(CuFe2S3),而细菌氧化还可产生硫磷化钴(CoPS),中间产物的形成并没有明显延缓黄铜矿的氧化速率;生物氧化可造成矿样表面侵蚀多坑,可能是细菌对黄铜矿的直接氧化作用造成的。由于黄铜矿的生物氧化明显控制其氧化进程,抑制黄铜矿的生物氧化对酸性矿山废水的源头治理具有十分重要的意义。 相似文献
85.
86.
针对昌吉市硫磺沟矿区煤矿开采引起的地表沉陷及其对矿区地表及环境破坏的影响,以减轻地表沉陷危害程度、恢复矿区所在地的生态功能为目标,按照采矿区塌陷类型、塌陷坑大小及塌陷区地理环境,采用不同的土地整治与生态恢复措施,在防治和控制矿区地表沉陷引起的生态破坏及生态环境保护方面取得很好的成果与经验. 相似文献
87.
Romero-Ruiz A Alhama J Blasco J Gómez-Ariza JL López-Barea J 《Environmental pollution (Barking, Essex : 1987)》2008,156(3):1340-1347
Metallothionein (MT) and other biomarker levels were measured in Scrobicularia plana clams to assess pollution of the Guadalquivir Estuary possibly affected by metals released from Aznalcóllar pyrite mine in 1998. After optimizing reagent concentrations for monobromobimane derivatization, MT levels were quantified by reversed-phase high-performance liquid chromatography coupled to fluorescence detection (RP-HPLC-FD) in heated or unheated digestive gland extracts and compared to those obtained by differential pulse polarography (DPP). MT content assayed by RP-HPLC-FD in unheated samples was higher than that obtained by DPP and correlated better with metals and anti-oxidant activities. MT assay by RP-HPLC-FD in unheated extracts would be preferable for assessing metal pollution, due to its greater sensitivity and specificity. In addition to MT induction, glyoxalase II inhibition was well correlated with metal contents. Our results suggest that metals at the estuary do not originate from Aznalcóllar spill, but from those carried along by the river and deposited at its concave bank. 相似文献
88.
Yang Y Hofmann T Pies C Grathwohl P 《Environmental pollution (Barking, Essex : 1987)》2008,156(3):1357-1363
We report on sorption isotherm of phenanthrene (Phe) for river floodplain soil associated with carbonaceous materials, with particular attention being devoted to the natural loading of Phe. Our sorption experiments with original soil samples, size, and density sub-fractions showed that the light fraction had the highest sorption capacity comparable to low rank coals. In addition, the light fraction contributed most for the sorption of Phe in total soil samples. Koc values for all fractions were in the same range, thus indicating that coal and coal-derived particles in all samples are responsible for the enhanced sorption for Phe. Sorption was strongly nonlinear and the combined partitioning and pore-filling model gave a better fit than the Freundlich sorption model. In addition, the spiked PAHs did not show the same behavior as the naturally aged ones, therefore the accessibility of indigenous background organic contaminants was reduced when coal and coal-derived particles are associated with the soils. 相似文献
89.
Comparative on Causes and Accumulation of Selenium in the Tree-rings Ambient High-selenium Coal Combustion Area from Yutangba, Hubei, China 总被引:1,自引:0,他引:1
Liu G Zhang Y Qi C Zheng L Chen Y Peng Z 《Environmental monitoring and assessment》2007,133(1-3):99-103
Toxic trace elements emitted during coal combustion are the main sources of air pollution. They are released into the atmosphere
mainly in the forms of fine ash, smoke and flue, and thus adversely affect plant, animal and human health. Selenium is one
of toxic and the most volatile in coal. Large amount of atmospheric emission of selenium, as well as selenium present and
scrubber stockpiles in ash may create serious environmental problems. In the paper, on the basis of investigating the abundance
and distribution of selenium in plant-rings during recent 20 years, the bioaccumulation of selenium is explained that selenium
in plant, which were collected from the village of selenium-rich coal combustion, is much higher than that in plants collected
away from the village of selenium-rich coal combustion. The main origins of selenium are selenium-rich coal combustion and
high-selenium rock weathered. The selenium recycle by food chain and selenium will accumulate and redistribute in environments. 相似文献
90.
Singh S Sharma DK Dhar S Kumar A Kumar A 《Environmental monitoring and assessment》2007,130(1-3):301-309
Two measurement campaigns were conducted in two sampling sites, An Thinh and Duy Minh, in northern Vietnam during the months
of November–December 2000 and November 2001–February 2002 in order to investigate the extend of the particulate air pollution
from the Pha Lai coal fired power plant. Fine particle samples were analyzed by Energy Dispersive X-Ray Fluorescence spectrometry
and soot samples were analyzed by reflectometer. The result showed that high concentration of soot and elements mostly coincided
with the air masses originating from the power plant. Sea spray aerosol was found to be the major source of chlorine at both
sites. Ratios of specific elements and principal component analysis (PCA) revealed that coal combustion was the main contributor
to the air pollution at both sites. PCA also indicated that there were other sources responsible for the elements emission,
probably the influence of long distance transport and Asian Brown Cloud. 相似文献