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101.
102.
Jeffrey R. Chiarenzelli Ronald J. Scrudato Michele L. Wunderlich James J. Pagano 《Chemosphere》2001,45(8):1159-1165
A combined treatment process utilizing steam distillation followed by electrochemical peroxidation (ECP) has been utilized to remove >90% of the polychlorinated biphenyls (PCBs) in St. Lawrence River sediment and destroy 95% of the PCBs recovered in the condensate. 2 l of condensate were collected by boiling 500 grams of sediment containing 4.3 mg PCBs. Most of the PCBs (82.3%) were recovered as a small volume (<1 ml) of yellow oil floating on the condensate and coating glassware surfaces. The aqueous phase PCBs (182 μg/l) were destroyed (95%) by three sequential ECP treatments at 16.8°C and pH 5, utilizing 1 ml of H2O2 (3%) and periodically reversed current (0.75–1.0 A @ 10 volts). Oxidation is primarily mediated by hydroxyl radicals produced by the reaction of hydrogen peroxide with electrochemically generated ferrous iron (Fenton's reagent). This work suggests steam extraction, in combination with advanced oxidation technologies, provides an effective treatment strategy for contaminated solids. 相似文献
103.
A-O工艺处理沤麻废水的实验研究 总被引:6,自引:0,他引:6
通过中试研究了沤麻废水的处理,结果证明,上流式厌氧污泥床(UASB)- 接触氧化工艺处理高浓度有机废水效果良好。CODCr去除率可达95%-97%,BOD5去除率达96%-99%,木质素去除率为75%-86%,每去除1kgCODCr可 产沼气0.349m^3,处理后的水回用沤麻,具有很好的经济效益 和环境效益。 相似文献
104.
Yalu Shao Qian Sun Liangkai Wang Weiyong Zhan Hongwei Zhang Hua Zhong 《环境科学学报(英文版)》2022,34(5):308-318
Antimony (Sb) is a recognized priority pollutant with toxicity that is influenced by its migration and transformation processes. Oxidation of Fe(II) to Fe(III) oxides, which is a common phenomenon in the environment, is often accompanied by the formation of Mn(III/IV) and might affect the fate of Sb. In this study, incorporated Mn(III) and sorbed/precipitated Mn(III/IV) associated with lepidocrocite were prepared by adding Mn(II) during and after Fe(II) oxidation, respectively, and the effects of these Mn species on Sb fate were investigated. Our results indicated that the association of these Mn species with lepidocrocite obviously enhanced Sb(III) oxidation to Sb(V), while concomitantly inhibiting Sb sorption due to the lower sorption capacity of lepidocrocite for Sb(V) than Sb(III). Additionally, Mn oxide equivalents increased in the presence of Sb, indicating that Sb oxidation by Mn(III/IV) associated with lepidocrocite was a continuous recycling process in which Mn(II) released from Mn(III/IV) reduction by Sb(III) could be oxidized to Mn(III/IV) again. This recycling process was favorable for effective Sb(III) oxidation. Moreover, Sb(V) generated from Sb(III) oxidation by Mn(III/IV) enhanced Mn(II) sorption at the beginning of the process, and thus favored Mn(III/IV) formation, which could further promote Sb(III) oxidation to Sb(V). Overall, this study elucidated the effects of Mn(III/IV) associated with lepidocrocite arisen from Fe(II) oxidation on Sb migration and transformation and revealed the underlying reaction mechanisms, contributing to a better understanding of the geochemical dynamics of Sb. 相似文献
105.
Ferrate(VI) salt is an oxidant and coagulant for water and wastewater treatment. It is considered as a possible alternative method in greywater treatment. However, challenges have existed in putting ferrate(VI) technology into full-scale practice in water and wastewater treatment due to the instability of ferrate solution and high production cost of solid ferrate products. This study demonstrated a new approach of greywater treatment with on-line batch production of Fe(VI) to which Fe(III) salt was oxidized at a weak acidity solution. A series of experiments were conducted to investigate the effect of Fe(VI) on light greywater (total organic carbon (TOC) = 19.5 mg/L) and dark greywater (TOC = 55 mg/L) treatment under different conditions with varying pH and Fe(VI) doses. In addition, the combination use of Fe(VI) and Al(III) salts was proved to be more efficient than using the Fe(VI) salts alone at greywater recycling. The optimum dosage of Fe(VI)/Al(III) salts was 25/25 mg/L for light greywater, 90/60 mg/L for dark greywater, respectively. The TOC values of both light greywater and dark greywater were reduced to less than 3 mg/L with the dosages. The cost for treating greywater was 0.06–0.2 $/ton at ferrate(VI) dosage of 25–90 mg/L and 0.008–0.024 $/ton at AlCl3 dosage of 25–60 mg/L. The full operating cost needs further assessment before the Fe(VI)/Al(III) technology could be implemented in greywater treatment. 相似文献
106.
苯酐生产氧化反应器组火灾爆炸危险性分析与对策 总被引:3,自引:1,他引:2
为预防苯酐生产中最危险部位氧化反应器组发生火灾、爆炸事故 ,详细分析了苯酐生产中氧化反应器组各部位的火灾、爆炸危险性 ,在危险性分析基础上 ,提出了可行的安全对策与措施 ,对苯酐装置的安全生产和管理具有重要的指导意义和参考价值 相似文献
107.
一种悬浮填料在处理PTA废水中的应用 总被引:4,自引:0,他引:4
殷渝强 《石油化工环境保护》2003,26(2):19-23
通过对生产实验及工程实例的运行分析,认为所开发的梅花形多孔面悬浮填料具有优异的性能,以该填料为主体的接触氧化法具有处理能力大、抗冲击性好、挂膜快等优点,在生产实验和PTA废水预处理的实际应用中化学耗氧量(CODcr)去除率分别达到了60%和40%,满足了生产要求。 相似文献
108.
钙钛矿CaFeO_3光催化降解大红染料废水性能的研究 总被引:1,自引:0,他引:1
用柠檬酸络合法制备钙钛矿型复合氧化物CaFeO3,并以其为光催化剂对水溶性染料进行光催化降解实验。讨论了光催化反应时间、催化剂投加量、光照强度、pH值、以及外加氧化剂(H2O2)等因素对光催化活性的影响。实验结果表明:在催化剂投加量0.4g,降解时间180min,pH值2,光照强度200W,H2O2的投加量5mL时,大红染料的降解率可达99.83%。 相似文献
109.
通过对焦作污水处理厂处理工艺特点的研究,分析了其电耗的组成和重点,提出了主要耗电环节的节电措施.每月节约电费12万元。 相似文献
110.