油田化工污水中总氰化物的检测

采用在线蒸馏-流动注射分析法检测大庆油田化工污水中总氰化物。分析流速和温度对流动注射仪检测结果的影响,得出结论:载流流速为1.8mL/min,显色剂流速在1.3mL/min,缓冲溶液流速稳定在1.6mL/min时,分析精度最好;显色反应在60℃以下进行时,可以消除温度差异对检测结果的干扰。该方法适用于油田化工废水中总氰化物的检测。     

地势起伏度对三峡库区人口及经济发展水平的影响

在1[DK]∶10万三峡库区DEM的基础上,采用窗口分析等方法提取了地形起伏度,利用均值变点分析方法确定三峡库区地势起伏度的最佳统计单元是015 km2。首次绘制了基于最佳统计单元的三峡库区地势分布图,确定地形起伏度是影响三峡库区人口分布和经济发展的重要因素之一。在系统分析了三峡库区地形起伏度的分布规律基础上,选择城镇化率、农村居民恩格尔系数、经济密度、人口密度等指标,定量揭示地形起伏度对人口和经济发展的影响。结果显示三峡库区的地形总体以起伏山地为主。地形起伏度与人口密度、经济密度呈极显著的负相关,地势起伏度大的区域,人口密度较小,经济发展相对滞后,农村居民生活相对贫困。地势起伏度小的区域,人口密度较大,经济相对发达。这对认知山区人口和经济的空间格局,将三峡库区资源开发利用以及产业布局在适度的地势起伏度范围,对于有效进行三峡库区资源开发、促进区域经济效益最大化具有重要的参考价值     

Comparison the effects of bioaugmentation versus biostimulation on marine microbial community by PCR–DGGE: A mesocosm scale

In order to better understand the effects of biostimulation and bioaugmentation processes on a marine microbial community, three different mesocosm experiments were planned. Natural seawater(10.000 L) was artificially polluted with crude oil(1 L) and(1) inorganic nutrients(Biostimulating Mesocosm, BM),(2) inorganic nutrients and an inoculum of Alcanivorax borkumensis SK2(Single Bioaugmentation Mesocosm, SBM),(3) inorganic nutrients and inoculums of A. borkumensis SK2 and Thalassolituus oleivorans MIL-1(Consortium Bioaugmentation Mesocosm, CBM). During the experimental period(20 days), samples were taken from each mesocosm and the community structure was analyzed by PCR–DGGE. The 16 S r RNA gene DGGE banding patterns and sequence analysis demonstrated that biostimulation had the lowest effect on microbial biodiversity in the mesocosms; however, the biodiversity of the marine microbial community dramatically decreased in the CBM(Shannon index was 0.6 in T3). The community structures among the three mesocosms were also markedly different,and major bacteria derived from DGGE bands were related to uncultured Gamma Proteobacteria. The biodegradation results show that the Single Bioaugmentation Mesocosm(SBM) system had the highest percentage of degradation(95%) in comparison to the BM mesocosm(80%) and CBM(70%).     

流域环境保护与均衡发展的矛盾及其对策探析

为寻找可兼顾发展与环保、效率与公平、能调动上下游双向积极性的制度安排或系统解决方案,尝试提出了“水系工业排放配额制”的方法,即将水系所能承载的最大工业排放量作为配额,公平分配到流域单元,并允许其交易;企业可在投资治污抑或购买排放配额之间进行自由选择,环境脆弱的流域单元也可向外转让其“闲置”的排放配额,这样其因承担源头保护义务而被迫放弃的部分工业发展权就从配额交易中得到了补偿,并可将此补偿用于发展生态适宜产业,鉴于流域环境保护与均衡发展矛盾的复杂性及工业排放控制的难度,方案的实施宜循序渐进．     

脱硫成本—地面浓度响应模型理论和案例初探

综合分析了目前二氧化硫削减技术政策现状,提出了一种评价二氧化硫治理效率的指标——单位投资地面浓度改善水平。利用该指标对一个地区SO2污染源进行评价,通过设定基金激励机制,吸引高效率的污染源积极完成污染治理任务,并应用博弈论分析基金如何影响企业污染治理决策,达到以较小成本控制污染的目的。通过案例的计算,比较A-P浓度贡献法削减方案和文章推荐方案的脱硫经济成本和环境效益。     

我国大气VOCs监测现状及挑战

对我国开展大气VOCs监测的必要性、监测现状以及主要使用的监测方法进行了分析。目前,我国已初步建立了大气VOCs手工与自动监测网络,主要采用预浓缩-热脱附-气相色谱-质谱/氢火焰离子化检测器法进行PAMS组分和TO-15组分分析,利用高效液相色谱法进行13种醛、酮类组分分析。目前大气VOCs监测还存在数据质量、灵敏度有待提高,不同设备或方法监测结果一致性较差等问题。为此在VOCs监测过程中应进一步加强质量保证与质量控制,并尝试通过提高预浓缩装置除水和干扰物效率、提升进样量等多种手段提高监测灵敏度。     

县级单元国土空间线控机制研究?——以涞水县为例

2019年10月,中共中央办公厅、国务院办公厅联合印发《关于在国土空间规划中统筹划定落实三条控制线的指导意见》后,线控管理模式将取代先前以量控为主的粗放型管理模式。本文以涞水县为例,通过分析涞水县生态保护红线、永久基本农田控制线、城镇开发边界三条控制线（以下简称“三线”）划定中的现实问题,剖析我国当前“三线”划定和实施线控的困境,从探索“三线”划定方法出发建立线控机制,包括“三线”优序管理、线数统管、两级分管和政策保障等内容;通过典型试点、用途管制与用态管治统筹推进线控实践;提出遗留问题处理、永久基本农田控制线和生态保护红线立法、顶层设计等当前主要任务。     

洁净手术部空调系统设计

简要介绍了手术室洁净技术的国内外发展历程与现状,并在此基础上,针对河北省三河市某医院的洁净手术部的工程建设,着重介绍了其工程概况和空调系统设计,包括空调系统的构成、设计参数、主要设备的特点及运行原理。在其工程实践的基础上提出了一些改进措施和建议。     

Monitoring of non-point source pollutants load from a mixed forest land use

The aim of this study was to determine the unit load of NPS (non-point source) pollutants including organic variables such as BOD (biochemical oxygen demand),COD (chemical oxygen demand) and DOC (dissolved organic carbon),nitrogen and phosphorus constituents,and suspended solids (SS) and their event mean concentration (EMC) of runoff flows from a water-shed of mixed forest land use by intensive field experiments.Field monitoring for continuous measurements of rainfall,flow,and water quality was conducted over 12 storm events during 2008–2009 using automated and manual sampling methods.The EMCs of individual runoff event were estimated for each water quality constituent based on the flow rate and concentration data of runoff discharge.The average EMCs of BOD,COD,DOC,SS,TN (total nitrogen),NH 4+ -N,NO 3- -N,TP (total phosphorus),PO 43- -P from the mixed forest land were 1.794,3.498,1.462,10.269,0.862,0.044,0.634,0.034,and 0.005 mg/L,respectively.The annual unit loads of BOD,COD,DOC,SS,TN,NH 4+ -N,NO 3- -N,TP and PO 43--P were estimated as 66.9,133.2,55.5,429.8,36.5,1.6,26.9,1.3 and 0.1 kg/(ha·yr),respectively.In addition,affecting parameters on the EMCs were investigated by statistic analysis of the field data.As a result,significant correlations with precipitation,rainfall intensity,and total runoff flows were found in most constituents.     

Transfer and transport of aluminum in filtration unit

Aluminum salt coagulants were used prevalently in various water works.In this article,the effects of filtration on residual aluminum concentration and species distribution were researched by determining the concentration of diiferent aluminum species before and after single layer filter,double layer filter,and membrane filtration units.In the research,size exclusion chromatography(SEC)was used to separate colloidal and soluble aluminum,ion exchange chromatography(IEC)was used to separate organic and inorganic aluminum, and inductivity coupled plasma-atomic emission spectrometry(ICP-AES)was used to determine the aluminum concentration.The results showed that the rapid filtration process had the ability of removing residual aluminum from coagulant effluent water,and that double layer filtration was more effective in residual aluminum removal than single layer filtration,while nano filtration was more effective than micro filtration.It was found that when the residual aluminum concentration was below 1mg/L in sediment effluent,the residual aluminum concentration in treated water was above 0.2 mg/L.The direct rapid filtration process mainly removed the suspended aluminum.The removal of soluble and colloidal aluminum was always less than 10% and the natural small particles that adsorbed the amount of soluble or small particles aluminum on their surface were difficult to be removed in this process.Micro filtration and nano filtration were good technologies for removing aluminum;the residual aluminum concentration in the effluent was less than 0.05 mg/L.