南宁城市内河水体和表层沉积物中有机氯农药分布特征

采用改进的固相萃取、加速溶剂萃取和气相色谱-电子捕获检测器,对广西壮族自治区南宁5条城市内河的水体和表层沉积物样品中7种痕量有机氯农药(OCPs)的残留状况进行了分析测定. 结果表明,南宁城市内河水体有机氯农药以HCHs为主,ρ(OCPs)为nd～0.141 μg/L. 5个点位沉积物中w(总OCPs)为2.13～2.80 μg/kg,均检出4,4′-DDE和4,4′-DDD,w(DDD)/w(DDE)<1,且DDTs在沉积物中的含量普遍高于HCHs. 各点位沉积物中有机氯农药各组分含量均低于美国环境保护署采用的无毒害风险浓度.      

EMC用V型人工电源网络的解析

本文分别对理想和实用的V型人工电源网络的阻抗(模和相位角)、隔离度进行计算和分析,并将其与某公司生产的ENV216型人工电源网络的测试参数进行比较,验证了ENV216型人工电源网络是完全符合标准要求的,加深了对电源端传导发射测试的理解。     

Do Polynomials Adequately Describe the Hypsometry of Monadnock Phase Watersheds?

Hypsometry has been shown to be a useful tool in geomorphic analysis of watersheds with the use of third‐degree polynomial equations to express the hypsometric curve. Despite its usefulness with watersheds in the equilibrium stage, the third‐degree polynomial has been found to be inadequate to describe the hypsometry of Monadnock phase watersheds. Three other equations — a modified third‐degree polynomial with a rational term, a sigmoidal model, and a double exponential — were used to determine hypsometric attributes of 32 Monadnock phase watersheds and compared to the third‐degree polynomial form. The three other equations were found to be better fits for Monadnock phase watersheds than the third‐degree polynomial equation, regardless of which ratio — area or elevation — was plotted as the independent variable. Due to the occasional failure of each functional form to give logical values for hypsometric attributes, the importance of using more than one form equation is discussed. After determining the best‐fit equation for each watershed, the usefulness of hypsometric attributes is discussed in relation to erosion processes within Monadnock phase watersheds.     

Highly active mixed-phase TiO2 photocatalysts fabricated at low temperature and the correlation between phase composition and photocatalytic activity

The idea of varying volume ratio of water to ethanol in solvent was firstly employed to yield phase composition controllable mixedphase titanium dioxide (TiO2) photocatalysts via a low temperature solvothermal route at 353 K. It was found that anatase contents increase from 0 to 100% with increase of ethanol contents in solvent. The mixed-phase TiO2 with 60% anatase content exhibited the best photocatalytic activity in photodecomposing formaldehyde (FAD) under UV light irradiation, which increases by about ...     

徐闻珊瑚礁保护区海水中多环芳烃的初探

2006年8月,对徐闻珊瑚礁自然保护区中多环芳烃的污染现状进行调查和研究,采用固相萃取,GC-MS检测,分析其中16种多环芳烃（PAHs）单体的含量,结果表明该海域海水中16种PAHs的总平均含量为87.06±90.62 ng·L^-1,变化范围为43.31～435.64 ng·L^-1,与世界其它一些近岸海区海水中的PAHs含量相比污染较为严重。A1站位的PAHs含量偏高,主要来源于陆地的工业废水和生活污水以及渔船油污。PAHs含量的增多对珊瑚礁生态系统具有一定影响,最终将影响到人类的自身健康。     

养殖废水中9种大环内酯及林可酰胺类抗生素的同时测定及分析方法研究

采用固相萃取-超高效液相色谱三重四极杆质谱联用法,建立了同时测定养殖废水中9种大环内酯及林可酰胺类抗生素的方法,并对样品pH值、保存时间、洗脱溶剂、上样流速及过滤材质等进行了优化。测定结果表明,pH值为6,过滤材质为聚丙烯（GHP）,上样速度为5 mL/min时,9种抗生素的加标回收率最优,为71.4%～126%,相对标准偏差最小,为2.4%～7.1%,标准曲线的线性最好,相关系数为0.998 5～0.999 5,检出限为0.78～1.22 ng/L。该方法灵敏度高、检出限低、测定结果准确,能够广泛应用于养殖废水中大环内酯及林可酰胺类抗生素残留量的监测分析。     

碳纳米管在环境样品前处理中的研究现状及应用进展

纳米碳管是一种新型的纳米材料,其独特的分子结构和性能引起了人们的广泛关注。本文重点评述了纳米碳管在环境样品前处理特别是在固相萃取和固相微萃取方面的研究现状与应用进展,并对纳米碳管的应用前景进行了展望。     

煤巷掘进过程中粉尘浓度影响因素分析

为了掌握煤巷掘进过程中粉尘浓度变化的影响因素,根据气固两相流理论,针对矿井掘进工作面的特点,采用计算流体力学的离散相模型（DPM）考察了掘进巷道风速、风筒直径、风筒出风口到掘进工作面距离以及风筒的悬挂高度对粉尘浓度变化的影响。结果发现：当掘进巷道风速为0.25-4 m/s时,提高巷道内的通风风速,可以降低巷道内的粉尘浓度,缩短呼吸性粉尘浓度达到稳定的时间,减小工作面粉尘的危害;有利于通风除尘的风筒相关参数为风筒直径0.4-0.6 m、风筒出风口到掘进工作面距离6-7 m、风筒悬挂高度2.0-2.2 m。     

纤维膜三相液相微萃取在测定偶氮染料降解产生芳香胺中的应用

采用纤维膜保护的三相液相微萃取（HF-LLLME）技术,对偶氮染料在人工汗液和光辐照协同作用下降解产生致癌芳香胺的分析方法进行了研究.选用苯胺、邻甲苯胺、对氯苯胺和对硝基苯胺的汗液混合溶液进行模拟样品预处理,以正辛醇为有机萃取相,在供体相pH值为9,NaC l浓度为200.gL-1,接收相为pH=1的盐酸水溶液,萃取时...     

加速溶剂萃取-固相萃取净化-高效液相色谱法测定玉米作物中多环芳烃含量

建立了加速溶剂萃取-固相萃取净化-高效液相色谱测定玉米作物中15种多环芳烃的方法,优化了试验条件.方法线性关系良好,15种多环芳烃的检出限在0.003 8～0.079μg/kg之间,空白加标试验的相对标准偏差在3.9%～11.7%之间,基质加标回收率在69.3%～115.3%之间.实际样品的测定结果表明,该方法分离效果...