Adsorption selectivity of salicylic acid and 5-sulfosalicylic acid onto hypercrosslinked polymeric adsorbents

Both bottle-point and column-feeding experiments involving different solutes and sorbents were carried out to investigate the adsorption selectivity and separation performance of salicylic acid and 5-sulfosalicylic acid. Their adsorption isotherms onto such hypercrosslinked polymeric adsorbents as NDA-100 and NDA-99 could be well described by the Freundlich equations whose characteristics describe extrathermic and favorable adsorption processes. The adsorption towards NDA-100 mainly depended on the π-π interaction, while that towards NDA-99 was extremely influenced by the static-electric interaction. Additionally, the adsorptive capacity of salicylic acid on NDA-99 decreased while it increased on NDA-100 with the presence of 5-sulfosalicylic acid in the adsorptive environment as the competitive component. Comparatively, the adsorption capacity of 5-sulfosalicylic acid decreased on both resins with salicylic acid as the competitive component. In fact, the difference in the interaction between adsorbent and adsorbate resulted in the straight antagonism on the effective adsorption sites on the adsorbent. In conclusion, the adsorption selectivity of salicylic acid onto NDA-100 was obviously larger than that onto NDA-99 with the existence of 5-sulfosalicylic acid in the adsorptive environment. A satisfactory separation and recovery of tested solutes in aqueous phase could be foreseeably achieved by the sequencing adsorption technique involving NDA-100 as well as NDA-99. Translated from Environmental Pollution & Control, 2005, 27(8): 570–574 [译自: 环境污染与防治]     

On the study of ecosystem health:state of the art

ＩｎｔｒｏｄｕｃｔｉｏｎＤｕｒｉｎｇｌａｓｔｄｅｃａｄｅｓ,ｔｈｅｔｅｒｍ“ｅｃｏｓｙｓｔｅｍｈｅａｌｔｈ”ｉｓｕｓｅｄｗｉｔｈｉｎｃｒｅａｓｉｎｇｆｒｅｑｕｅｎｃｙｉｎｔｈｅｌｉｔｅｒａｔｕｒｅ.Ｔｈｅｇｒｏｗｉｎｇｉｎｔｅｒｅｓｔｓｉｎｔｈｅｓｔｕ...     

Stipulation of the criteria for the construction of eco agricultural county in China

ＩｎｔｒｏｄｕｃｔｉｏｎＮｏｗｗｅａｌｌｃｏｎｃｅｒｎｏｕｒｓｅｌｖｅｓｗｉｔｈｔｈｅｃｏｎｔｅｍｐｏｒａｒｙｐｒｏｂｌｅｍｓｏｆｏｖｅｒｐｏｐｕｌａｔｉｏｎ,ｒｅｓｏｕｒｃｅｅｘｐｌｏｉｔａｔｉｏｎ,ｅｎｖｉｒｏｎｍｅｎｔａｌｐｏｌｌｕｔｉｏｎａｎｄ...     

2024铝合金连接结构两种防护涂层耐蚀性研究

目的研究铝合金两种防护涂层在5%NaCl盐雾环境下的腐蚀疲劳性能。方法针对在两种涂层防护作用下的2024铝合金连接结构,开展实验室加速试验,采用"腐蚀环境-疲劳加载"交替循环的试验模式,得到铝合金两种防护涂层在5%NaCl盐雾环境下的腐蚀疲劳寿命值,对比分析涂层体系对铝合金连接结构的腐蚀疲劳寿命影响。结果 5%NaCl盐雾环境对于铝合金连接结构疲劳寿命有较大影响,相较于传统涂层,纳米涂层在5%NaCl盐雾环境下的防护效果更好。结论纳米涂层表面破坏后快速生成的致密氧化膜能有效提高涂层的耐蚀性能。     

清洁的胡椒基T醚生产工艺的研究I,5-丙基-1,3-苯并二氧杂茂的氯甲基化废水的处理

报道了胡椒基丁醚生产中５－丙基－１，３－苯并二氧杂茂的氯甲基化的废水处理，该废水经蒸馏可回收９４％的盐酸，此酸吸收氯化氢后浓度在３６％以上，可再用于氯甲基化反应。蒸馏残液经分油、Ｆｅｎｔｏｎ试剂处理和五次生炭柱吸附后ＣＯＤＣｒ等项指标均可国家二类污染物的一级排放标准。     

用BOD5/TOD值评价废水可生化性的可行性分析

在阐述ＴＯＤ的组成、可降解率等特征的基础上，探讨了用ＢＯＤ５／ＴＯＤ值评价废水可生化性的可行性及其存在的问题，并提出了相应的改进措施。     

45,X/46,XY chromosome mosaicism detected by midtrimester amniocentesis in amniocyte clones

Amniocyte clones from a mid-trimester pregnancy disclosed 45,X/46,XY sex chromosome mosaicism. Because of the uncertainty concerning the phenotype of the fetus, the parents elected to terminate the pregnancy. Mixed (asymmetrical) gonadal dysgenesis was not found. The fetus appeared to have a normal male uro-genital system. No malformations of any type were detected, although as expected, the fetus did have 45,X/46,XY mosaicism.     

黄酒行业工业废水COD与BOD_5相关性研究

对黄酒厂各工序产生废水及各酒厂产生综合性废水及其处理后的排放水进行ＣＯＤ、ＢＯＤ５的测定，对两者的相关性进行研究，同时对两种回归方程作方差分析及相关系数的显著性检验．回归方程的建立对酒厂污染源监测分析、环境管理具有实际意义．     

Solid phase extraction of methomyl and thiodicarb from environmental water with an activated carbon cartridge and their determination by HPLC

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Conceptual understandings of the ecological engineering issues: in China and abroad

ＩｎｔｒｏｄｕｃｔｉｏｎＡｓａｎｅｗｂｒａｎｃｈｏｆｅｃｏｌｏｇｙａｎｄａｎｉｎｔｅｒｄｉｓｃｉｐｌｉｎａｒｙｆｉｅｌｄ,ｔｈｅｅｃｏｌｏｇｉｃａｌｅｎｇｉｎｅｅｒｉｎｇｗａｓｉｎｉｔｉａｌｌｙｆｏｒｍｕｌａｔｅｄｉｎｔｈｅｅａｒｌｙ1960ｓ.Ｄｕｒｉｎ...