对甲醛法测定二氧化硫的疑议

采用3种方法分别制作的SO2校准曲线无显著差异，且斜率一致，测定标准样品均在保证值范围之内，说明省略标定NaSO3的过程是可行的，同时对甲醛法给定的浓度范围和斜率值进行质疑。     

高层建筑承受纵向地震波时的安全核算构想

高层建筑可预期的灾变非至一端，这里仅探讨高层建筑的抗震性能问题。地震过程中楼体受到的是地震波和自身固有频率的共同作用，此时楼体是一个多维动态系统，其应力状态比传统方法所描述的力学模型要复杂行多。本文应用ANSYS三维仿真有限元软件，采用单点响应谱的方法，对楼体在纵向地震波作用下的应力状态和变形情况进行了分析。对楼体构件单元型式的选择、网格密度的确定、有限元模型的建立等也提出了自己的见解。在后处理中，用列表和图形的方式显示了楼体的位移和应用状态。     

极谱催化波法测定痕量亚硝酸根的研究

在含稀硫氰酸盐的底液中 ,在单扫示波极谱仪上 ,有一灵敏的亚硝酸根催化波。峰电位为 -0 .47V( vs·SCE)。阳极化二阶导数峰高与亚硝酸根浓度在 1× 10 - 7～ 5× 10 - 5mol/L 之间成线性关系。检测限达 5× 10 - 5mol/L( 2 .3ppbNO - 2 )。试验了多种共存离子对测定的影响 ,表明该法具有较好的选择性 ,尤其是大量硝酸根不干扰。应用该法测定了许多样品中的亚硝酸根 ,并对该波的机理进行了研究 ,结果证明该波是 [SCN· NO]催化溶液中的溶解氧还原所致     

风浪流影响下的船舶废气排放测度模型研究

船舶速度是船舶废气排放量计算的重要影响因子。为更加准确地测度船舶废气排放量,考虑海洋环境场对船舶速度的影响,分析了风、浪、流影响下的船舶运动,利用获取的实时风、浪、流信息对船舶AIS提供的航速进行修正,在此基础上建立了风、浪、流影响下的船舶废气排放测度模型,并介绍了船舶引擎功率的估算方法,以及排放因子和负荷因子的确定。最后,选取某散货船和客滚船的两个航次,分别采用传统模型和风、浪、流影响下的船舶废气排放计算模型进行计算,以CO2排放量反推油耗,并计算其与实际油耗的误差,结果表明,与传统模型计算结果相比,基于风、浪、流影响下的船舶废气排放测度模型得到的误差均有所减小,分别减小16.90%、18.60%、21.59%、21.94%,验证了模型的有效性。     

人为热对广州高温天气影响的数值模拟个例分析

基于广州市2009,2000和1990年工业、交通、生活能源统计数据,通过能源清单法估算出广州市对应年份的人为热排放量,再通过在WRF模式中引入2009,2000和1990年的下垫面数据和人为热排放方案,对2005,2012和2017年广州市的3次持续高温过程进行模拟,从而评估不同年代人为热排放水平对广州市极端高温天气的影响.结果表明,模拟的2m气温较为准确,能合理模拟出城市地区的热岛效应,但对极端高温的模拟略有偏低,而引入人为热有助于改善模拟结果.在case2012中,2009,2000和1990年3种人为热排放水平使广州城市下垫面的平均气温分别上升0.53,0.44和0.13℃,热岛强度增强0.43,0.38和0.13℃.3个模拟个例的结果均表明,日间的人为热排放比夜间大,但夜间气温及热岛强度的变化比日间要明显.     

2450MHz电磁波污泥脱水过程中的温度效应

采用2450MHz电磁波进行污泥脱水,研究电磁波加载过程中污泥温度变化对于剩余污泥性质和溶出效应的影响.研究发现,经电磁波加载后,污泥的容积指数（SVI）随着温度的升高而降低,在温度为80℃时由原泥的130.73mL/g降至最低值95.25mL/g,污泥沉降性能得到改善;经电磁波加载后,污泥离心含水率也随着温度的升高持续降低,最低降到80℃时的93.52%;污泥的毛细吸水时间（CST）在60℃时由原泥的29.4s降至最低值23.2s,污泥比阻（SRF）始终高于初始值,说明电磁波的加载一定程度上可以改善剩余污泥的离心脱水和板框压滤脱水效果,但不利于剩余污泥的真空抽滤.在电磁波加载过程中,检测污泥胞外聚合物（EPS）及上清液中可溶性化学需氧量（SCOD）的含量,发现污泥温度升高有利于污泥胞内物质的溶出.在80℃时,污泥上清液中SCOD含量由初始的124.1mg/L增大到883.4mg/L;同时也发现,温度高于60℃后,污泥中微生物细胞破壁更明显,污泥EPS含量随之发生变化,对污泥脱水性能的影响更加显著.     

Theoretical study on the formation mechanism of polychlorinated dibenzothiophenes/thianthrenes from 2-chlorothiophenol molecules

Homogeneous formation of polychlorinated dibenzothiophenes/thianthrenes(PCDT/TAs),sulfurated compounds analogous to polychlorinated dibenzo-p-dioxin/dibenzofurans(PCDD/Fs), has been well-documented to occur via radical–radical coupling reactions from chlorinated thiophenol precursors. However, the current understanding of the formation mechanism of PCDT/TAs is exclusively limited to the inherent point of view that chlorothiophenoxy radicals act as the only required intermediates for PCDT/TAs. This study investigates reaction pathways for the formation of PCDT/TAs involving two new types of radical species, i.e., substituted phenyl radicals and substituted thiophenoxyl diradicals. Taking 2-chlorothiophenol(2-CTP) as a model compound for chlorothiophenols,we found that apart from the mostly discussed chlorothiophenoxy radicals, substituted phenyl radicals and substituted thiophenoxyl diradicals could also be readily formed via the reaction of 2-CTP with H radicals. Furthermore, direct self-and cross-coupling of these radicals can result in the formation of PCDT/TAs, including 1-monochlorothianthrene(1-MCTA), 1,6-dichlorothianthrene(1,6-DCTA), 4,6-dichlorodibenzothiophene(4,6-DCDT)and 1,6-dichlorodibenzothiophene(1,6-DCDT). The pathways proposed in this work are proven to be both thermodynamically and kinetically favorable. Particularly, comparisons were made between the formation mechanisms of sulfurated and oxygenated dioxin systems from an energetic point view, showing that replacing oxygen with sulfur atoms greatly reduces the activation barriers of the rate-controlling steps involved in the PCDT/TA formation processes compared with those involved for PCDD/Fs. The calculated results in this work may improve our understanding of the formation mechanism of PCDT/TAs from chlorothiophenol precursors and should be informative to environmental scientists.     

大尺寸通风管网中障碍物对瓦斯爆炸冲击波传播特性影响的数值模拟

为了研究大尺寸通风管网中的瓦斯爆炸传播规律,采用数值模拟方法,针对具有不同障碍物数量的大尺寸通风管网模型,利用Fluent分析管网中各个监测点的超压变化曲线以及障碍物附近的速度矢量图,分析爆炸冲击波传播规律。研究结果表明:初期瓦斯爆炸后,障碍物的存在改变了通风管网内未燃瓦斯的积聚区域;高温和高压发生耦合作用,在氧气相对充足的进气管道中形成二次爆炸;障碍物与火焰波以及管网自身结构变化等多种因素形成复合作用,改变了通风管网内瓦斯爆炸冲击波的传播路径和叠加区域的位置;无障碍物时高压区域出现在进气管道中,有障碍物时高压区域出现在中部直管与斜管的交汇处附近,且数值相对较大。     

浅层小尺度隐伏断层地表勘探的正演模拟及应用

采用二维声波方程有限差分法对浅层小尺度隐伏断层地质模型的地震波场响应进行数值模拟,分别从震源位于断层下降盘顶、断层上升盘顶及断层顶三个不同位置进行正演模拟,对地震波场在断层模型中的传播规律及其地震记录变化特征进行了详细分析。结果表明多个单炮记录的变化对比不仅可以对断层进行快速有效的判断,而且为分析断层几何类型、估计断裂带范围与宽度等方面提供重要的依据。同时将模拟结果应用到实际生产中,取得了较好的应用效果。该方法能有效辅助实际野外工作中对断层的判断,为合理设计观测系统及采集参数设置提供指导,对提高浅层地震勘探现场工作效率和精度具有重要作用。     

Modelling of dust lifting process behind propagating shock wave

Dust dispersion from a layer is a complicated problem, which has not been completely solved yet, especially if an Eulerian–Eulerian approach has to be used to model the two-phase dusty flow. In previous investigation, a phenomenological model of the dust dispersion process from a layer was developed, but the evaluation of the model revealed some weaknesses. In the current paper, the model of the dust dispersion process was presented and three improvements of the model were studied: Saffman force, Magnus force and particles collisions. The implementation of Magnus and Saffman forces into the code did not improve the numerical results and it was shown that it had very little influence on the dust lifting process, in case the phenomenological model of the layer is used. Some explanations were proposed in the paper. Besides, an empirical model of particles collisions was also added to the code and its influence on the results was studied. It was shown that the particles collisions model improved the obtained results, but further modifications are to be studied in the future.