全文获取类型
收费全文 | 933篇 |
免费 | 102篇 |
国内免费 | 423篇 |
专业分类
安全科学 | 72篇 |
废物处理 | 43篇 |
环保管理 | 118篇 |
综合类 | 718篇 |
基础理论 | 165篇 |
污染及防治 | 225篇 |
评价与监测 | 57篇 |
社会与环境 | 52篇 |
灾害及防治 | 8篇 |
出版年
2024年 | 2篇 |
2023年 | 10篇 |
2022年 | 26篇 |
2021年 | 26篇 |
2020年 | 22篇 |
2019年 | 31篇 |
2018年 | 22篇 |
2017年 | 37篇 |
2016年 | 52篇 |
2015年 | 53篇 |
2014年 | 71篇 |
2013年 | 106篇 |
2012年 | 92篇 |
2011年 | 101篇 |
2010年 | 82篇 |
2009年 | 100篇 |
2008年 | 62篇 |
2007年 | 91篇 |
2006年 | 96篇 |
2005年 | 54篇 |
2004年 | 54篇 |
2003年 | 44篇 |
2002年 | 29篇 |
2001年 | 32篇 |
2000年 | 29篇 |
1999年 | 21篇 |
1998年 | 18篇 |
1997年 | 14篇 |
1996年 | 19篇 |
1995年 | 11篇 |
1994年 | 9篇 |
1993年 | 6篇 |
1992年 | 4篇 |
1991年 | 7篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1971年 | 2篇 |
排序方式: 共有1458条查询结果,搜索用时 46 毫秒
141.
海洋纤毛虫——巨大拟阿脑虫的实验生态研究Ⅲ.pH对种群生长的影响 总被引:1,自引:0,他引:1
就水环境中pH对巨大拟阿脑虫Paranophys magna(纤毛门,盾纤目)种群生长的影响及后者的应答与适应进行了探讨,结果表明,虫体生存的pH阈值约为5-9.6,最适范围为7.0-9.0;pH对巨大拟阿脑虫的种群生长有显著影响,种群自然增长率及种群所达最大种群密度均随pH的不同而明显改变。 相似文献
142.
143.
以柠檬酸废水厌氧颗粒污泥为接种物,在不同pH值调控条件下开展柠檬酸生产废水剩余活性污泥厌氧发酵产酸研究.通过对发酵液挥发性脂肪酸(VFAs)、有机质、氮磷和污泥脱水性能的分析,探讨了柠檬酸污泥厌氧产酸机制.结果表明,pH≥10的碱性条件更有利于有机质的溶出从而促进VFAs的产生.三维荧光光谱分析发现在恒定pH值下腐殖酸(HA)和富里酸(FA)会大量溶出降低VFAs的产量.初始pH=10是柠檬酸污泥厌氧产酸的最佳p H值,发酵4d的VFAs浓度最高达(6681.47±126.82)mgCOD/L,是文献报道中市政污泥产酸量的近2倍,其中乙酸占比49.8%,发酵后产酸功能菌Chloroflexi、Bacteroidota的相对丰度分别由初始的9.52%、10.87%增至16.84%、14.39%,污泥归一化毛细吸水时间(nCST)为(11.34±0.27)s·L/g,脱水性能良好,发酵液TP浓度为(20.45±0.33) mg/L.研究表明,利用柠檬酸剩余活性污泥碱性厌氧发酵产酸作为污水处理过程中的外加碳源具有较大潜力. 相似文献
144.
Fanos Papanicolaou Stella Antoniou Ioannis Pashalidis 《Journal of environmental radioactivity》2009,100(10):854-857
Phosphogypsum is a waste by-product of the phosphate fertilizer industry, which is usually disposed in the environment because of its restricted use in industrial applications. Physico-chemical conditions existing in stack fluids and leachates are of major importance and determine solubility and redox stability of phosphogypsum, as well as radionuclide release from stacks to terrestrial environments. The aim of this study is to assess the effect of key parameters (e.g. ionic strength, temperature, pH) on the solubility of phosphogypsum. Phosphogypsum sampling and in-situ measurements were carried out at a coastal stack in Cyprus, solubility experiments were performed in simulated laboratory systems and thermodynamic calculations by means of MINTEQA2, an equilibrium speciation model. Generally, increasing ionic strength and temperature leads to increased phosphogypsum solubility, with the former being much more effective. The increased solubility of phosphogypsum in saline solutions is attributed solely to ionic strength effects on the activity of ionic species in solution and no solid phase transformations could be observed. The effect of pH on phosphogypsum solubility seems to be insignificant at least in a pH range between 4 and 8. Regarding uranium levels, there is a strong correlation between salinity and uranium concentration and linear correlation between phosphogypsum solubility and uranium levels in stack solutions, indicating the incorporation of uranium into the gypsum lattice and the formation of a solid solution. 相似文献
145.
Abstract The pH‐disappearance rate profiles were determined at ca. 25°C for 24 insecticides at 4 or 5 pH values over the range 4.5 to 8.0 in sterile phosphate buffers prepared in water‐ethanol (99: 1 v/v). Half‐lives measured at pH 8 were generally smaller than at lower pH values. Changes in half lives between pH 8.0 and 4.5 were largest (>1000x) for the aryl carbamates, carbofuran and carbaryl, the oxime carbamate, oxamyl, and the organophosphorus insecticide, trichlorfon. In contrast, half lives of phorate, terbufos, heptachlor, fensulfothion and aldicarb were affected only slightly by pH changes. Under the experimental conditions described half lives at pH8 varied from 1–2 days for trichlorfon and oxamyl to >1 year for fensulfothion and cyper‐methrin. Insecticide persistence on alumina (acid, neutral and basic), mineral soils amended with aluminum sulfate or calcium hydroxide to different pH values and four natural soils of different pH was examined. No correlation was observed between the measured pH of these solids and the rate of disappearance of selected insecticides applied to them. These observations demonstrate the difficulty of extrapolating the pH dependent disappearance behaviour observed in homogeneous solution to partially solid heterogeneous systems such as soil. 相似文献
146.
Donald S. Cherry John H. Van Hassel Paul H. Ribbe John Cairns 《Journal of the American Water Resources Association》1987,23(2):293-306
ABSTRACT: The potentially toxic components in coal ash (ash particles, heavy metals) were evaluated in laboratory static, acute (96 hr) bioassays, both separately and in various combinations with extreme pH (5.0 and 8.5), using rainbow trout (Salmo gairdneri) and bluegifi sunfish (Lepomis macrochirus). Ash particle morphology and metal distribution anlaysis, using electron microscopy and surface-subsurface analysis by ion microscopy, showed that metals could be either clumped or evenly distributed on the surface of fly ash. Surface enrichment on fly ash particles from electrostatic precipitators, as measured by ion microscopy, was found for cadmium, copper, chromium, nickel, lead, mercury, titanium, arsenic, and selenium. Bottom (heavy) ash was not acutely toxic to either fish species at concentrations of up to 1500 mg/l total suspended solids (TSS) at pH 5.0, 7.5, or 8.5. Fly ash particles were not acutely toxic to blue-gill at levels up to 1360 mg/l TSS. Rainbow trout were highly sensitive to fly ash (25 to 60 percent mortality) at concentrations of 4.3 to 20.5 mg/I TSS when dissolved metal availability was high but were not sensitive at higher particulate concentrations (58 to 638 mg/I TSS) when dissolved metals were low. When metals were acid-leached from fly ash prior to testing, no rainbow trout mortality occurred at TSS concentrations of up to 2,350 mg/l TSS. When the percent of dissolved metal was high (e.g., 50–90 percent of the total), fish mortality was increased. Rainbow trout were nearly two orders of magnitude more sensitive than bluegill when subjected to a blend of cadmium, chromium, copper, nickel, lead, and zinc. The two species were similar in their acute sensitivity to acidic pH at levels at or below 4.0 and alkaline pH of 9.1. If the pH of coal ash effluent is contained within the range 6.0 to 9.0, acute toxicity to fish can be attributed to trace element availability from fly ash but not heavy ash. Control of holding pond and effluent pH and maximizing pond residence time are important strategies for minimizing effects of ash pond discharges on fish. 相似文献
147.
148.
149.
Anne Chin Daniel L. Harris Todd H. Trice Jeffrey L. Given 《Journal of the American Water Resources Association》2002,38(6):1521-1531
ABSTRACT: In Yegua Creek, a principal tributary of the Brazos River in Texas, surveys of a 19 km channel reach downstream of Somerville Dam show that channel capacity decreased by an average of 65 percent in a 34 year period following dam closure. The decrease corresponds with an approximately 85 percent reduction in annual flood peaks. Channel depth has changed the most, decreasing by an average of 61 percent. Channel width remained stable with an average decrease of only 9 percent, reflecting cohesive bank materials along with the growth of riparian vegetation resulting from increased low flows during dry summer months. Although large changes in stream channel geometry are not uncommon downstream of dams, such pronounced reductions in channel capacity could have long‐term implications for sediment delivery through the system. 相似文献
150.
Irving Spiewak 《Journal of the American Water Resources Association》1971,7(4):844-855
ABSTRACT The selection of an evaporator design must reflect the balancing of captial cost (primarily in heat exchanger surface and vessels) against operating cost (primarily steam cost) to achieve minimum cost. In a conjunctive plant the tendency is to select a low-capital cost, high-operating cost plant. In addition, it is advantageous to use a high-capacity plant which needs to be operated much less of the time than a plant which is sized just at the needed rate. For example, in the study of a possible system to satisfy a future increase of 450 MGD in water supply to New York Qty, a plant of 750 MGD capacity was selected as optimum. This plant, of the advanced VTE-MSF process type, would have a performance ratio of 9 lb product/1000 Btu as compared to 10-13 normally used for base-loaded plants. Steam would be supplied by a multi-unit dual-purpose nuclear power plant. The most economical type of energy supply would be “interruptible”; the steam would be used by a low pressure turbine to generate electricity during periods of peak electrical demand but would be available to the desalting plant at other times. The low pressure turbine would be available as spinning reserve during desalting plant operation. It is estimated that the desalting plant would have a load factor of 27 per cent over its life. 相似文献