废物热解焚烧工艺设备选择的技术要点

主要介绍了热解氧化焚烧的概念及原理,指出了实现热解氧化焚烧的关键因素。根据热解焚烧的控制过程,详细地介绍了静态热解和动态热解的工艺特点,并对实现热解焚烧所采用的焚烧炉进行了比较及适用性分析,提出了废物热解焚烧工艺的技术要点。     

水环境质量评价的可视化系统研究

以河南省安阳市境内3条水系为例,提出了实现水环境质量评价的计算机图形可视化的技术路线和系统设计方案。深入探讨了实现河流水系的动态控制和交互处理的可能性。通过形象直观的计算机动态图形画面,再现了河流水质的现在和将来。      

Consequence risk analysis using operating procedure event trees and dynamic simulation

Faults due to human errors cost the petrochemical industry billions of dollars every year and can have adverse environmental consequences. Unquantified human error probabilities exist during process state transitions performed each day by process operators using standard operating procedures. Managing the risks associated with operating procedures is an essential part of managing the overall safety risk. Additional operator training and safety education cannot eliminate all such faults due to human errors; therefore, we propose an operating procedure event tree (OPET) like analysis with branches and events specifically designed to perform risk analysis on operating procedures. The OPET method adapts event trees to analyze the risk due to human error while performing operating procedures. We consider human error scenarios during the procedure and determine the likely consequences by applying dynamic simulation. The modified event tree provides an estimate of the error frequencies.Operating procedure steps were developed, and potential operator faults were determined for two typical equipment switching procedures found in chemical plant operations. Then, dynamic simulation using Aspen HYSYS software was applied to determine the overpressure related consequences of each fault. Finally, the error frequencies resulting from those scenarios were analyzed using operating procedure event trees. We found that a typical ethylene plant gas header would overpressure with 0.6% frequency per manual dryer switch. Since dryer switches occur from every few days up to once per shift, these results suggest that dryer switching should be automated to ensure safe and environmentally friendly operation. Process dryer switching performed manually by operators opening and closing gate valves can be automated with control valves and a distributed control system. A sample distillation column was found to overpressure with 0.85% frequency per manual reflux pump switch.     

Experimental research of the dynamic behavior of the natural gas suspension pipeline aerial crossing during pigging process

Suspension pipeline aerial crossings (SPAC) are mainly used to carry pipeline segments over large obstacles that are not suitable for trenchless technologies. It may suffer great vibrations and displacements during the pigging process due to the dynamic pigging loads and insufficient constraints from cables. Based on similarity criteria, an experimental scale model based on the Nujiang natural gas SPAC was designed and established. The vibration and displacement of the scale model were measured under different pigging velocities and liquid deposit volumes. The experimental results reveal that the natural gas SPAC vibrates during the pigging process, but the displacement versus time forms a U curve instead of a sinusoidal like curve. The extremum of the displacement is positively related to the pigging velocity and liquid deposit volume. In particular, the extremum increases by 0.37% with a 1% increase in the pigging velocity, while the displacement increases by 0.62% with a 1% increase in the liquid deposit volume. Under certain pigging conditions, or with damaged constraint components, the displacement extremum could be unacceptable. A low pigging velocity and a short time interval between two pigging operations are suggested to guarantee the safety of the natural gas SPACs. Besides, based on the experimental data, an empirical formula is developed to obtain the SPAC displacement-time curve with consideration of the span length, the pipeline diameter, the pigging velocity, the length and holdup of the liquid column. This formula can help to determine a suspicious displacement overrun, and to develop a data basis for choosing a safe pigging scheme of SPACs. This research provides insightful information to understand the mechanism of the SPAC's dynamic response as well as a practical tool to calculate the SPAC's displacement during the pigging process.     

Reliability evaluation of fire alarm systems using dynamic Bayesian networks and fuzzy fault tree analysis

In almost all industries, fire alarm systems play a vital role in the reducing the risks associated with fires and damages. Therefore, it is necessary to evaluate their reliability and performance in emergency situations. The present study aimed to use fault tree analysis (FTA) to determine the root causes involved in the failure of fire alarm systems, to use Fuzzy set theory and expert elicitation to determine relative probabilities, and finally, to evaluate the reliability of a fire alarm system using dynamic Bayesian networks (BNs) during a thirty-six months period. A total of 29 basic events were detected from the FT. The reliability of the fire alarm system was estimated at 0.954 according to the FT and 0.957 according to conventional BNs. The reliability of the fire alarm system after 36 months was estimated at 0.375 according to dynamic BNs. All the events involved in the failure of fire alarm systems were drawn in the fault tree diagram. The results indicate that remodeling of these systems and simultaneous construction activities are the most important factors in the failure of the fire alarm system. System reliability can also be increased to 0.965 by providing preventive and control measures to reduce the probability of critical events.     

Mutual effects between dynamic leakage behavior and the pressure/temperature in a LNG tank with external heat fluxes

The objective of this work is to investigate and model the mutual effects between the dynamic pressure/temperature in the LNG tank and the leakage behavior with external heat fluxes. The results suggest that the pressure and temperature in tank during leakage change with the comparison results between the heat flux consumed in liquid boil-off and the external heat flux supplied. At the liquid leakage stage, when the external heat flux is not very high, the pressure in tank tends to increase significantly, even results in tank explosion. It increases more and more heavily with higher and higher external heat fluxes. At the vapor leakage stage, large amount of vapor spray out, which results in a high generation rate of vapor by the liquid boil-off. The pressure in tank normally decreases to be low, which is unfavorable for the LNG tank explosion. Therefore, at this vapor leakage stage, blocking the leakage hole as soon as possible is not always a right choice for fire fighters. Finally, it is suggested that reducing the heat flux into the tank, either at the liquid leakage stage or in vapor one, is key to the tank safety.     

浅议排污申报登记与环境监理的关系

阐述了排污申报登记与环境监理的关系。指出,排污申报的作用 应当体现在对污染源监理的全过程中,应对申报数据进行核查,形成一个有效的污染源动态管理系统,并建立相应的污染源动态信息库。     

松花江哈尔滨段主干流常规污染物动态衰减速度系数的测算研究

采用2011—2013年松花江哈尔滨段各断面水质监测数据和老头湾水文数据,运用实测资料反推法和河流一维水质模型对该段干流的COD、BOD5、NH3-N的衰减速度系数K进行测算,结果表明:1—12月朱顺屯—大顶子山的KCOD、KBOD5、KNH3-N分别在0.035 d-1~3.372 d-1、0.368 d-1~5.459 d-1和0.245 d-1~5.600 d-1之间;冰封期各污染物K值小于明水期,夏季(6—8月)K值大于其他季节。以2013年阿什河口下—呼兰河口下河段上、下游各断面的监测数据对测算的各污染物动态K值进行率定,实际监测值与预测浓度年内变化趋势基本一致,相对误差在25%以内,水质验证结果较满意。     

Field-scale operation of methane biofiltration systems to mitigate point source methane emissions

Methane biofiltration (MBF) is a novel low-cost technique for reducing low volume point source emissions of methane (CH₄). MBF uses a granular medium, such as soil or compost, to support the growth of methanotrophic bacteria responsible for converting CH₄ to carbon dioxide (CO₂) and water (H₂O). A field research program was undertaken to evaluate the potential to treat low volume point source engineered CH₄ emissions using an MBF at a natural gas monitoring station. A new comprehensive three-dimensional numerical model was developed incorporating advection-diffusive flow of gas, biological reactions and heat and moisture flow. The one-dimensional version of this model was used as a guiding tool for designing and operating the MBF. The long-term monitoring results of the field MBF are also presented. The field MBF operated with no control of precipitation, evaporation, and temperature, provided more than 80% of CH₄ oxidation throughout spring, summer, and fall seasons. The numerical model was able to predict the CH₄ oxidation behavior of the field MBF with high accuracy. The numerical model simulations are presented for estimating CH₄ oxidation efficiencies under various operating conditions, including different filter bed depths and CH₄ flux rates. The field observations as well as numerical model simulations indicated that the long-term performance of MBFs is strongly dependent on environmental factors, such as ambient temperature and precipitation.     

Direct comparison of 210Po, 234Th and POC particle-size distributions and export fluxes at the Bermuda Atlantic Time-series Study (BATS) site

Particle-reactive, naturally occurring radionuclides are useful tracers of the sinking flux of organic matter from the surface to the deep ocean. Since the Joint Global Ocean Flux Study (JGOFS) began in 1987, the disequilibrium between ²³⁴Th and its parent ²³⁸U has become widely used as a technique to measure particle export fluxes from surface ocean waters. Another radionuclide pair, ²¹⁰Po and ²¹⁰Pb, can be used for the same purpose but has not been as widely adopted due to difficulty with accurately constraining the ²¹⁰Po/²¹⁰Pb radiochemical balance in the ocean and because of the more time-consuming radiochemical procedures. Direct comparison of particle flux estimated in different ocean regions using these short-lived radionuclides is important in evaluating their utility and accuracy as tracers of particle flux. In this paper, we present paired ²³⁴Th/²³⁸U and ²¹⁰Po/²¹⁰Pb data from oligotrophic surface waters of the subtropical Northwest Atlantic and discuss their advantages and limitations. Vertical profiles of total and particle size-fractionated ²¹⁰Po and ²³⁴Th activities, together with particulate organic carbon (POC) concentrations, were measured during three seasons at the Bermuda Atlantic Time-series Study (BATS) site. Both ²¹⁰Po and ²³⁴Th reasonably predict sinking POC flux caught in sediment traps, and each tracer provides unique information about the magnitude and efficiency of the ocean's biological pump.