复合式吸收器采样还原一体化冷原子吸收法测定大气中的汞

目的研制一种高效率采集大气中汞的吸收器.方法利用一种集大泡式与玻砂板式吸收器为一体的复合式吸收器采样,并使采样还原一体化冷原子吸收法测定大气中汞.结果平均吸收率为96%,变异系数在4%～12%之间.结论复合式吸收器采样吸收效率高,适合于大气中微量汞的测定.     

两次金汞齐—冷原子吸收光谱法测定大气中的痕量气态总汞

本文作者在已有仪器的基础上进行简单改装,建立了两次金汞齐—冷原子吸收光谱法测定大气中的微量气态总汞的方法。研究表明,这种方法最低检出限为０．０５ｎｇ;１００μｌ饱和汞蒸气连续测定结果表明其相对标准偏差＜１．４１％。在０～２．０ｎｇ汞量范围内标准工作曲线线性关系良好。运用该法,对贵州省万山汞矿、丹寨汞矿、清镇汞污染农田、省农科院和中国科学院地球化学研究所等地大气气态总汞进行了测定。这种分析方法还可以运用到其它环境样品微量汞的测定。     

Characteristic and mercury adsorption of activated carbon produced by CO2 of chicken waste

Preparation of activated carbon from chicken waste is a promising way to produce a useful adsorbent for Hg removal. A three-stage activation process （drying at 200℃, pyrolysis in N2 atmosphere, followed by CO2 activation） was used for the production of activated samples. The effects of carbonization temperature （409-4500℃）, activation temperature （700-900℃）, and activation time （1-2.5 h） on the physicochemical properties （weight-loss and BET surface） of the prepared carbon wereinvestigated. Adsorptive removal of mercury from real flue gas onto activated carbon has been studied. The activated carbon from chicken waste has the same mercury capacity as commercial activated carbon （Darco LH） （Hg^v： 38.7% vs. 53.5%, Hg^0： 50.5% vs. 68.8%）, although its surface area is around 10 times smaller, 89.5 m^2/g vs. 862 m^2/g. The low cost activated carbon can be produced from chicken waste, and the procedure is suitable.     

试剂对微量汞分析的影响及其引起的“干扰异常”的排除

用ＸＧ－冷原子吸收型数字测汞仪对水汞等进行纳克级别以下的极微含量分析。测量中加入的一些试剂影响测量数据的准确性和稳定性。对此笔者进行了一些实验研究。本文分析和介绍了测定中添加试剂的影响情况和一些实测数据分析实例；并提出了一般的解决方法，在地震和其他领域微量汞测量中有使用价值。     

Characterization of fulvic acids during olive mill waste composting (Elemental, Thermal and fluorescence analyses)

Elemental analysis, fluorescence spectroscopy and differential scanning calorimetry (DSC) were applied to the study of fulvic acids isolated from different stages during olive mill waste composting. The fulvic extracted acids are characterized by a high nitrogen content and O/C ratio values that may result from the high degree of humification and the synthesis of more condensed humic complexes. This was confirmed by fluorescence spectroscopy in the synchronous-scan mode by the decrease of shoulder intensities at intermediate wavelengths indicating the increase of polycondensation and conjugation of unsaturated structures and the greater uniformity of fluorophores. Fluorescence spectra in the emission, excitation and synchronous modes became simpler with compost maturation. This was confirmed by DSC results which proved the high degree of polycondensation of aromatic nuclei of fulvic acid molecules during olive mill waste composting.     

岷—沱江汞环境背景值研究

本文介绍了用冷原子荧光法测定岷—沱江原水(总汞)、过滤水(溶解性汞)、悬浮物(悬浮态汞)及沉积物中汞含量。方法检测限为0.004μg/l。经选用W检验、Vistelius置信带法和偏度、峰度法联合进行汞含量分布类型检验,综合判断、研究得出岷—沱江水系河水中汞背景值(总量)为0.25μg/l,汞主要以溶解态存在于水体中,沉积物中汞背景值为0.018mg/kg。岷—沱江水系汞背景值无论与国内各水系还是同世界河流水平相比,均处于相同和较低水平。     

Effects of mercury contaminated rice from typical chemical plant area in China on nitric oxide changes and c-fos expression of rats brain

IntroductionMercury(Hg) ,asoneoftheprioritypollutantandhottopicinthefrontofenvironmentalresearchinmanycountries ,hasbeenpaidhigherattentionintheworldsincethemiddleoflastcentury .Chinaisthethirdlargestmercuryproducer,GuizhouProvince(2 4°3 0′— 2 9°13′N     

怀4井气汞固体潮观测中的两个关键环节

本文在数字化地下流体化学组分的观测中,认为热水井的脱气和脱气后的气体干燥是两个关键环节。我们在怀4井的气汞观测中,经过多次试验改进较好地解决了这两个环节。2004年以来,观测资料稳定,并清晰地记录到了固体潮形态。     

银膜富集法测定大气中的气态汞

探讨了用银膜富集管测定大气中气态汞的方法、影响气态汞吸收率的因素和银膜富集管的再生方法。结果表明 :银膜富集管对大气中的气态汞能有效富集。当银膜长 /管径大于 2 0 0 mm/4.5mm,流速为 0 .4L/min时 ,银膜富集管对气态汞的吸收率达 98%以上。     

氢化物-原子吸收法测定水中汞的分析质量控制

在实际检测工作中,通过制作质控图控制方法的精密度和准确度,有效地控制了系统误差和随机误差,试样的回收率为97～102%,相对标准偏差2.59%,实际样品测定结果较好.