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21.
通过利用挥发回转窑处置钢丝绳行业污泥的工业化试验,测定了烟气排放参数及污染物排放指标,分析了污泥添加对挥发回转窑烟气排放的影响程度及各项污染物指标之间的相关性。结果表明,污泥添加量18%~22%,对挥发回转窑烟气排放无影响,烟尘、SO2、氮氧化物、Zn、Pb、HCl等各项污染物指标均符合国家控制标准;烟尘排放浓度与Pb、Zn排放浓度呈显著正相关;SO2排放浓度与烟气含氧量、空气过剩系数、排放浓度呈显著负相关。通过控制烟气中烟尘浓度可减少Zn、Pb的排放,在满足SO2排放浓度达标的同时,还应加强工艺供氧量的管理,控制的产生,减少烟气对生产设备的腐蚀。 相似文献
22.
23.
工业企业挥发性有机物(VOCs)污染排放对大气环境影响日益突出,工业源VOCs污染防治成为环境保护的重点工作。为进一步提高秦皇岛市工业源挥发性有机物(VOCs)治理的科学性、针对性和有效性,对2019年秦皇岛市重点排污企业VOCs的排污量、区域分布、排放行业等进行了详细调查分析:秦皇岛市重点工业源VOCs排放总量为6875.83t,排放量最大的区域是秦皇岛经济技术开发区,占比51.1%;排放量最大的行业是交通运输设备制造业,占总排放量的33.5%;溶剂使用源的排放量最大,占比52.3%。 相似文献
24.
25.
对某省52家焚烧企业(21家生活垃圾和31家危险废物)排放烟气数据进行了分析,结果表明,两类焚烧企业二噁英类17种单体分布有所不同,生活垃圾焚烧烟气中浓度较高的是O8CDD和O8CDF;危险废物焚烧烟气中较大的是2,3,4,7,8-P5CDF、2,3,7,8-T4CDD和1,2,3,7,8-P5CDD;两类焚烧企业二噁英类单体对I-TEQ贡献最高的都是2,3,4,7,8-P5CDF,贡献率分别为0. 7%~45%和10%~67%;两者的17种二噁英类与I-TEQ的相关性分析表明,1,2,3,7,8-P5CDF在2类焚烧炉中与I-TEQ均存在较高的相关性,其相关系数分别0. 932和0. 927,可以作为潜在的测定指示物。 相似文献
26.
能源短缺和环境污染已成为中国推行全面协调可持续发展的重要制约因素,作为能源消耗的主体和环境污染的控制重点,在城市层面推动能源发展战略的转变和强化环境保护是发展的基本要求.鉴于能源与环境之间的高度关联性,在管理方面要求对能源发展和环境保护进行统筹考虑和综合管理,充分强调能源经济效率和环境制约因素在能源发展中的作用.通过制定合理的产业能效标准和排放绩效标准,为城市经济、能源和环境的可持续性发展提供科学性、系统性决策支持. 相似文献
27.
Sludge concentration dynamic distribution and its impact on the performance of UNITANK 总被引:2,自引:0,他引:2
UNITANK is a biological wastewater treatment process that combines the advantages of traditional activated sludge process and sequencing batch reactor, which is divided into Tank A, B and C. In this study, the sludge distribution and its impact on performance of UNITANK were carried out in Liede Wastewater Plant (WWTP) of Guangzhou, China. Results showed that there was a strong affiliation between Tank A and B of the system in sludge concentration distribution. The initial sludge concentration in Tank A could present the sludge distribution of the whole system. The sludge distribution was mainly influenced by hydraulic condition. Unsteady sludge distribution had an impact on variations of substrates in reactors, especially in decisive reactor, and this could lead to failure of system. Settler could partially remove substrates such as COD and NO3-N, but there was adventure of sludge deterioration. The rational initial sludge concentration in Tank A should be 4000-6000 mg/L MLSS. 相似文献
28.
基于对西北地区大开发的关键性难题与一些违背自然规律的不良倾向的讨论 ,认为大开发的实施需要在系统科学思维的基础上综合考虑资源—环境—经济的协调发展。近年来 ,许多科学家从各种角度揭示了我国西北乃至北半球中纬度地区持续干旱的发展规律 ,对干旱化趋势与水盐失衡的分析表明 ,西北地区气候干旱化将长期存在 ,生态将继续退化 ,这种趋势是人力不可抗拒的。人为活动尤其是水资源的开发利用 ,对土壤生态的影响是非常明显的 ,应该在严格控制水资源利用总量的前提下 ,调整用水格局 ,发展节水经济 ,科学确定社会经济用水和生态用水的比例 ,保证必须的生态用水 ,大力发展生态植被。指出在分析西北生态环境问题时过于强调人为活动而忽视自然因素作用的倾向 ,讨论了水库兴修、灌溉、土地利用与改良、深层水利用、水环境脆弱性等水资源—生态建设与可持续发展中的若干关键性问题 相似文献
29.
A highly resolved temporal and spatial air pollutant emission inventory for the Pearl River Delta region, China and its uncertainty assessment 总被引:31,自引:0,他引:31
Junyu Zheng Lijun Zhang Wenwei Che Zhuoyun Zheng Shasha Yin 《Atmospheric environment (Oxford, England : 1994)》2009,43(32):5112-5122
A highly resolved temporal and spatial Pearl River Delta (PRD) regional emission inventory for the year 2006 was developed with the use of best available domestic emission factors and activity data. The inventory covers major emission sources in the region and a bottom–up approach was adopted to compile the inventory for those sources where possible. The results show that the estimates for SO2, NOx, CO, PM10, PM2.5 and VOC emissions in the PRD region for the year 2006 are 711.4 kt, 891.9 kt, 3840.6 kt, 418.4 kt, 204.6 kt, and 1180.1 kt, respectively. About 91.4% of SO2 emissions were from power plant and industrial sources, and 87.2% of NOx emissions were from power plant and mobile sources. The industrial, mobile and power plant sources are major contributors to PM10 and PM2.5 emissions, accounting for 97.7% of the total PM10 and 97.2% of PM2.5 emissions, respectively. Mobile, biogenic and VOC product-related sources are responsible for 90.5% of the total VOC emissions. The emissions are spatially allocated onto grid cells with a resolution of 3 km × 3 km, showing that anthropogenic air pollutant emissions are mainly distributed over PRD central-southern city cluster areas. The preliminary temporal profiles were established for the power plant, industrial and on-road mobile sources. There is relatively low uncertainty in SO2 emission estimates with a range of −16% to +21% from power plant sources, medium to high uncertainty for the NOx emissions, and high uncertainties in the VOC, PM2.5, PM10 and CO emissions. 相似文献
30.
Long-range atmospheric transport of three toxaphene congeners across Europe. Modeling by chained single-box FATEMOD program 总被引:1,自引:1,他引:0
Jaakko Paasivirta Seija Sinkkonen Vladimir Nikiforov Fedor Kryuchkov Erkki Kolehmainen Katri Laihia Arto Valkonen Manu Lahtinen 《Environmental science and pollution research international》2009,16(2):191-205
Background, aims, and scope Since toxaphene (polychlorocamphene, polychloropinene, or strobane) mixtures were applied for massive insecticide use in the
1960s to replace the use of DDT, some of their congeners have been found at high latitudes far away from the usage areas.
Especially polychlorinated bornanes have demonstrated dominating congeners transported by air up to the Arctic areas. Environmental
fate modeling has been applied to monitor this phenomenon using parallel zones of atmosphere around the globe as interconnected
environments. These zones, shown in many meteorological maps, however, may not be the best way to configure atmospheric transport
in air trajectories. The latter could also be covered by connecting a chain of simple model boxes. We aim to study this alternative
approach by modeling the trajectory chain using catchment boxes of our FATEMOD model. Polychlorobornanes analyzed in biota
of the Barents Sea offered one case to study this modeling alternative, while toxaphene has been and partly still is used
massively at southern East Europe and around rivers flowing to the Aral Sea.
Materials and methods Pure model substances of three polychlorobornanes (toxaphene congeners P26, P50, and P62) were synthesized, their environmentally
important thermal properties measured by differential scanning calorimetry, as evaluated from literature data, and their temperature
dependences estimated by the QSPR programs VPLEST, WATSOLU, and TDLKOW. The evaluated property parameters were used to model
their atmospheric long-range transport from toxaphene heavy usage areas in Ukraine and Aral/SyrDarja/AmuDarja region areas,
through East Europe and Northern Norway (Finnmarken) to the Barents Sea. The time period used for the emission model was June
1997. Usual weather conditions in June were applied in the model, which was constructed by chaining FATEMOD model boxes of
the catchment’s areas along assumed maximal air flow trajectories. Analysis of the three chlorobornanes in toxaphene mixtures
function as a basis for the estimates of emission levels caused by its usage. High estimate (A) was taken from contents in
a Western product chlorocamphene and low estimate (B) from mean contents in Russian polychloroterpene products to achieve
modeled water concentrations. Bioaccumulation to analyzed lipid of aquatic biota at the target region was estimated by using
statistical calculation for persistent organic pollutants in literature.
Results The results from model runs A and B (high and low emission estimate) for levels in sea biota were compared to analysis results
of samples taken in August 1997 at Barents Sea. The model results (ng g−1 lw): 4–95 in lipid of planktovores and 7–150 in lipid of piscivores, were in fair agreement with the analysis results from
August 1997: 21–31 in Themisto libellula (chatka), 26–42 in Boreocadus saida (Polar cod), and 5–27 in Gadus morhua (cod) liver.
Discussion The modeling results indicate that the application of chained simple multimedia catchment boxes on predicted trajectory is
a useful method for estimation of volatile airborne persistent chemical exposures to biota in remote areas. For hazard assessment
of these pollutants, their properties, especially temperature dependences, must be estimated by a reasonable accuracy. That
can be achieved by using measurements in laboratory with pure model compounds and estimation of properties by thermodynamic
QSPR methods. The property parameters can be validated by comparing their values at an environmental temperature range with
measured or QSPR-estimated values derived by independent methods. The chained box method used for long-range air transport
modeling can be more suitable than global parallel zones modeling used earlier, provided that the main airflow trajectories
and properties of transported pollutants are predictable enough.
Conclusions Long-range air transport modeling of persistent, especially photo-resistant organic compounds using a chain of joint simple
boxes of catchment’s environments is a feasible method to predict concentrations of pollutants at the target area. This is
justified from model results compared with analytical measurements in Barents Sea biota in August 1997: three of six modeled
values were high and the other three low compared to the analysis results. The order of magnitude level was similar in both
modeled (planktovore and piscivore) and observed (chatka and polar cod) values of lipid samples. The obtained results were
too limited to firm validation but are sufficient to justify feasibility of the method, which prompts one to perform more
studies on this modeling system.
Recommendations and perspectives For assessment of the risk of environmental damages, chemical fate determination is an essential tool for chemical control,
e.g., for EU following the REACH rules. The present conclusion of applicability of the chained single-box multimedia modeling
can be validated by further studies using analyses of emissions and target biota in various other cases. To achieve useful
results, fate models built with databases having automatic steps for most calculations and outputs accessible to all chemical
control professionals are essential. Our FATEMOD program catchments at environments and compound properties listed in the
database represent a feasible tool for local, regional, and, according our present test results, for global exposure predictions.
As an extended use of model, emission estimates can be achieved by reversed modeling from analysis results of samples corresponding
to the target area.
This article is dedicated to the memory of Professor Alexander B Terentiev (who passed away in November 2006), our true friend.
With his Institute of Organo-Element Compounds, Russian Academy of Science, Moscow, he was an important main organizer of
the six joint Finnish–Russian seminars (every third year since 1989) on the field (‘Chemistry and Ecology of Organo-Element
Compounds’). He prompted us especially to search properties and environmental fates for various polyhalogen compounds. We
remember him for his friendly character and great sense of humor. 相似文献