Ammonia in the environment: from ancient times to the present

Recent research on atmospheric ammonia has made good progress in quantifying sources/sinks and environmental impacts. This paper reviews the achievements and places them in their historical context. It considers the role of ammonia in the development of agricultural science and air chemistry, showing how these arose out of foundations in 18th century chemistry and medieval alchemy, and then identifies the original environmental sources from which the ancients obtained ammonia. Ammonia is revealed as a compound of key human interest through the centuries, with a central role played by sal ammoniac in alchemy and the emergence of modern science. The review highlights how recent environmental research has emphasized volatilization sources of ammonia. Conversely, the historical records emphasize the role of high-temperature sources, including dung burning, coal burning, naturally burning coal seams and volcanoes. Present estimates of ammonia emissions from these sources are based on few measurements, which should be a future priority.     

Inventory of Interbasin Transfers in the United States

Interbasin transfers (IBTs) are man‐made transfers of water that cross basin boundaries. These transfers are used to distribute water resources according to supply and demand. The objectives of this work were to quantify the number of IBTs that exist in the United States (U.S.) and to examine the distribution of IBTs and potential causes associated with any observed clustering of IBTs. Defining “basin” was important to enable determination of which transfers qualify as “interbasin.” A variety of definitions are employed by states, with no federal definition. The most recent national studies of IBTs were conducted by the U.S. Geological Survey (USGS) in 1985 and 1986 using USGS Hydrologic Unit Code (HUC) definitions of basins. To build a 2016 inventory of IBTs in the U.S., and to identify where they most commonly occur, the USGS National Hydrography Database (NHD) was utilized in conjunction with the Watershed Boundary Dataset (WBD). Transfers across HUC6 basin boundaries were considered interbasin. Geographical information analysis with the NHD and WBD databases revealed that there are a total of 2,161 man‐made waterways crossing HUC6 basin boundaries in the U.S. IBTs are somewhat concentrated: Florida, Texas, and North Carolina account for over 50% of the total identified IBTs. For some states, identified IBTs are locally clustered. Analysis of these clusters suggests a variety of reasons that IBTs have been built, including population, drainage, and agricultural factors.     

Subgame-perfect cooperative agreements in a dynamic game of climate change

We model climate change as a dynamic game and prove existence of a unique subgame-perfect Nash equilibrium (SPNE) that is also Markov perfect. We interpret this unique SPNE as the business-as-usual (BAU) equilibrium and show that if the countries are not sufficiently symmetric then the familiar trigger strategy equilibria may not be Pareto improvements over the BAU equilibrium and may even lack efficiency properties. We then motivate and introduce a subgame-perfect cooperative agreement as an improvement over the BAU equilibrium in the sense that every country or coalition of countries is better off in every subgame, irrespective of the extent of heterogeneity of the countries. We characterize subgame-perfect cooperative agreements and identify sufficient conditions for their existence. We show that (direct or indirect) transfers between countries to balance the costs and benefits of controlling climate change are a necessity and not a matter of approach.     

Risk aversion and compliance in markets for pollution control

This paper examines the effects of risk aversion on compliance choices in markets for pollution control. A firm's decision to be compliant or not is independent of its manager's risk preference. However, non-compliant firms with risk-averse managers will have lower violations than otherwise identical firms with risk-neutral managers. The violations of non-compliant firms with risk-averse managers are independent of differences in their profit functions and their initial allocations of permits if and only if their managers' utility functions exhibit constant absolute risk aversion. However, firm-level characteristics do impact violation choices when managers have coefficients of absolute risk aversion that are increasing or decreasing in profit levels. Finally, in the equilibrium of a market for emissions rights with widespread non-compliance, risk aversion is associated with higher permit prices, better environmental quality, and lower aggregate violations.     

Effects of low concentration biodiesel blends application on modern passenger cars. Part 3: Impact on PAH, nitro-PAH, and oxy-PAH emissions

This study explores the impact of five different types of methyl esters on polycyclic aromatic hydrocarbon (PAH), nitrated-PAH and oxygenated PAH emissions. The measurements were conducted on a chassis dynamometer, according to the European regulation. Each of the five different biodiesels was blended with EN590 diesel at a proportion of 10-90% v/v (10% biodiesel concentration). The vehicle was a Euro 3 compliant common-rail diesel passenger car. Emission measurements were performed over the NEDC and compared with those of the real traffic-based Artemis driving cycles. The experimental results showed that the addition of biodiesel led to some important increases in low molecular-weight PAHs (phenanthrene and anthracene) and to both increases and reductions in large PAHs which are characterised by their carcinogenic and mutagenic properties. Nitro-PAHs were found to reduce with biodiesel whereas oxy-PAH emissions presented important increases with the biodiesel blends. The impact of biodiesel source material was particularly clear on the formation of PAH compounds. It was found that most PAH emissions decreased as the average load and speed of the driving cycle increased. Cold-start conditions negatively influenced the formation of most PAH compounds. A similar trend was observed with particulate alkane emissions.     

Flocculant in wastewater affects dynamics of inorganic N and accelerates removal of phenanthrene and anthracene in soil

Recycling of municipal wastewater requires treatment with flocculants, such as polyacrylamide. It is unknown how polyacrylamide in sludge affects removal of polycyclic aromatic hydrocarbons (PAH) from soil. An alkaline-saline soil and an agricultural soil were contaminated with phenanthrene and anthracene. Sludge with or without polyacrylamide was added while emission of CO₂ and concentrations of NH₄⁺, NO₃⁻, NO₂⁻, phenanthrene and anthracene were monitored in an aerobic incubation experiment. Polyacrylamide in the sludge had no effect on the production of CO₂, but it reduced the concentration of NH₄⁺, increased the concentration of NO₃⁻ in the Acolman soil and NO₂⁻ in the Texcoco soil, and increased N mineralization compared to the soil amended with sludge without polyacrylamide. After 112 d, polyacrylamide accelerated the removal of anthracene from both soils and that of phenanthrene in the Acolman soil. It was found that polyacrylamide accelerated removal of phenanthrene and anthracene from soil.     

An experimental analysis of compliance in dynamic emissions markets

Two important design elements for emission trading programs are whether and to what extent firms are able to bank emissions permits, and how these programs are to be enforced. In this paper we present results from laboratory emissions markets designed to investigate enforcement and compliance when these markets allow permit banking. Banking is motivated by a decrease in the aggregate permit supply in the middle of multi-period trading sessions. Consistent with theoretical insights, our experiments suggest that high permit violation penalties have little deterrence value in dynamic emissions markets, and that the main challenge of enforcing these programs is to motivate truthful self-reports of emissions.     

重庆市工业耗能相关碳排放变化驱动因素研究

在构建重庆市工业耗能相关碳排放影响因素分解模型的基础上,采用因素分解方法分析了过去十余年间(1999²011)4种驱动因素对重庆市工业碳排放变化的影响,并识别出关键驱动因素。结果显示:能耗增长的主要原因是工业经济发展;工业能源强度是促进重庆市工业耗能相关碳减排的主要影响因素;产业结构因素对重庆市工业耗能相关碳排放变化的影响存在波动,但其累积效果表现为减排;能源结构因素对重庆市工业耗能相关碳排放变化没有显著影响。最后,结合各关键因素的未来发展趋势,提出重庆市工业未来低碳发展的可行途径为技术进步和产业升级。     

Can environmental compensation contribute to socially equitable conservation? The case of an ecological fiscal transfer in the Brazilian Atlantic forest

ABSTRACT

Regions of high biodiversity often coincide with regions of poverty and conservation can imply economic and social costs for poor resident populations. Environmental compensation is considered a tool to reduce socio-environmental conflict, improve the equity of conservation and promote sustainable development. The intricacies of specific socio-ecological systems may determine how compensation payments are interpreted locally to produce outcomes. This research examines the social perceptions of an ecological fiscal transfer which intends to compensate the local public administration for the substantial costs of conservation in a hotspot of biological and social diversity in the Brazilian Atlantic forest. In this context we explore whether financial compensation (1) influences local perceptions of the conservation regime, (2) contributes towards the reconciliation of human-conservation conflicts and (3) triggers any meaningful socio-economic improvement that would counter the local costs of conservation. Results show that environmental compensation is not widely recognised as effectively benefiting the community. Local authorities consider compensation insufficient to enact a sustainable development agenda. Environmental compensation could play an important role in a policy mix for socially equitable conservation by being explicitly linked to community benefits, especially to fostering local livelihoods. The collaboration of actors operating across multiple governance levels may improve the institutional capacity of local actors to produce effective outcomes.     

Political influence on non-cooperative international climate policy

We analyze non-cooperative international climate policy in a setting of political competition by national interest groups. In the first stage, countries decide whether to link their domestic emission permit markets to an international market, which only forms if it is supported by all countries. In the second stage, countries non-cooperatively decide on the number of tradable emission allowances. In both stages, special interest groups try to sway the government in their favor. We find that (i) both the choice of regime and the levels of domestic and global emissions only depend on the aggregate levels of organized stakes in all countries and not on their distribution among individual interest groups and (ii) an increase in lobbying influence by a particular lobby group may backfire by inducing a change towards the lobby group's less preferred regime.