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11.
为提高炼油厂废水中氨氮化合物的去除效率.对生物曝气池活性污泥中的硝化菌群进行培养条件优化和并富集培养。实验结果表明,在pH值为8.0,28℃环境,150r/min振荡暗培养条件下,通过不断添加富集培养基,经过6周培养后,可使湿泥中硝化细菌的数量增加24.95倍/g,硝化速率提高2.76倍,达到了富集的目的。 相似文献
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金华市大气降水的化学组成特征及来源解析 总被引:3,自引:3,他引:3
对2004年大气降水样品监测资料的综合分析和研究表明,金华市降水样品pH值的分布范围在3.64~6.76之间,降水的酸雨率为79.3%。SO24-和NO-3是降水中主要的阴离子,分别占降水中阴离子总量的66.1%和21.7%。NH 4和Ca2 是降水中含量最高的阳离子,分别占阴离子总量的56.6%和33.4%。降水中这些离子的浓度水平一般比世界上其它地方高,但大大低于国内的北方地区。由于降水中缺乏足够的中和物质,大约76%的降水酸度被NH 4、Ca2 和K 等碱性成分中和。陆源型离子Ca2 、Mg2 和K 以及海盐性离子Na 和Cl-之间存在明显的相关关系,另外Ca2 和SO24-、Mg2 和SO24-、Mg2 和NO-3以及Mg2 和Cl-之间也可以观察到比较好的相关关系。土壤和海水的富集系数表明,研究区域的Ca2 和K 主要来源于岩石/土壤风化,SO24-和NO-3主要归因于人为活动的影响。 相似文献
14.
Concentration, size distribution, and dry deposition rate of particle-associated metals in the Los Angeles region 总被引:1,自引:0,他引:1
Jeong-Hee Lim Lisa D. Sabin Kenneth C. Schiff Keith D. Stolzenbach 《Atmospheric environment (Oxford, England : 1994)》2006,40(40):7810-7823
Daily averaged atmospheric concentrations and dry deposition fluxes of particulate metals were measured seasonally at six urban sites and one non-urban coastal site in the Los Angeles region using a conventional total suspended particulate matter (TSP) filter, surrogate surface deposition plates, and a Noll Rotary Impactor (NRI), which provides information about particle size distribution in four size ranges above 6 μm. With the exception of the non-urban site, particulate metal concentrations and deposition fluxes were remarkably uniform spatially and temporally. At all sites there were significant metal concentrations on particles greater than 10 μm, a commonly used upper limit for many air quality monitoring studies, and these large particles were estimated to be responsible for most of the deposited mass of metals. Annual averaged values of deposition rates measured with a surrogate surface were in good agreement with values estimated using theoretical deposition velocities in conjunction with measured size-segregated particle concentrations. Image analysis of particles deposited on NRI stage A, which collects all particles greater than 6 μm, indicated nighttime metal concentrations and deposition at the non-urban coastal site was higher than in the day time due to offshore advection of urban air associated with the diurnal land breeze. Measured enrichments of crustal elements and metals were correlated, indicating efficient mixing of natural and anthropogenic material from different sources, hypothesized to be the result of cyclical resuspension and deposition of dust by moving vehicles and wind. 相似文献
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本文介绍了大气中微量汞的一种监测方法,利用汞富集解析器富集大气中的微量汞.解析后用冷原子吸收法测定.研究了FJ-1型汞富集解析器与WYX-405原子吸收分光光度计联用的工作条件,相对标准偏差为1.7%. 相似文献
17.
González-Macías C Schifter I Lluch-Cota DB Méndez-Rodríguez L Hernández-Vázquez S 《Environmental monitoring and assessment》2007,133(1-3):187-207
Concentrations of total aromatic hydrocarbons and extractable organic matter in the water column and sediment were determined
in samples collected in the course of the last 20 years from the Salina Cruz Harbor, México, to assess the degree of organic
contamination. In sediments, organic compounds accumulate in shallow areas mostly associated with extractable organic matter
and fine fractions. Calculated geocumulation index and enrichment factors suggest that contamination could be derived from
anthropogenic activities attributed to harbor and ship scrapping activities, as well as transboundary source. Concentration
of total aromatic hydrocarbons (as chrysene equivalents) ranged from 0.01 to 534 μg l−1 in water, and from 0.10 to 2,160 μg g−1 in sediments. Total aromatic concentration of 5 μg g−1 is proposed as background concentration. 相似文献
18.
Panichayapichet P Nitisoravut S Simachaya W 《Environmental monitoring and assessment》2007,135(1-3):181-193
The aim of this study was to investigate the spatial distribution of heavy metal in soil and evaluate the dissolution of metal
from soil to ponded-surface water, leaching through soil profiles and metal uptake in grass as related to different land-use
practices. The data provided a scientific basis for best-management practices for land use in Khli Ti watershed. The watershed
has a Pb-contamination problem from the previous operation of a Pb-ore concentrator and abandoned Zn–Pb mine. Sampling sites
were selected from a land-use map, with land-use types falling into the following four categories: forest, agricultural land,
residential area and road. Soil, ponded-surface water, grass samples and soil profiles were collected. The study related soil
characteristics from different land-use practices and locations with observed metal concentrations in ponded-surface water
and soil. High enrichment factors of Pb and As in soil were found. Partitioning coefficient, Kd values were in the order: Cr > Pb > Ni > Cu > Cd > Zn. Soil disturbance from land-use activities including tillage and traffic
increased leaching of trace metal from soils. Pb in soil was significantly taken up by grass even though the Transfer Factor,
TF values were rather low. Agricultural activities in the watershed must be limited. Moreover, land encroachments in the upper
and middle part of the watershed which have high potential of Pb must be strictly controlled in order to reduce the Pb contamination
from non-point sources. 相似文献
19.
典型电子垃圾拆解区大气颗粒物中元素污染的季节变化特征 总被引:3,自引:0,他引:3
分别在典型电子垃圾拆解区(E)和其参考区(S)采集了大气总悬浮颗粒物(TSP)样品,利用等离子体电感耦合质谱(ICP-MS)检测了13种元素。结果表明,E地区大气TSP中各元素含量均高于对照区,特别是污染元素Zn、Cu、Cd、Sn和Pb。E地区和S地区TSP中元素质量浓度的季节变化趋势相似,TSP中地壳元素质量浓度夏季高于冬季,而污染元素冬季高于夏季。E地区和S地区TSP中Cu、Zn、Sn和Pb的富集因子(EF)100,E地区EF值高于对照区,说明这些元素主要来源于电子垃圾处理过程;而Mg、K、Ca、Ti、V、Mn、Fe、Co和Cd的EF值为1~10,说明元素主要为自然来源。 相似文献
20.
纳米材料在痕量重金属离子测定中的应用 总被引:2,自引:2,他引:0
介绍了纳米材料的吸附性能,评述了影响其分离富集重金属离子效果的主要因素,综述了纳米金属氧化物、碳纳米管及其他纳米材料在痕量重金属离子测定中的应用进展,提出提高纳米吸附材料的选择性和稳定性,开发便携式商品化的纳米材料萃取小柱是今后的发展方向. 相似文献