环境监理运行模式初探

围绕环境监理的基本职责 ,对捆绑式、专一式、切块式 3种不同的环境监理运行模式进行了探讨。提出切块式环境监理运行模式比较适合现阶段环境监理工作 ,是一种值得推广的环境监理运行模式。     

Artificial neural network based carbon monoxide persistence models for episodic urban air quality management

This paper describes the development of artificial neural network (ANN) based carbon monoxide (CO) persistence (ANNCOP) models to forecast 8-h average CO concentration using 1-h maximum predicted CO data for the critical (winter) period (November–March). The models have been developed for three 8-h groupings of 10 p.m. to 6 a.m., 6 a.m. to 2 p.m. and 2–10 p.m., at two air quality control regions (AQCRs) in Delhi city, representing an urban intersection and an arterial road consisting heterogeneous traffic flows. The result indicates that time grouping of 2–10 pm is dominantly affected by inversion conditions and peak traffic flow. The ANNCOP model corresponding to this grouping predicts the 8-h average CO concentrations within the accuracy range of 68–71%. The CO persistence values derived from ANNCOP model are comparable with the persistence values as suggested by the Environmental Protection Agency (EPA), USA. This work demonstrates that ANN based model is capable of describing winter period CO persistence phenomena.     

净水厂氯气泄漏的环境风险分析

以丹阳净水厂为例,选取大气非正常排放模式,预测了液氯钢瓶阀门泄漏及爆炸对周围环境和保护目标的影响,并模拟了钢瓶爆裂事故的后果,计算出事故发生时的初始警戒区半径,提出了相应的氯气泄漏防范措施。     

The Role of Abatement Costs in GHG Permit Allocations: A Global Stabilization Scenario Analysis

Our objective is to propose permit allocation schemes that lead to a fair distribution of the net abatement cost among regions in a global greenhouse gas (GHG) stabilization scenario. We use a detailed technology-based energy model, World-MARKAL, to determine efficient abatement decisions, and to calculate the regional gross abatement costs (before permit allocation and trading). The net abatement costs are then calculated and used for different permit allocation schemes.     

Coupling upland watershed and downstream waterbody hydrodynamic and water quality models (SWAT and CE-QUAL-W2) for better water resources management in complex river basins

Effective water resources management programs have always incorporated detailed analyses of hydrological and water quality processes in the upland watershed and downstream waterbody. We have integrated two powerful hydrological and water quality models (SWAT and CE-QUAL-W2) to simulate the combined processes of water quantity and quality both in the upland watershed and downstream waterbody. Whereas the SWAT model outputs water quality variables in its entirety, the CE-QUAL-W2 model requires inputs in various pools of organic matter contents. An intermediate program was developed to extract outputs from SWAT at required subbasin and reach outlets and converts them into acceptable CE-QUAL-W2 inputs. The CE-QUAL-W2 model was later calibrated for various hydrodynamic and water quality simulations in the Cedar Creek Reservoir, TX, USA. The results indicate that the two models are compatible and can be used to assess and manage water resources in complex watersheds comprised of upland watershed and downstream waterbodies.     

Hydrologic–Economic Model for Managing Irrigation Intensity in Irrigation Areas under Watertable and Soil Salinity Targets

This paper gives mathematical details and sample applications of SWAGMAN Farm (SWAGMAN, Salt Water and Groundwater Management), a farm-scale hydrologic economic model that integrates agronomic, climatic, irrigation, hydrogeological and economic aspects of irrigated agriculture. The model is capable of determining optimum mix of land use to keep watertable and soil salinity within acceptable limits while maximising the economic returns. Alternatively, the model can simulate water and salt balance and economics of a given cropping preference. Web-based and Geographic Information Systems versions of the model are available for integration with the environmental reporting systems of the irrigation areas.     

Optimal Selection of Priority Development Areas Considering Tradeoffs Between Hydrology and Development Configuration

Mixed-integer linear programs are proposed for siting development and conservation areas in watersheds, addressing economic objectives (development perimeter and proximity) and ecological objectives. Links between watershed hydrology and ecology need not be well defined. Parameters for the linear programs are obtained from linearization of the SWAT hydrologic model.     

Modeling Acidification Recovery on Threatened Ecosystems: Application to the Evaluation of the Gothenburg Protocol in France

To evaluate the acid deposition reduction negotiated for 2010 within the UNECE LRTAP Gothenburg Protocol, sulphur and nitrogen deposition time-series (1880–2100) were compared to critical loads of acidity on five French ecosystems: Massif Central basalt (site 1) and granite (2); Paris Bassin tertiary sands (3); Vosges mountains sandstone (4) and Landes eolian sands (5). The SAFE model was used to estimate the response of soil solution pH and ratio to the deposition scenario. Among the five sites, critical loads were exceeded in the past at sites 3, 4 and 5. Sites 3 and 4 were still expected to exceed in 2010, the Protocol year. Further reduction of atmospheric deposition, mainly nitrogen, would be needed to achieve recovery on these ecosystems. At sites 3, 4 and 5, the delay between the critical load exceedance and the violation of the critical chemical criterion was estimated to be 10 to 30 years in the top soil and 50 to 90 years in the deeper soil. At site 5, a recovery was expected in the top soil in 2010 with a time lag of 10 years. Unexpectedly, soil pH continued to decrease after 1980 in the deeper soil at sites 2 and 5. This time lag indicated that acidification moved down the soil profile as a consequence of slow base cation depletion by ion exchange. This delayed response of the soil solution was the result of the combination of weathering rates and vegetation uptake but also of the relative ratio between base cation deposition and acid compounds.     

Modified Fenton reaction for trichlorophenol dechlorination by enzymatically generated H2O2 and gluconic acid chelate

Glucose oxidase is a well-known enzyme that catalyzes the oxidation of β-d-glucose to produce gluconic acid and hydrogen peroxide. Fenton reaction is a powerful oxidation technology used for the oxidation of groundwater pollutants. For the application of Fenton reaction in groundwater remediation, successful operation of Fenton reaction near neutral pH, and on-site generation of both H₂O₂ and chelate will be beneficial. The focus of this experimental study was to couple the glucose oxidation reaction with chelate-based Fenton reaction. The idea was to use the hydrogen peroxide and chelate gluconic acid generated during glucose oxidation for the dechlorination of 2,4,6-trichlorophenol (TCP) by Fenton reaction. The oxidation of glucose was achieved using the enzyme in free and immobilized forms. The rate of production of hydrogen peroxide was determined for each system, and was used to estimate the time required for complete consumption of glucose during the process, thus avoiding any traces of glucose in the Fenton reaction. In the case of free enzyme reaction, separation of the enzyme was achieved using an ultrafiltration membrane before initiating the Fenton reaction. The oxidation of TCP by Fenton reaction was performed at varying ratios of gluconic acid/Fe, and its effect on the decomposition of TCP and H₂O₂ was studied. TCP degradation was studied both in terms of parent compound degradation and free chloride generation.