燃煤高温固硫的机理及固硫影响因素探讨

燃烧中固硫是一种适合我国国情的燃煤脱硫技术。本文探讨了燃煤高温固硫过程的主要反应机理和一些常用固硫添加剂的助固硫作用,分析了影响固硫效率的主要因素,进而提出实际应用中应考虑的提高固硫效率的措施。     

基于因子分析的电缆烟气毒性评估

<正>火灾条件下电缆燃烧烟气的毒性分析对于电缆火灾安全研究非常重要。为了研究典型电缆燃烧烟气的组分及毒性大小定量,通过搭建试验装置并进行实验研究。对采集的实验数据采用FED模型进行了烟气的毒性评价,并进一步采用因子分析法对组分烟气数据进行分析。分析结果表明,基于因子分析法的烟气毒性评价方法与FED模型分析结果趋于一致,但此方法可以揭示出更多有用信息用以指导电缆火灾危险性评价。研究为电缆燃烧烟气的毒性效应评价提出了一种新的思路。     

Atmospheric Aerosol over a Southeastern Region of Texas: Chemical Composition and Possible Sources

Speciated samples of PM_2.5 were collected at a site in Jefferson County, Texas by US EPA (Environmental Protection Agency) from July of 2003 to August of 2005. A total of 269 samples with 52 species were measured; however, 22 species were excluded in this study because of too many below-detection-limit data. The data set was analyzed by positive matrix factorization (PMF) to infer the sources of PM observed at the site. The analysis identified ten sources: sulfate-rich secondary aerosol I (35.9%), sulfate-rich secondary aerosol II (21.0%), cement/carbon-rich (11.7%), wood smoke (8.8%), metal processing (6.3%), motor vehicle/road dust (5.7%), nitrate-rich secondary aerosol (3.3%), soil (3.2%), sea salt (2.6%), and chloride depleted marine aerosol (1.6%). Sulfate and nitrate mainly exist as salts. The two sulfate-rich secondary aerosols account for almost 57% of the PM_2.5 mass concentration. The factor containing highest concentrations of Cl and Na was attributed to sea salt due to the proximity of the monitoring site to the Gulf of Mexico. The chloride depleted marine aerosol was related to the sea salt aerosol. Cement/carbon-rich, wood smoke, metal processing, and motor vehicle/road dust factor were likely to be the local sources.     

Assessment of the spring water quality in The Shoubak area,Jordan

The present study investigates the physical, chemical, and biological characteristics of spring water samples in Shoubak area in the southern Jordan. The samples were collected from May 2004 to May 2005. All samples were analyzed for temperature, conductivity, dissolved oxygen, pH, major cations (Ca²⁺, Mg²⁺, K⁺, Na⁺), major anions (Cl⁻, NO₃⁻, HCO₃⁻, SO₄²⁻, PO₄³⁻, F⁻), and trace metals (Fe²⁺, Al³⁺, Mn²⁺, Cu²⁺, Cr³⁺, Ni²⁺, Zn²⁺, Pb²⁺, Cd²⁺). Water quality for available springs showed high salinity through long period of contact with rocks. The ion concentrations in the water samples were from dissolution of carbonate rocks and ion exchange processes in clay. The general chemistry of water samples was typically of alkaline earth waters with prevailing bicarbonate chloride. Some springs showed elevated nitrate and sulfate contents which could reflect to percolation from septic tanks, cesspools, and agricultural practices. The infiltration of wastewater from cesspools and septic tanks into groundwater is considered the major source of water pollution. The results showed that there were great variations among the analyzed samples with respect to their physical, chemical and biological parameters, which lie below the maximum permissible levels of the Jordanian and WHO drinking water standards. The results indicate that the trace metals of spring’s water of Shoubak area do not generally pose any health or environmental problems. Factor analysis was used to identify the contributers to water quality. The first factor represents major contribution from anthropogenic activities, while the second one represents major contribution from natural processes.     

An Interpretation of the Influential Power of China Development

Through the analysis on China’s economic development, utilization of resource environment and soft power, a basic judgment was made of the influence of "China development". The overall influential power of China development on international community was misunderstood. What we see is the role of "China Factor" in different fields. In the process of economic globalization, what economic system of capitalist market has seen is "China’s cheap labor", "China’s loose economic system environment", "earlier abuse of unlimited resource environment", "China’s broad consumption market" and "demographic dividend". In global or Asian financial crisis, what other countries valued was China’s "foreign currency" accumulated over the years. In global governance or crisis management, what international community expected was "China’s obligations and responsibilities" without the right of speech, etc.. All these are the "passive" roles produced by "a single factor" in definite fields. The active and initiative role China will play in international community still needs time and the continuous efforts of several generations. China once was a big country that had significant influential power on the world, and China’s renaissance is a normal process of development of things. What excessive talks about its influential power reflect may be the lack of China’s influence.     

影响强化生物除磷的关键因素研究进展

磷已经成为引起水体富营养化的关键控制因子之一。本文对影响生物除磷效果的关键因素的研究进展进行了分析,并对在生物除磷研究过程中出现的问题作了说明。     

Hydrogeochemistry and Groundwater Quality Assessment of Lower Part of the Ponnaiyar River Basin, Cuddalore District, South India

The Lower Ponnaiyar River Basin forms an important groundwater province in South India constituted by Tertiary formations dominated by sandstones and overlain by alluvium. The region enjoyed artesian conditions 50 years back but at present frequent failure of monsoon and over exploitation is threatening the aquifer. Further, extensive agricultural and industrial activities and urbanization has resulted in the increase in demand and contamination of the aquifer. To identify the sources and quality of groundwater, water samples from 47 bore wells were collected in an area of 154 km² and were analysed for major ions and trace metals. The results reveal that the groundwater in many places is contaminated by higher concentrations of NO₃, Cl, PO₄ and Fe. Four major hydrochemical facies Ca–Mg–Cl, Na–Cl, Ca–HCO₃ and Na–HCO₃ were identified using Piper trilinear diagram. Salinity, sodium adsorption ratio, and sodium percentage indicate that most of the groundwater samples are not suitable for irrigation as well as for domestic purposes and far from drinking water standards. The most serious pollution threat to groundwater is from nitrate ions, which are associated with sewage and fertilizers application. The present state of the quality of the lower part of Ponnaiyar River Basin is of great concern and the higher concentration of toxic metals (Fe and Ni) may entail various health hazards.     

Exploring the need for more radical sustainable innovation: what does it look like and why?

It has been argued in recent years that Western economies need to increase their resource productivity by 90% over the next 50 years. This is a radical aim. This paper draws on design for sustainability (DfS) thinking to scope interventions that encourage greater levels of resource productivity through reconfiguring concepts of growth and well‐being within organisational strategies, structures, systems, processes and outputs. Based on research from a UK EPSRC funded project Design Dialogues (2005–2008), this paper links together sustainable design and innovation literatures and dialogue‐based primary research that together inform the development of an approach to innovation for sustainability. The emphasis on sustainable innovation is to understand what is designed (the outputs of business) and why (the inputs: the values, beliefs, visions and objectives) within a context of ecological limits. The foundations of this approach are introduced here in order to demonstrate the potential to provoke a new way of thinking about longer‐term organisational innovation through making explicit the intrinsic connections between natural and human capitals. This paper explores the need to think differently in order to create sustainability and presents the outcome of this research: a methodology for innovation for sustainability.     

A composite receptor and dispersion model approach for estimation of effective emission factors for vehicles

It is difficult to estimate vehicular emission factors at traffic junctions for use in dispersion modelling studies. Firstly, because the vehicles are in various modes of operation and secondly, it is difficult to delineate the effects of other contributing sources, mainly the effects of road dust and deposited constituents, which are very prominent at traffic junctions in India. Factor analysis-multiple regression (FA-MR), a receptor modelling technique has been used in this study for apportioning the contributing sources. The measurement data consist of one year's temporal variation of suspended particulate matter (SPM), analysed for its trace metal constituents, and two gaseous components NO₂ and SO₂ at two traffic junctions in Mumbai (India). FA-MR apportioned 40% of the observed SPM to road dust and 15% to vehicular sources. Of the total Pb observed in the SPM, FA-MR apportioned 60% to vehicular sources and 20% to road dust. The field-observed vehicular counts, meteorological parameters and road geometry were used in California line source dispersion model to estimate the effective vehicular emission factor for Pb at one traffic junction. This derived emission factor was used to predict the Pb concentration at second (independent observation) traffic junction. The result was found to be more satisfactory than using default emission factors obtained from literature. Similarly, effective vehicular emission factor for NO₂ was also evaluated for one site and tested for predicting concentrations at the other site.     

矿区周边土壤重金属污染治理的优势植物筛选——以关中西部某铅锌冶炼区为例

通过对关中西部某铅锌冶炼区周边实地调查、采样和室内样品分析,采用原子吸收分光光度计测定铅锌冶炼区周边地区长势良好的13种优势植物对Pb、Zn、Cd、Cr、Cu、Ni的吸收与富集能力及其富集特征。结果表明,矿区土壤均受到Pb、Zn、Cd 3种重金属的污染,13种植物体内的Pb、Zn、Cd的含量比正常植物的含量高出数倍,白蒿、蒲公英、播娘蒿、牛舌草和秃疮花这5种植物对于Pb、Zn、Cd这3种重金属的转移系数均大于1,从植物体内重金属含量、转运系数和富集系数3个指标来看,白蒿和蒲公英可作为首选的2种先锋植物。此结果为利用本土植物治理铅锌矿区土壤重金属污染提供一定的参考依据。