葫芦岛有色金属集团废气治理对环境空气质量的影响

在研究分析葫芦岛有色金属集团近年来废气治理情况的基础上,根据葫芦岛市工业区环境空气质量监测数据,通过环境空气综合污染指数评价和Spearman秩相关系数评价,分析了废气治理对环境空气质量的影响.     

水解(酸化)工艺预处理难降解有机废水应用技术分析

本文对水解(酸化)工艺进行了原理分析,论述了该工艺的优缺点,以及对后续工艺的影响.分析论述了该工艺对几种典型的难降解有机废水的降解机理.认为水解(酸化)作为难降解有机废水的预处理工艺具有很高的推广应用价值.     

Metal chlorides loaded on activated carbon to capture elemental mercury

Activated carbon (AC) was considered to be an effective sorbent to control mercury in combustion systems. However, its capture capacity was low and it required a high carbon-to-mercury mass ratio. AC loaded with catalyst showed a high elemental mercury (Hg0) capture capacity due to large surface area of AC and high oxidization ability of catalyst. In this study, several metal chlorides and metal oxides were used to promote the sorption capacity of AC. As a result, metal chlorides were better than metal oxides loaded on AC to remove gaseous mercury. X-ray diffractometer (XRD), thermogravimetric analyzer (TGA) and specific surface area by Brunauer- Emmett-Teller method (BET) analysis showed the main mechanisms: first, AC had an enormous surface area for loading enough MClx; second, Cl and MxOy were generated during pyrogenation of MClx; finally, there were lots of active elements such as Cl and MxOy which could react with elemental mercury and convert it to mercury oxide and mercury chloride. The HgO and HgCl2 might be released from AC’s porous structure by thermo regeneration. A catalytic chemisorption mechanism predominates the sorption process of elemental mercury. As Co and Mn were valence variable metal elements, their catalytic effect on Hg0 oxidization may accelerate both oxidation and halogenation of Hg0. The sorbents loaded with metal chlorides possessed a synergistic function of catalytic effect of valence variable metal and chlorine oxidation.     

CSTR系统发酵产氢细菌群落动态与产氢能力关系解析

将CSTR系统内pH由4.2一次性提高至6.0左右,启动发酵类型的转化,研究了转化过程系统内的产氢动态和细菌群落.结果表明,在有机负荷维持在（33±1）kg/(m³·d)的情况下,发酵类型10 d内未发生改变,产氢量8 d内未降低,15 d后系统内种群由乙醇型转化为丁酸型,进水碱度由250 mg/L增至2 450　mg/L.研究中利用荧光原位杂交技术（FISH）对反应系统内3类微生物群进行监测发现,在转化过程中Clostridium cluster XI数量增加,Clostridium cluster Ⅰ 和Ⅱ数量减少,而Enterobacteriaceae始终存在,变化不明显.种群的消长同反应系统产氢能力的高低存在密切关联,以Clostridium cluster Ⅰ和Ⅱ占优势的乙醇型发酵具有更佳的产氢能力,平均比产氢速率为23.6 mol/(kg·d).     

深圳市清水河垃圾焚烧厂周围地区优势植物的汞污染研究

为研究垃圾焚烧厂对周围植物的汞污染状况,分析了深圳市清水河垃圾焚烧厂周围优势植物茎叶以及土壤的总汞浓度.结果表明,该垃圾焚烧厂周围的优势植物均受到一定程度的汞污染,叶总汞浓度为0.0309~0.2467 mg.kg-1,平均值为0.0948 mg.kg-1,所选择的6种优势植物叶总汞的浓度:台湾相思豺皮樟马占相思大叶相思木荷梅叶冬青;茎总汞浓度为0.0074~0.1196 mg.kg-1,平均值为0.0417 mg.kg-1.同种植物茎叶总汞浓度呈显著正相关,而植物茎叶的总汞浓度与土壤总汞浓度并无显著相关性;在该垃圾焚烧厂主导风向的下风向,距污染源的距离和地形差异共同对烟气扩散浓度产生影响,而植物茎叶总汞浓度变化则与烟气扩散浓度的空间分异格局基本吻合.上述结果充分证明,本研究区内烟气-叶的交互作用在植物与环境的汞交换中占据主导地位.     

全程高温好氧堆肥快速降解城市生活垃圾

为了提高堆肥处理城市生活垃圾（MSW）的速率和质量,设计了一种外加热源的全程高温好氧堆肥工艺.实验以全程高温好氧堆肥和传统好氧堆肥两种方法对MSW进行了60d的堆肥处理.同时,监测了堆肥的pH和温度等参数的变化情况,并以C/N、种子发芽率(GI)、可溶性有机碳(DOC)、比好氧速率(SOUR)和脱氢酶（DH-ase）活性为指标评价了堆肥的腐熟度和质量.结果表明,全程高温堆肥法和传统堆肥法的堆肥周期分别为16d和28d,两种方法得到的产品其pH值均在7左右.在第31d将全程高温堆肥产品置于30℃恒温箱时,其理化性质没有出现明显波动,说明其堆肥产品性质稳定.因此,全程高温好氧堆肥法能明显缩短堆肥周期、提高堆肥质量,具有很大的应用潜力.     

废弃钻井液固化处理pH值控制措施

提出了在原有固化处理技术的基础上,根据钻井泥浆原样pH值的高低,在固化材中适量加入酸性盐类混凝剂有效控制pH值的方法。采用此方法后,废弃钻井液的固化处理效果好,能够满足环保标准要求。     

高寒地区露天矿排土场稳定性分析研究*

为分析高寒地区露天排土场稳定性,以乌努格吐山铜钼矿排土场为工程背景,结合室内试验并利用GeoStudio及FLAC3D软件对边坡进行模拟计算分析,给出边坡治理有效措施。结果表明:前3次冻融循环对散体物料的抗剪强度影响显著,后期影响则趋于稳定;6个剖面的安全系数普遍大于1.2,在地下水的干扰下,各剖面安全系数普遍下降,尤其是剖面E-E,其安全系数低于1,存在滑坡风险;水对边坡的安全性影响较大,其次提出削坡治理及布置抗滑桩措施,当边坡角度削减至31°时,边坡的安全系数增至为1.383;抗滑桩增至8根时,安全系数增加至1.296,这些措施对边坡的治理皆起到积极作用。研究结果可为高寒地区矿山安全开采提供技术支持。     

Comparison of energy produced from waste by removing its different components: A case study of the waste landfill in Tehran

In developing and populated cities such as Tehran, a massive amount of municipal solid waste (MSW), both wet and dry, is transferred to landfills daily. Combustion is one of the most common methods of using mixed waste energy from the past to the present. The Dulong formula is widely used to calculate the energy released from MSW combustion. According to the constituent components of Tehran MSW, removing food waste leads to an increase in energy potential, which will be a suitable condition for energy production. In this work, the energy derived from the combustion of mixed and separated dry MSW generated in Tehran was calculated using the experimental Dulong formula and tables in Integrated Solid Waste Management (Tchobanoglous et al. 1993, McGraw‐Hill). The Dulong formula indicates that the use of Tehran mixed MSW (without separating materials for recycling) as a fuel source yields 8,966.40 KJ/kg while the use of Tchobanoglous et al. (1993) tables can generate 8,236 kJ/kg. By removing food waste and recyclable materials, the potential of energy production changes to 22,047 kJ/kg using the Dulong formula and 16,207 kJ/kg and the Tchobanoglous et al. (1993) tables. It indicates increase by 1.46 times and 46%, respectively. Regarding the 200‐ton capacity of the Tehran waste incinerator, the Dulong formula indicated generation of 4,409 MJ/day energy, and the Tchobanoglous et al. table presents 3,241 MJ/day. Therefore, considering that Tehran generates more than 4,000 tons of reject waste daily, it can easily be converted to energy rather than landfilled. This can alleviate the problem of buying land and construction of landfills and leachate generation.     

废弃液晶屏玻璃基板的行星式球磨工艺研究

以废弃液晶屏玻璃基板为原料,研究了球磨方式和球磨时间在球磨过程中对粉料粒径分布的影响。通过对废弃液晶屏玻璃基板的行星式球磨工艺的研究,探讨了球磨方式、球磨时间等因素对球磨效果的影响,以建立玻璃粉体细化的合理球磨方式和工艺参数。