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81.
在Ti(Ⅳ)和过氧化氢存在条件下,考察了臭氧化酸性苯乙酮溶液、硝基苯溶液和垃圾渗滤液(浙江衢州某垃圾填埋场)的预处理效能。结果表明,在pH2.86条件下,单独臭氧化处理对苯乙酮、硝基苯和垃圾渗滤液的COD去除率分别为10.1%、44%和28.6%。BOD,/COD值分别从原来的0.039、0.060和0.085提高到了0.130、0.158和0.174,仍属生化难降解废水。当体系加入Ti(Ⅳ)后,臭氧化苯乙酮和硝基苯的COD去除率分别达到了75.5%和65%,BOD;/COD则提高到了0.679和0.314,可生化性提升明显。对于垃圾渗滤液,只有当体系加入Ti(Ⅳ)和H22后,臭氧化COD的去除率达到66.6%,BOD、/COD提高至0.425。上述结果对酸性难降解废水的处理实际意义非常突出。 相似文献
82.
橡胶促进剂M盐废水生物处理技术研究 总被引:1,自引:0,他引:1
为探讨微生物技术在橡胶促进剂M盐废水处理中的应用,利用高效优势蘸强化A2O工艺对橡胶促进剂M盐废水进行处理,整个系统运行过程分为污泥的培养与驯化阶段及稳定运行阶段。在稳定运行阶段COD0平均去除率达90.71%,氨氮平均去除率达78.31%。以Mn^2+、Fe^2+、Mg^2+、Ni^2+为4个影响因子,通过正交实验分析无机离子对橡胶促进剂M盐废水中有机物降解的促进作用。由实验数据的摄差大小可知,各无机离子对优势复合菌降解橡胶有机废水的影响从大到小依次为:Mn^2+、Fe^2+、Ni^2+和Mg^2+。4种离子最佳质量浓度组合为:0.500mg/L的Mn^2+、1.00mg/L的Fe^2+、35.0mg/L的Mg^2+和0.025mg/L的Ni^2+。 相似文献
83.
介绍了阜康冶炼厂无污染新工艺和环境治理的有关情况 ,从理论上阐述了无污染工艺和污水治理的技术原理 ,对有色金属冶炼工业逐步采用湿法精炼清洁工艺有一定的指导作用 相似文献
84.
Satoru Fujita Kenzi Suzuki Yasuo Shibasaki Toshiaki Mori 《Journal of Material Cycles and Waste Management》2002,4(1):70-76
Hydrogarnet was synthesized hydrothermally below 200°C using molten slag obtained from municipal solid waste. For comparison,
it was also synthesized using pure-phase CaO–Al2O3–SiO2–H2O, as reported previously. The structural and textural properties of this material were investigated using various analytical
and spectroscopic techniques such as X-ray diffraction, X-ray fluorescence spectrometry, atomic absorption spectrometry (AAS),
thermogravimetry/differential thermal analysis, Fourier transform infrared spectroscopy, and scanning electron microscopy.
The Cl− fixation ability of hydrogarnet was investigated in the temperature range 500–800°C in a fixed-bed flow reactor using a HCl
concentration (1000 p.p.m.v.) similar to that of incinerator exhaust gas. Under these experimental conditions, the hydrogarnet
was capable of reducing the HCl gas level to less than 1 p.p.m.v. Analysis of the spent catalyst revealed that the hydrogarnet
was being transformed into wadalite and CaCl2 at high temperatures. The elution test for chromium ions in hydrogarnet obtained from slag was also used, and it was found
that chromium ions were not eluted from hydrogarnet.
Received: January 27, 2001 / Accepted: October 11, 2001 相似文献
85.
石脑油罐硫铁化合物自燃原因分析 总被引:4,自引:0,他引:4
刘同华 《中国安全科学学报》2002,12(4)
对一起石脑油罐硫化铁化合物自燃事故的经过和原因进行了分析 ,推断出发生在石脑油罐硫铁化合物自燃并非为FeS自燃 ,并提出了预防同类事故的防范措施。 相似文献
86.
城市土地资产经营新思路探讨 总被引:5,自引:0,他引:5
康雄华 《中国人口.资源与环境》2003,13(4):60-63
自1996年上海市成立第一家土地收购储备机构——土地发展中心后,全国各大城市已纷纷效仿它的成功经验。截止2001年8月不完全统计,全国已有大小不同的土地收购储备机构669家。实践证明,土地收购储备机制在盘活城市存量土地,促进土地集约利用,保障城市土地资产的保值增值等方面成绩卓著。然而,实践过程中,土地收购储备机制的运作也暴露出不少问题。本文通过对这些问题的分析,提出了引进公司制度完善土地收购储备机制,合理运营城市土地资产的新思路。 相似文献
87.
88.
Joseph A. Laszlo 《Journal of Polymers and the Environment》1998,6(2):73-78
Quaternized, crosslinked sugarcane bagasse can adsorb anionic dyes from textile wastewater. Disposal of dye-saturated adsorbent by composting or land application would require that modifications made to the bagasse do not interfere with its decomposition. The impact of quaternization and crosslinking on bagasse biodegradability was examined. Bagasse in varying states of modification was mixed with soil and monitored for carbon dioxide evolution for four weeks at 27°C. After subtracting the amount of carbon evolved from control soil samples, the net carbon evolved from the bagasse samples was determined and used as a measure of their extent of biodegradation. Biodegradability decreased in the order: bagasse (approx. 60% degraded after four weeks) > quaternized bagasse > quaternized, epichlorohydrin-crosslinked bagasse > quaternized, methylene-bis-acrylamide-crosslinked bagasse > epichlorohydrin-crosslinked bagasse (less than 5% degraded). Crosslinking severely impacted biodegration, probably by preventing the penetration of (hemi)cellulytic and lignolytic enzymes into the interior of the modified bagasse particles. It is concluded that the biodegradability of quaternized, crosslinked bagasse is too low for composting or land application. 相似文献
89.
The adsorption behaviors of ammonium ions from aqueous solution by a novel bioadsorbent,the Boston ivy (Parthenocissus tricuspidata) leaf powder (BPTL) were investigated.The SEM images and FT-IR spectra were used to characterize BPTL.The mathematical models were used to analyze the adsorption kinetics and isotherms.The optimum pH range for ammonium adsorption by BPTL was found to be 5-10.The adsorption reached equilibrium at 14 hr,and the kinetic data were well fitted by the Logistic model.The intraparticle diffusion was the main rate-controlling step of the adsorption process.The high temperature was favorableto the ammonium adsorption by BPTL,indicating that the adsorption was endothermic.The adsorption equilibrium fitted well to both the Langrnuir model and Freundlich model,and the maximum monolayer adsorption capacities calculated from Langmuir model were 3.37,5.28 and 6.59 mg N/g at 15,25 and 35℃,respectively,which were comparable to those by reported minerals.Both the separation factor (RL) from the Langmuir model and Freundlich exponent (n) suggested that the ammonium adsorption by BPTL was favorable.Therefore,the Boston ivy leaf powder could be considered a novel bioadsorbent for ammonium removal from aqueous solution. 相似文献
90.