火焰原子吸收光谱法测定畜禽粪便中铜和锌

采用冻干法-全量酸消解-火焰原子吸收光谱法测定畜禽粪便中铜和锌,优化了试验条件.铜和锌分别在0 mg/L～3.00 mg/L和0 mg/L～1.00 mg/L范围内线性良好,检出限分别为6 mg/kg和2 mg/kg(按取0.5 g试样消解定容至50 mL计算),粪便试样测定的RSD分别为1.3%和3.7%,加标回收率分别为104%和107%.     

改性沸石分离富集-火焰原子吸收光谱法测定长江水中镉

采用改性沸石分离富集-火焰原子吸收光谱法测定长江水中微量镉,优化了富集和洗脱条件,讨论了干扰离子的影响。方法在0μg~4.00μg范围内线性良好,检出限为0.214μg/L,长江水平行测定的RSD为1.8%,加标回收率为99.0%~104%。     

外力作用下管道内表面缺陷处裂纹扩展研究

为提高油气管道安全风险评估的准确性,以含内表面缺陷管道为研究对象,利用ABAQUS软件线弹性及弹塑性分析不同尺寸缺陷对裂纹萌生特征的影响;采用扩展有限元法,建立管道3点弯曲模型与全尺寸静载物理试验,并非线性拟合裂纹扩展尺寸,研究内表面缺陷处裂纹扩展情况.研究结果表明:内表面缺陷中心处极易萌生裂纹,随着缺陷尺寸的增大,裂...     

Assessing and testing prediction uncertainty for single tree-based models: A case study applied to northern hardwood stands in southern Québec, Canada

Estimating prediction uncertainty for a single tree-based model is hindered by the complex structure of these models. In this paper, we addressed this issue with a case study applied to northern hardwood stands in Québec, Canada. SaMARE is a stochastic single tree-based model that was designed for these types of stands. Using a Monte Carlo approach, the model can provide a mean predicted value and its confidence limits for some plot-level attributes.The mean predicted values were compared to observed values in terms of bias and accuracy. In addition to these common statistics, we compared nominal coverage of Monte Carlo-simulated confidence intervals with real (observed) coverage to verify the adequacy of the simulated uncertainty. A comparison was made using several plot-level attributes, which exhibited an increasing discriminative complexity. This complexity ranges from coarse attributes, such as all-species basal area, up to more complex ones, such as basal area for stems of a particular species and with sawlog potential.The results showed that in terms of absolute value, biases were small, but could be relatively high with respect to the average observed value when the discriminative complexity of the attribute increased. The comparison between nominal and real coverage of confidence intervals gave satisfactory results for all-species plot-level attributes. However, for some species-specific attributes, the Monte Carlo-simulated confidence intervals overestimated the real coverage.     

长江流域的鱼类资源及其保护对策

长江水系的鱼类约有300种,其中鲤科鱼类占半数以上,主要的经济鱼类多数属于鲤科。对不同江段的鱼类资源作了简介,并提出了相应的保护措施。上游江段以维护生物多样性,保护特有种为主,需要建立鱼类自然保护区;中游应保证主要经济鱼类的自然繁殖条件,加强珍稀鱼类的人工繁殖放流工作,同时对湖泊幼鱼资源进行保护;下游应注意保持江水质量,严格遵守工业废水排放标准;河口江段应规定幼鲟保护期,建议每年6月15日至7月31日停止一切损害幼鲟资源的渔捞作业。     

"燃烧假人"测试方法中燃烧系统设计研究

“燃烧假人”测试方法中火场环境生成是对服装整体阻燃性能进行定量评估的前提，而燃烧系统设计是实现具有可重复性、一致性、均匀性等特点火场环境的关键。本文对燃烧系统的需求进行了分析，对其构成及设计思路进行了研究，提出了一种解决方案。     

Flame behaviors and pressure characteristics of vented dust explosions at elevated static activation overpressures

Dust explosion venting experiments were performed using a 20-L spherical chamber at elevated static activation overpressures larger than 1 bar. Lycopodium dust samples with mean diameter of 70 μm and electric igniters with 0.5 KJ ignition energy were used in the experiments. Explosion overpressures in the chamber and flame appearances near the vent were recorded simultaneously. The results indicated that the flame appeared as the under-expanded free jet with shock diamonds, when the overpressure in the chamber was larger than the critical pressure during the venting process. The flame appeared as the normal constant-pressure combustion when the pressure venting process finished. Three types of venting processes were concluded in the experiments: no secondary flame and no secondary explosion, secondary flame, secondary explosion. The occurrence of the secondary explosions near the vent was related to the vent diameter and the static activation overpressure. Larger diameters and lower static activation overpressures were beneficial to the occurrence of the secondary explosions. In current experiments, the secondary explosions only occurred at the following combinations of the vent diameter and the static activation overpressure: 40 mm and 1.2 bar, 60 mm and 1.2 bar, 60 mm and 1.8 bar.     

Flame regime estimations of gasoline explosion in a tube

Flame regime of gasoline-air mixture explosion is related to chemical reaction, turbulent flow and heat and mass transfer. Experimental data of gas velocity, pressure and flame temperature of gasoline-air mixture explosion in a tube at the equivalence ratio of 0.72, 1.00 and 1.28 were preliminarily acquired. Then, fluctuating velocities, overpressures, and burned and unburned gas temperatures at early stage (50 ms), intermediate stage (150 ms) and last stage (250 ms) in three explosions were determined through the analysis of the experimental data. Finally, the Damköhler number and Reynolds number of the early, intermediate and late stage were calculated respectively, and the flame regimes for each stage were estimated through the Damköhler number vs. Reynolds number diagram. Results show that all the flames at early, intermediate and late stage of the three explosions have the same regime of flamelets-in-eddies. The conclusions can provide some useful references for further study of the flame regime and the numerical analysis model selection of gasoline-air mixture explosion.     

Gas flame acceleration in long ducts

In many practical situations, a flame may propagate along a pipe, accelerate and perhaps transform into a devastating detonation. This phenomenology has been known, more or less qualitatively, for a long time and mitigation techniques were proposed to try and avoid this occurrence (flame arresters, vents,...). A number of parameters need to be known and in particular the “distance to detonation” and more generally the flame acceleration characteristic scales. Very often, the ratio between the detonation run-up distance and the pipe diameter is used without any strong justification other that using a non-dimensional parameter (L/D). In this paper, novel experimental evidence is presented on the basis of relatively large scale experiments using 10 cm and 25 cm inner diameter duct with a length between 7 and 40 m. Homogeneous C₂H₄-air, CH₄-air, C₃H₈-air and H₂-air mixtures were used and different ignition sources. The interpretation suggests that the self-acceleration mechanism of the flame may be much better represented by flame instabilities than by turbulence build-up. One consequence would be that the maximum flame velocity and, following, the maximum explosion overpressure, would be rather linked with the run-up distance than with the L/D ratio.     

Deflagration to detonation transition in a vapour cloud explosion in open but congested space: Large scale test

The paper reviews large scale experiments with various fuels in air where successful deflagration to detonation transition (DDT) took place. This includes a recent experiment disclosed in the Buncefield R&D program, where DDT developed in the propane/air mixture. The DDT occurred in branches of deciduous trees in a premixed stagnant mixture. An internal R&D investigation programme was initiated to better understand the phenomena. A large scale experiment in an open space with ethane air mixture is presented in the paper. The premixed mixture was ignited at the edge of the congested three-dimensional rigs which consisted of vertical and horizontal pipes. After ignition, the flame accelerated in the congestion and transitioned to detonation at the end of congestion. Stable detonation propagated through the remaining open and uncongested space.The flame acceleration process leading to DDT is scale dependent. It also depends on many parameters leading to a large investigation array and, significant cost. However, such R&D efforts aimed toward a safer plant design, i.e. the prevention of occurrence of a major accident, are a small fraction of a real accident cost.