Novel functional fiber loaded with carbon dots for the deep removal of Cr(VI) by adsorption and photocatalytic reduction

A novel functional fiber (PAN-CDs) loaded with carbon dots (CDs) with excellent photoreduction and adsorption properties for Cr(VI) was prepared via an amidization reaction between the CDs' carboxyl groups and amine groups on polyacrylonitrile (PAN)-based ion exchange fibers, which could completely preserve the fluorescence properties of the CDs. The photoluminescence (PL), photocatalysis and adsorption properties of PAN-CDs were characterized and analyzed. The PAN-CDs possess high adsorption capacity (297.6?mg/g) and excellent kinetic behavior (attaining adsorption equilibrium in 30?min) for Cr(VI) adsorption. Furthermore, the residual Cr(VI) (approximately 3?mg/L) after adsorption could be removed completely by subsequent photoreduction by the PAN-CDs. The Cr-saturated PAN-CDs could be easily separated by filtering and regenerated, with no observable decay of removal efficiency after five regeneration cycles. In addition, due to the PL quenching action of Cr(VI), the PAN-CDs can also be used as sensor for quantitative detection of trace Cr(VI) in aqueous solution.     

工业园共生演化定量研究

以江苏泰兴精细化工园及南通农药化工园为例,将最大流原理及自组织特征映射神经网络用于研究非成熟工业园的产业共生演化.由于演算得到的序参量ξ值虽然可以表征各工业园共生效益随时间变化情况,却无法用来横向比较工业园间共生效益,因此对计算过程进行了改进,提出新的序参量计算方法.比较了序参量ξ与产业关联度、交换量等指标后,定义ξ为产业共生演化效率指标,并将卡伦堡工业园2005年得出的ξ值2.87作为共生演化稳定状态标准值.研究发现,2个工业园在较少人工干预下,ξ值逐年上升,分别从0.04,0.133增加到1.51和1.675,但远小于卡伦堡工业园的2005年ξ值.建议在工业园自发形成进程基础上,加以合理引导,促进工业园更好更快地发展.     

牛栏江污染物源解析与空间差异性分析

牛栏江-滇池补水是缓解滇池生态用水短缺的重要工程,对牛栏江流域主要污染源与空间差异性的识别分析,将有助于进一步改善牛栏江的水质. 采用CFA(对应分析)对牛栏江流域污染源进行解析识别,结果表明流域内TN、NH₃-N(氨氮)等污染物主要来源于嵩明县境内,TP、氟化物等污染物主要来源于寻甸县境内. 在CFA分析的基础上,采用HCA(层次聚类分析)和SOM(自组织映射神经网络)对4个监测点、10种污染物指标进行分析,以识别空间分布的差异性和相似性,并且评价各指标的空间分布特征及监测点代表性. 结果表明:4个监测点中,TP、氟化物、砷化物、Vph(挥发酚)在寻甸县境内的七星桥污染最严重;TN、NH₃-N在牛栏江上游嵩明县境内的四营污染最重. 结合流域污染负荷调查可知,寻甸县的磷负荷最大,占流域总负荷的58.73%,七星桥的TP污染贡献大于其他3个监测点,与七星桥TP污染最为严重相符合. 该研究结果可为牛栏江流域实施进一步的分段治理提供决策支撑.      

长三角地区汛期暴雨时空特征分析

为揭示长三角地区汛期暴雨时空特征,利用该地区20个气象测站1959—2005年逐日降水数据,统计不同测站年汛期(5月—9月)暴雨量、暴雨日数,采用数据场、线性趋势法、Mann-Ken-dall非参数检验法及Morlet小波方法对其进行分析。结果表明,长三角地区可分为南区、中区、北区3个空间区域。47 a来各分区汛期暴雨量呈先减少再增加的趋势,整体上呈增加趋势,但均不显著,只有中区在1998—2003年间出现超过α=0.05显著性水平的变化特征。各分区均存在25 a左右的准周期震荡,且具有全域性;从20世纪80年代开始短时间尺度周期(小于20 a)有延长趋势,但不稳定。     

Response of indigenous Cd-tolerant electrochemically active bacteria in MECs toward exotic Cr(VI) based on the sensing of fluorescence probes

Electrochemically active bacteria (EAB) on the cathodes of microbial electrolysis cells (MECs) can remove metals from the catholyte, but the response of these indigenous EAB toward exotic metals has not been examined, particularly from the perspective of the co-presence of Cd(II) and Cr(VI) in a wastewater. Four known indigenous Cd-tolerant EAB of Ochrobactrum sp X1, Pseudomonas sp X3, Pseudomonas delhiensis X5, and Ochrobactrum anthropi X7 removed more Cd(II) and less Cr(VI) in the simultaneous presence of Cd(II) and Cr(VI), compared to the controls with individual Cd(II) or single Cr(VI). Response of these EAB toward exotic Cr(VI) was related to the associated subcellular metal distribution based on the sensing of fluorescence probes. EAB cell membrane harbored more cadmium than chromium and cytoplasm located more chromium than cadmium, among which the imaging of intracelluler Cr(III) ions increased over time, contrary to the decreased trend for Cd(II) ions. Compared to the controls with single Cd(II), exotic Cr(VI) decreased the imaging of Cd(II) ions in the EAB at an initial 2 h and negligibly affected thereafter. However, Cd(II) diminished the imaging of Cr (III) ions in the EAB over time, compared to the controls with individual Cr(VI). Current accelerated the harboring of cadmium at an initial 2 h and directed the accumulation of chromium in EAB over time. This study provides a viable approach for simultaneously quantitatively imaging Cd(II) and Cr (III) ions in EAB and thus gives valuable insights into the response of indigenous Cd-tolerant EAB toward exotic Cr(VI) in MECs.

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Exploring human–nature interactions in national parks with social media photographs and computer vision

Understanding the activities and preferences of visitors is crucial for managing protected areas and planning conservation strategies. Conservation culturomics promotes the use of user-generated online content in conservation science. Geotagged social media content is a unique source of in situ information on human presence and activities in nature. Photographs posted on social media platforms are a promising source of information, but analyzing large volumes of photographs manually remains laborious. We examined the application of state-of-the-art computer-vision methods to studying human–nature interactions. We used semantic clustering, scene classification, and object detection to automatically analyze photographs taken in Finnish national parks by domestic and international visitors. Our results showed that human–nature interactions can be extracted from user-generated photographs with computer vision. The different methods complemented each other by revealing broad visual themes related to level of the data set, landscape photogeneity, and human activities. Geotagged photographs revealed distinct regional profiles for national parks (e.g., preferences in landscapes and activities), which are potentially useful in park management. Photographic content differed between domestic and international visitors, which indicates differences in activities and preferences. Information extracted automatically from photographs can help identify preferences among diverse visitor groups, which can be used to create profiles of national parks for conservation marketing and to support conservation strategies that rely on public acceptance. The application of computer-vision methods to automatic content analysis of photographs should be explored further in conservation culturomics, particularly in combination with rich metadata available on social media platforms.     

Consumption-based accounting of CO2 emissions in the sustainable development Goals Agenda

In 2017 the paper ‘The Sustainable Development Oxymoron: Quantifying and Modelling the Incompatibility of Sustainable Development Goals’ was published, showing that there is a conflict between socio-economic development goals and ecological sustainability goals using cross-country time-series data. The authors looked at production-based CO2 emissions to measure and model the 13^th SDG goal addressing climate change. Their models showed that production-based CO2 emissions were stalling or even decreasing in rich countries, which suggests that other countries are also likely to see stalling and decrease in their CO2 emissions once they become rich. However, this conclusion can be challenged when accounting for consumption-based CO2 emissions rather than production-based CO2 emissions. In this follow-up paper, we re-run some of the analyses performed in the original paper making use of consumption-based CO2 emissions. The analysis confirms the inherent SDG conflict between socio-economic and ecological SDGs. But, this new analysis demonstrates that from a consumption perspective the trend of stalling or decreasing CO2 emissions is reversed, with natural depletion costs being exported to poorer countries. Despite this new perspective on CO2 emissions, the conflict between SDG goals can still be avoided by making investments in public health, education and renewable energy, as suggested in the original paper.     

城市边缘旅游新区的开发模式--以西安曲江新区为例

作为城市边缘的旅游新区开发,既是城市化发展的需要,也是提升区域旅游业竞争力的要求.开发旅游新区,整合区域旅游资源,打造旅游特色,已成为各个区域旅游业发展的必然选择.以西安曲江旅游新区的开发为例证,从新区功能定位、空间组织以及旅游特色塑造等方面阐释了城市新区的开发模式,即功能定位的"三维视角","主-次中心组团式"的空间组织模式以及旅游产品开发的"三优模式",可为其它城市边缘旅游新区的开发提供可资借鉴的典型案例.     

Temperature, Salinity, and Fluorescence in Southern North Sea: High-Resolution Data Sampled from a Ferry

/ In 1991 and 1992, temperature, salinity, and fluorescence were measured by automatic continuous registration using instrumentation on a ferry crossing the southern North Sea daily along a transect between Zeebrugge, Belgium, and Hull, United Kingdom. The temperature ranged between 4 and 21 degrees C off the Belgian coast and between 6 and 17 degrees C in the middle of the transect. Salinity varied between 34 and 35.5 PSU in the offshore part of the transect, but showed much larger variation along the Belgian and UK estuarine coasts. Fluorescence, which was used as a measure of phytoplankton biomass, was highest at the continental coast and lowest near the English coast. Spring blooms of phytoplankton were found along the continental coast and in the channel-influenced water; in 1991 the blooms were denser than in 1992. Some summer blooms were also recorded. Water masses could be distinguished on the basis of salinity and fluorescence patterns. The general patterns in the data are compared with the literature and discussed in relation to river discharge, light penetration, and wind speed and direction. Finally, the value of automatic and frequent measurements of fluorescence for monitoring phytoplankton is compared with less frequent observations at selected stations. It is concluded that accurate information about phytoplankton biomass can only be established from the high-frequency data. KEY WORDS: Monitoring; Sampling; North Sea; Ferry; Fluorescence; Salinity; Temperature     

龙虎山世界地质公园丹霞景观特征及其科学价值

江西龙虎山世界地质公园是一个集地质、地貌、人文、自然生态景观为一体的综合性地质公园,其中以丹霞地貌景观最具特色。它是国内发育老年早期丹霞地貌的典型地区之一,以孤峰、峰林、残丘等丹霞地貌景观为特色。公园内拥有丹霞地貌景观、丹霞水体景观、丹霞生态景观和丹霞文化景观等4大丹霞类型。地质公园的地质遗迹记录了中生代以来地球历史的丰富信息和演化过程,展示了世界上一些重要地质事件的突出证据;孕育了分布最密集、造型最精美的造型石;是世界上极具濒危的中华秋沙鸭最大群体的越冬地;古崖墓文化、道教文化、佛教文化等历史人文遗迹以其独特的方式融汇在具有突出价值的自然美之中,构成了人与自然和谐共处的最富特色的例证。这些具有国际意义的自然现象、自然演化过程和杰出的天然美景集中展示于公园,具有不可替代的美学价值、科学价值和重要的保护意义。