Hexavalent chromium in drinking water: Chemistry,challenges and future outlook on Sn(II)- and photocatalyst-based treatment

• Wide occurrence of Cr(VI) in US source drinking water. • A strong dependence of occurrence on groundwater sources. • Elucidate Redox and equilibrium chemistry of Cr(VI). • Sn(II)-based and TiO₂-based reductive treatments hold extreme promise. • Key challenges include residual waste, Cr(VI) re-generation and socioeconomic drivers. Chromium (Cr) typically exists in either trivalent and hexavalent oxidation states in drinking water, i.e., Cr(III) and Cr(VI), with Cr(VI) of particular concern in recent years due to its high toxicity and new regulatory standards. This Account presented a critical analysis of the sources and occurrence of Cr(VI) in drinking water in the United States, analyzed the equilibrium chemistry of Cr(VI) species, summarized important redox reaction relevant to the fate of Cr(VI) in drinking water, and critically reviewed emerging Cr(VI) treatment technologies. There is a wide occurrence of Cr(VI) in US source drinking water, with a strong dependence on groundwater sources, mainly due to naturally weathering of chromium-containing aquifers. Challenges regarding traditional Cr(VI) treatment include chemical cost, generation of secondary waste and inadvertent re-generation of Cr(VI) after treatment. To overcome these challenges, reductive Cr(VI) treatment technologies based on the application of stannous tin or electron-releasing titanium dioxide photocatalyst hold extreme promise in the future. To moving forward in the right direction, three key questions need further exploration for the technology implementation, including effective management of residual waste, minimizing the risks of Cr(VI) re-occurrence downstream of drinking water treatment plant, and promote the socioeconomic drivers for Cr(VI) control in the future.     

The ecological footprint: an exhibit at an intergenerational trial?

This paper aims at assessing the extent to which the ecological footprint indicator (EF) can be regarded as an exhibit allowing an intergenerational trial about the use of natural resources. For that purpose, we examine various criticisms questioning the relevancy of EF measures for the study of environmental justice between generations. We explore the difficulties raised by the physical—and highly aggregated—nature of EF measures, as well as problems related to the number, the possible non-existence, and the tastes of future generations. The extent to which postulates on nature’s regeneration and technological progress affect the significance of EF studies is also discussed. It is concluded that those criticisms, by identifying various weaknesses of EF measures for the study of intergenerational justice, point to several crucial refinements of existing EF-based analyses.

The environmentalist who cried drought: Reactions to repeated warnings about depleting resources under conditions of uncertainty

Three studies examined the impact of warnings about depleting resources. In Study 1, participants played 16 trials of a 5-person resource dilemma game with complete resource uncertainty. After trial 12, participants were told they were close to depleting the resource, and thereafter received no additional warnings. Size of harvests dropped after the warning, but rebounded within 3 trials to pre-warning levels, a pattern stronger under low harvesting variability. In Study 2, participants received warnings after trials 12 and 16 of a 22-trial game. Again, harvesting dropped after the first warning, but rebounded to pre-warning levels within 3 trials, a pattern stronger under a short-term vs. a long-term warning. Harvesting was unaffected by the second warning. In Study 3, when participants received no feedback about others' harvests, harvesting dropped after both warnings, and was lower among those led to believe the resource would last a short number of trials.     

Maritime Transport in the Gulf of Bothnia 2030

Scenarios for shipping traffic in the Gulf of Bothnia (GoB) by 2030 are described in order to identify the main factors that should be taken into account when preparing a Maritime Spatial Plan (MSP) for the area. The application of future research methodology to planning of marine areas was also assessed. The methods include applying existing large scale quantitative scenarios for maritime traffic in the GoB and using real-time Delphi in which an expert group discussed different factors contributing to future maritime traffic in the GoB to find out the probability and significance of the factors having an impact on maritime traffic. MSP was tested on transnational scale in the Bothnian Sea area as a pilot project.     

Does a change of irrigation technique impact on groundwater resources? A case study in Northeastern Italy

The Venetian plain is a densely populated area and one of the most economically competitive regions in Europe. Therefore, a sustainable management of the water resources has to be accomplished to preserve both the social and economic value of this area and the regional environment in accordance with the European water policy directives. This paper presents the analysis of hydrologic and hydrogeological water balances of the high alluvial plain (approximately 790 km²) highlighting some important peculiarities that could be crucial for the local water policy. By focusing on the importance of different water budget components, the obtained results indicate in the irrigation the most relevant component of the aquifer recharge. Thus, the irrigation management policy of the Land Reclamation Consortia strongly influences aquifer recharge. Moreover, future scenarios (2071–2100) for the high Venetian plain are performed taking into account the changes of climate and irrigation policy. The inflow of the aquifer suffers a decrease ranging from 18% in the scenario influenced by climate change to 28% in the scenario affected by both the variations. In particular, the irrigation recharge shows the highest reduction due to both an increase in evaporation, owing to an increase in the surface temperature, or the irrigation methods. Therefore, the irrigation management policy adopted by the Land Reclamation Consortia is a fundamental concern. Changes from surface irrigation to spray or drip irrigation could strongly affect the aquifer recharge. The classical technique of surface irrigation is very useful in terms of aquifer recharge in comparison with drip or spray irrigation. However, it also requires a huge volume of water compared with the minimum desirable streamflow of a river and its management policy. Currently in Italy, the transition from conventional irrigation systems to water saving techniques is favored by the Land Reclamation Consortia in response to European and Italian directives. However, the possible reduction of the aquifer recharge could influence the actual social and economic condition of the Venetian plain because the human and industrial water needs are mostly dependent by groundwater exploitation. Therefore, water saving activities should be accompanied by appropriate corrective actions to reduce the environmental and social impact due to the decrease in aquifer recharge.