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221.
S. Christensen P. Ambus J.R.M. Arah H. Clayton B. Galle D.W.T. Griffith K.J. Hargreaves L. Klenzedtsson A.-M. Lind M. Maag A. Scott U. Skiba K.A. Smith M. Welling F.G. Wienhold 《Atmospheric environment (Oxford, England : 1994)》1996,30(24):4183-4190
The soil in a drained fjord area, reclaimed for arable farming, produced N2O mainly at 75–105 cm depth, just above the ground water level. Surface emissions of N2O were measured from discrete small areas by closed and open-flow chamber methods, using gas chromatographic analysis and over larger areas by integrative methods: flux gradient (analysis by FTIR), conditional sampling (analysis by TDLAS), and eddy covariance (analysis by TDLAS). The mean emission of N2O as determined by chamber procedures during a 9-day campaign was 162–202 μg N2ONm−2h−1 from a wheat stubble and 328–467 μg N2ONm−2 h−1 from a carrot field. The integrative approaches gave N2O emissions of 149–495 μg N2ONm−2 h−1, i.e. a range similar to those determined with the chamber methods. Wind direction affected the comparison of chamber and integrative methods because of patchiness of the N2O emission over the area. When a uniform area with a single type of vegetation had a dominant effect on the N2O gradient at the sampling mast, the temporal variation in N2O emission determined by the flux gradient/FTIR method and chamber methods was very similar, with differences of only 18% or less in mean N2O emission, well below the variation encountered with the chamber methods themselves. A detailed comparison of FTIR gradient and chamber data taking into account the precise emission footprint showed good agreement. It is concluded that there was no bias between the different approaches used to measure the N2O emission and that the precision of the measurements was determined by the spatial variability of the N2O emission at the site and the variability inherent in the individual techniques. These results confirm that measurements of N2O emissions from different ecosystems obtained by the different methods can be meaningfully compared. 相似文献
222.
223.
城市污水处理厂不同工艺段中有机氯农药残留 总被引:3,自引:0,他引:3
建立了基于HLB固相萃取柱和气相色谱 /电子捕获 (GC/ECD)分析城市污水中有机氯农药的分析方法 ,同时分析了北京市高碑店和北小河两个污水处理厂中 4个不同工艺段水体中有机氯农药的浓度。在两个污水处理厂的水体中共检出了 6种有机氯类农药 ,分别是α 六六六、β 六六六、γ 六六六、δ 六六六、艾氏剂和 4 ,4’ 滴滴滴 ,浓度在 1 89—6 9 6ng/L之间。结果表明 ,曝气活性污泥法对六六六类有机氯农药的去除效果较好。 相似文献
224.
超声波萃取—GC/MS测定大气颗粒物中的多环芳烃 总被引:11,自引:0,他引:11
魏恩棋 《城市环境与城市生态》2002,15(4):44-45
采用超声波萃取大气颗粒物样品中的多环芳烃,样品不须纯化,直接可用于GC/MS分析,超声波萃取效率高,萃取时间短;采用MS的SIM方式对多环芳烃进行定性定量,回收率84.5%-108.5%,变异系数3.1%-14.5%。 相似文献
225.
新型固相萃取器用于污染水样中痕量杀虫剂的浓缩及热解吸气相色谱-质谱分析 总被引:3,自引:0,他引:3
WANGLi-Li HOSAKAAkihiko WATANABEChuichi 《环境化学》2003,22(3):267-270
1 IntroductionSolid phasemicro extraction (SPME)asasimpleandrapidextractiontechniqueiswidelyusedinvariousareasforextractingdiluteanalytesfromliquid ,gaseousandsolidsamplesbecauseofitshighextractionefficiency[1 ].Recently ,astirbarsorptiveextraction (SBSE… 相似文献
226.
本文采用活性炭管对糠醛厂厂界空气中糠醛进行吸附,选用适当的有机溶剂进行解吸,运用气相色谱-质谱(GC/MS)方法对空气中糠醛进行定性、定量分析。此方法适用于环境空气中糠醛的测定。 相似文献
227.
为了解我国中小城市地区SOA(二次有机气溶胶)的质量浓度及来源,采集了浙江省中西部典型地区——兰溪市城区和近郊2个站点2016年四季的PM2.5样品,利用GC/MS(气相色谱/质谱)分析了PM2.5中11种指示不同来源的SOA示踪物的质量浓度水平,利用示踪物产率法估算了不同来源前体物对SOC(二次有机碳)的贡献.结果表明:兰溪市PM2.5中ρ(异戊二烯SOA示踪物)的年均值为40.79 ng/m3,约占检测示踪物总质量浓度的89%;ρ(α-蒎烯SOA示踪物)、ρ(β-石竹烯SOA示踪物)和ρ(甲苯SOA示踪物)的年均值分别为4.09、0.36和1.01 ng/m3.ρ(异戊二烯SOA示踪物)和ρ(α-蒎烯SOA示踪物)存在夏季 > 秋季 > 春季 > 冬季的季节性变化趋势,ρ(β-石竹烯SOA示踪物)为秋季、冬季 > 春季、夏季,而ρ(甲苯SOA示踪物)的季节性变化不显著,表明不同类型VOCs(挥发性有机物)前体物排放量的季节性变化明显不同.基于示踪物产率法的估算结果表明:夏季异戊二烯等植物源VOCs可能是兰溪市PM2.5中SOA的主要来源;而春季、秋季、冬季甲苯等人为源VOCs是SOA的主要前体物,贡献了兰溪市PM2.5中ρ(SOC)的60%左右.研究显示,减少人为源VOCs的排放对相关地区灰霾及大气细颗粒物污染的防控具有重要作用. 相似文献
228.
Gulnara M. Shaydullina Natalya A. Sinikova Albert T. Lebedev 《Environmental Chemistry Letters》2005,3(1):1-5
Ozone, chlorine and sodium hypochlorite are commonly used as disinfecting agents for drinking water production. The reaction pathways of ozonation and chlorination of o-methoxybenzoic acid in aqueous solution were studied using gas chromatography-mass spectrometry (GC-MS) and high pressure liquid chromatography (HPLC). The results show that less than 1% of o-methoxybenzoic acid remains in reaction. The final major products using ozone oxidation are oxalic and glyoxalic acids. Phenols appear only at insufficient ozone levels. Sodium hypochlorite leads to higher levels of primary products. Molecular chlorine leads to the formation of higher amounts of polychlorinated derivatives. Model experiments allow to propose schemes of o-methoxybenzoic acid transformation under the conditions simulating water treatment processes. 相似文献
229.
S.?HeimEmail author J.?Schwarzbauer A.?Kronimus R.?Littke A.?Hembrock-Heger 《Environmental Chemistry Letters》2003,1(3):169-173
Organic-geochemical investigations were performed on layers of a dated sediment core taken from a riparian wetland of the Lippe river, Germany. The samples were collected from two distinct depth intervals representing sedimentation periods of 1944–1952 and 1972–1984, respectively. Comprehensive screening analyses by gas chromatography-mass spectrometry (GC-MS) revealed a complex mixture of anthropogenic contaminants. Here, we report the quantitative distribution of selected persistent lipophilic organic substances characterizing municipal as well as industrial emissions. Considering both geochemical and geochronological data, we deduced time-dependent information about industrial production and domestic effluents for the region investigated. In addition, usage and subsequent emission of characteristic pollutants into the riverine system were interpreted for both time periods monitored. 相似文献
230.
固相萃取法提取净化生物检材中三类农药的实验研究 总被引:19,自引:0,他引:19
本文以常见的六种有机磷类、四种氨基甲酸脂类和五种拟种虫菊酯类农药为对象,研究了用国产GDX-403或C18固相小柱同时提取净化环境样品和生物检材中三种类型的农药,分别采用GC/FPD,GC/NPD和GC/ECD三种特征性气相色谱法进行分析鉴定,为系统分析有机农药提供了一套快速、简便的固相提取方法。 相似文献