井下火花——矿井火灾的点燃源

考察了各类井下火花诱发灾害的典型实例以及８０年代以来国内外的研究状况，指出深入开展这一课题的研究对防灾的重要性．     

回采工作面瓦斯涌出量预测的神经网络方法

回采工作面瓦斯涌出量受煤层瓦斯含量、工作面产量和采煤方法等各种因素的影响 ,笔者通过研究得出 :回采工作面瓦斯涌出量与煤层的赋存条件和开采条件之间是一种非线性关系 ,但目前还难以用精确的数学建模来求解。因此 ,提出了一种应用BP人工神经网络模型和算法 ,建立工作面瓦斯涌出量预测模型 ,从而预测不同开采条件下回采工作面瓦斯涌出量。实际应用表明 ,模型精度能满足要求。笔者还对隐含层神经元数目对步长影响作了讨论。     

City hazardous gas monitoring network

In our today's societies, many dangerous chemicals are produced and transported. Due to the vast use of chemicals, more chemical accidents are taking place with huge losses. In this study a city hazardous gas monitoring network was designed to detect the dispersion of toxic and combustible gases in the primary stages. The network could cover hazardous chemical facilities, important hazardous chemical routes, warehouses and special locations which may be the targets of terrorist attacks. The network is consisted of several local networks and a central control panel complex. Each local network has a local control panel in the center and many detectors and sounders around it at distances less than 3000 m that communicate with the local control panels wirelessly. In each location there are two types of gas detectors, toxic and combustible, and a sounder which are equipped with a wireless, radio frequency modem allowing the units to communicate readings and other information on a real-time basis with a remotely located local control panel. High sensitive Photo Ionization Detectors, PIDs, are used to provide fast and low-level on-site screening for chemicals contamination. Combustible gas detectors are the second choice to sense the combustible gas and verify the readings of PIDs in this regard. The central panel consists of several connected control panels work uniquely helping a computer set and the appropriate software and communicate with local control panels via telephone lines. All of the network components are shown on the monitor of central panel with special symbols by geographical information system program. The system is fully addressable so that the high level detection of a detector produces a blinking color double-circle around its symbol in GIS plan. In case of high level gas detection, a team of experts who are fully equipped with different portable detectors depart to the site to test the field to identify the chemicals. All readings of detectors are saved in a data bank and then analyzed to find any chemicals spills and leakages. The network was simulated by a special program so that the components of local networks and the central panel are shown in separate windows. By clicking on one detector on environmental window the formerly designed responses will be activated in central panel window.     

顶空气相色谱法测定食品中甜蜜素含量

采用顶空气相色谱法测定食品中甜蜜素含量,探讨了气液相平衡条件及色谱条件的选择,实验结果表明甜蜜素的标准溶液在0.1-0.4μg/l范围内具有良好的线性关系,回收率为87.5%-101.8%,相对标准偏差为2.6%.     

Systems thinking in a gas explosion accident – lessons learned from Taiwan

On July 31, 2014, at around 23:57, several huge explosions occurred that lasted for 2 h in Kaohsiung City, Taiwan. As a result of a gas leak from a ruptured underground pipeline, the catastrophic incident destroyed more than 6 km of roads, killed 32 people, injured 321 people, and damaged 3259 buildings. Pipeline explosions have been reported as a repeatedly occurring problem, indicating that (1) complex systems are difficult to manage and control, and (2) humans are unable to effectively learn from experiences of accidents. Initial analyses results reveal that root causes of this incident were a combination of a series of complex chain reactions, which eventually led to propylene leakage and explosion. This is a systematic problem, which can hardly be investigated or analyzed by traditional research approaches. Based on the investigation reports and “systems thinking” method, this study develops causal loop diagrams for the Kaohsiung gas explosion to explore the root causes of the disaster. The research results indicate that (1) this pipeline explosion incident was the result of the chain reactions and was the output of a complex system; (2) the mental model of “production first” and “experience gap” were the root causes of the disaster; and (3) to achieve a higher safety standard, continuous education to improve the mental model of “safety first and safety over production” are essential. The findings of this study may contribute toward the improvement of the standard operating procedure for disaster management and preventing similar incidents in the future.     

Experimental study on the synergistic inhibition effect of nitrogen and ultrafine water mist on gas explosion in a vented duct

In this study, in order to research the synergistic inhibition effect of nitrogen and ultrafine water mist on gas explosion in a vented duct, a semi-confined transparent chamber was designed with the size of 120 × 120 × 840 mm, and the experiments were carried out with stoichiometric methane/air premixed mixture (fraction of methane: 9.5%), adding different fractions of nitrogen and ultrafine water mist. The experimental results showed the following: The combination of nitrogen and ultrafine water mist had a synergistic inhibiting effect on methane/air explosion, which was preferable to the single use of any kind. With the increase of spraying time of water mist and fraction of nitrogen, the initial shape of the explosion flame became snakelike, and at the same time the peak flame propagation speed and peak overpressure decreased significantly. When the nitrogen fraction was increased to 10% and the mist spraying time was increased to 2min, synergistic inhibiting effect on overpressure was high efficient. However, with the increase of spraying time of water mist and fraction of nitrogen going on, the amount of increase of explosion inhibition efficiency was gradually reduced.     

A product analysis-based study on the mechanism of inflammable gas explosion suppression

To study the mechanism of the suppressing effect of Expanded Aluminium (EA) on the premixed gas explosion, premixed methane-air and propane-air gases were undergone explosion reaction in the presence of EA in a self-designed closed pipeline with the overpressures and the compositions, rates and sensitivities of products analyzed. The results showed that the 9.5% methane-air and 5% propane-air explosions produced peak pressures decreased by 79.3% and 65.6%, and residual methane and propane contents increased by 270% and 560% respectively than without EA. In addition, the results revealed that the explosions of propane in the presence of EA produced less methane and carbon oxides contents, but more ethylene and propylene contents. The simulation showed that H, O, and OH are the key factors affecting the rate of products. The product compositions, together with other parameters, suggested that EA decreased temperature, inhibited chain initiation and propagation reaction, but facilitated chain termination reaction by advancing and accelerating the gas phase and wall destruction reaction of radicals, especially collisions and concentration of key free radicals. This new research method based on the analysis of explosion products can be used for in-depth research into gas explosion features and shed light on the suppressing mechanism of EA in flammable gas explosion.     

Construction of vesicle CdSe nano-semiconductors photocatalysts with improved photocatalytic activity: Enhanced photo induced carriers separation efficiency and mechanism insight

Visible-light-driven photocatalysis as a green technology has attracted a lot of attention due to its potential applications in environmental remediation. Vesicle Cd Se nano-semiconductor photocatalyst are successfully prepared by a gas template method and characterized by a variety of methods. The vesicle Cd Se nano-semiconductors display enhanced photocatalytic performance for the degradation of tetracycline hydrochloride, the photodegradation rate of78.824% was achieved by vesicle Cd Se, which exhibited an increase of 31.779% compared to granular Cd Se. Such an exceptional photocatalytic capability can be attributed to the unique structure of the vesicle Cd Se nano-semiconductor with enhanced light absorption ability and excellent carrier transport capability. Meanwhile, the large surface area of the vesicle Cd Se nano-semiconductor can increase the contact probability between catalyst and target and provide more surface-active centers. The photocatalytic mechanisms are analyzed by active species quenching. It indicates that h+and UO_2~-are the main active species which play a major role in catalyzing environmental toxic pollutants. Simultaneously, the vesicle Cd Se nano-semiconductor had high efficiency and stability.     

烟气黑度的产生及处理方法

本文从原料、生产工艺、处理设备、企业管理等方面论述了烟气黑度超标的相关原因,针对具体情况提出了有针对性的解决方案,改进生产工艺、加强人员管理和设备投入等防治烟气黑度超标现象。     

城市居住区毒气扩散数值模拟

针对某居住区附近氯气储罐连续泄漏,通过求解三维不可压缩Navier-Stokes方程、K-ε湍流模型和物质浓度方程,模拟毒气在建筑物扰动条件下的扩散过程以及浓度时空分布特征,以毒气负载为基础给出近地面毒气危害区域,探讨毒气扩散对周边居民的影响。