基于云模型的页岩气开发环境影响评价

从大气环境、噪声与土壤环境、水环境和生态、安全与可持续4个方面构建页岩气开发环境影响指标体系,并建立基于熵权法和云模型评价法的页岩气环境影响评价模型。针对四川省某国家级页岩气示范区进行实证分析,结果表明:该地区页岩气开发环境影响处于中等程度。页岩气开发对水环境影响最大,其次是对大气环境的影响,再次是对噪声与土壤环境,对生态、安全与可持续方面影响相对最小。该模型的评价结果与页岩气开发环境影响现状相符,最后根据评价结果提出相关政策建议。     

Determination of Commonly Used Herbicides in Surface Water Using Solid-Phase Extraction and Dual-Column HPLC-DAD

The present study describes the application of different solid-phase extraction techniques for the extraction, separation, and quantitative determination of 10 commonly used herbicides with different chemical structures (chlorsulfuron, diuron, bentazone, linuron, chlorpropham, fenoxoprop-ethyl, MCPA, diclofop-methyl, fluazifop-butyl, trifluraline) in water. Octadecyl (C₁₈) Empore extraction disks, octadecyl (C₁₈), and stryene divinylbenzene (SDB) Bond Elut Env cartridges were compared for solid-phase extraction efficiency. Herbicides were separated and quantified by reversed-phase high performance liquid chromatography with diode-array detection (HPLC-DAD) with simultaneous separation on two columns of differing polarity (C₁₈ and CN) to confirm identification. Analytical separation was performed simultaneously on C₁₈ and CN columns. Reanalysis of the sample extracts on a (cyano) CN column were used to confirm the identity of these compounds. Method optimization and validation parameters were presented in this work. Recoveries varied from 76.0% to 99.0% for C₁₈ disks, from 75.1% to 100.0% for C₁₈ cartridges, and from 54.0% to 98.0% for SDB cartridges over concentrations at 0.025–0.4 μg L^?1. The limits of detection were 0.012–0.035 μg L^?1.     

基于模糊优选和CRITIC法的电力碳排放权区域初始分配——以华东电网区域为例

为科学、合理分配电力行业碳排放权,文章综合考虑公平、效率和可持续发展原则,构建了电力碳排放权分配体系,并利用CRITIC法确定指标权重,运用模糊优选法计算碳排放权初始分配比例,结果表明:单位地区生产总值电耗是最主要的影响因素,公平原则下的电力碳排放量、电力能源消费总量和火力发电量也是重要的影响因素;碳排放量问题是复杂的系统问题,碳排放权初始分配要综合考虑公平性原则、效率性原则和可持续原则。最后,为达到和谐稳定的碳排放权分配方案,希望在以后的研究中加强和谐型评判与改进方法。     

我国环保产业研究现状分析——基于宏观视角的文献述评

通过文献研究法,基于宏观视角对我国环保产业研究成果进行梳理。当前,我国的环保产业研究成果初具规模,研究重点在于环保产业的现状分析、问题探讨以及对策研究,包括环保产业各主体间博弈均衡、环保产业的技术支持、投融资机制等内容。未来环保产业研究应注意环保产业竞争力的科学评价、环保产业主体间的良性互动及其合力的达成以及环保技术评价和兑现。     

火灾探测的原理和方法(下)

简述了火灾现象的物理特征、火灾探测的基本原理并对火灾探测算法的建立及发展作了介绍。对产生火灾误报警的原因进行了分析，指出要改善火灾探测的准确性，缺少的不是思路和技术，而是火灾科学基础研究的积累。     

REGIONAL WATER QUALITY MANAGEMENT BY THE GENERALIZED REDUCED GRADIENT METHOD1

ABSTRACT: A river basin-wide water quality management system is considered. The river receives thermal as well as organic wastes. At-source treatment of these pollutants is imposed to control the basin-wide water quality. The related water quality standards are: the minimum DO concentration, the maximum allowable BOD concentration, the maximum allowable stream temperature, and the allowable rise in stream temperature. The general dynamic mathematical model representing water quality in streams and the thermal effects on BOD and DO concentrations is presented. The model is highly nonlinear in nature. The optimal management problem involving the model is solved by a recently developed nonlinear propgramming technique - the generalized reduced gradient (GRG) method. Comparison of results obtained by the GRG method vs. dynamic programming, and of results using a more realistic mathematical model vs. a simple model are presented. The analysis procedure can be applied to designing new and examining existing water quality programs, and to study the influence of alternate policies and constraints.     

A HYBRID OPTIMIZATION APPROACH TO THE ESTIMATION OF DISTRIBUTED PARAMETERS IN TWO-DIMENSIONAL CONFINED AQUIFERS1

ABSTRACT: In using non-linear optimization techniques for estimation of parameters in a distributed ground water model, the initial values of the parameters and prior information about them play important roles. In this paper, the genetic algorithm (GA) is combined with the truncated-Newton search technique to estimate groundwater parameters for a confined steady-state ground water model. Use of prior information about the parameters is shown to be important in estimating correct or near-correct values of parameters on a regional scale. The amount of prior information needed for an accurate solution is estimated by evaluation of the sensitivity of the performance function to the parameters. For the example presented here, it is experimentally demonstrated that only one piece of prior information of the least sensitive parameter is sufficient to arrive at the global or near-global optimum solution. For hydraulic head data with measurement errors, the error in the estimation of parameters increases as the standard deviation of the errors increases. Results from our experiments show that, in general, the accuracy of the estimated parameters depends on the level of noise in the hydraulic head data and the initial values used in the truncated-Newton search technique.     

维多利亚蓝B与碘在水溶液中的显色反应-吸光光度法测定海产品中的碘

研究了水相中,维多利亚蓝B与碘离子(I~-)的显色反应.当磷酸浓度为1.6mol/L,聚乙烯醇为0.08％时,维多利亚蓝B与碘形成络合比为1∶3的络合物,最大吸收峰位于375nm处,表观摩尔吸光系数为1.02×10~4L/mol·cm,碘在(0～16)μg/ml范围内符合比耳定律.方法可用于海洋生物等样品中的微量碘测定,结果满意.     

室内空气中TVOC的分析测试技术

综述了国内外室内空气中TVOC的分析测试技术：比色管检测法，便携式TVOC仪检测法气相色谱或色质联用分析方法，介绍了我国TVOC标准物质／样品的研制与应用情况。     

对水质自动监测中测量值突变的判别与处理

以程序化方式介绍了判别水质自动监测中测量突变的原因。提出当发现某主要指标异常时，应查看相关指标的运行情况，再校准仪器，并人工同步分析样品。若测定结果的相对偏差大于5％，表明测量仪器故障；若相对偏差小于5％，应继续进行源水分析比对，以判别是仪器故障还是污染事故。通过实例分析，淮南市水质自动监测中DO测量值偏低的原因：一是取水泵安装位置不当，造成负压抽水，使水中DO溢出；二是流程太低，致使管道藻类大量繁殖，消耗了水中DO。解决方法：正确安装取水泵，并加大水泵抽水量，冲刷管道藻类。