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31.
32.
Kenneth R. Krach Benjamin R. Burns Baikun Li Alison Shuler Charles Cole Yuefeng Xie 《Water, Air, & Soil Pollution: Focus》2008,8(3-4):369-378
Over three million dry metric tons of biosolids produced in the United States are land applied as Class B. Lime stabilization
is employed for biosolids treatment at approximately 20% of the wastewater treatment plants because it is a simple and inexpensive
process. During lime stabilization, the pH of sewage sludge is raised above 12 for pathogen inactivation and odor reduction.
Lime dose and mixing have been found to greatly reduce odor generation from lime stabilized biosolids. A better quality biosolids
product is less likely to create public opposition to land application programs. In this study, land application tests using
Class B biosolids were conducted in order to determine whether better mixing can reduce odor generation during the land application
of lime stabilized biosolids. The mixing quality of a treatment plant’s lime stabilized biosolids was improved by relocating
the lime addition point, which prolonged the mixing time and produced a better mixed biosolids product. Based on field observations
of land application, the poorly mixed biosolids were more odorous and offensive prior to incorporation. However, once incorporated
into the soil, there was no appreciable odor difference between the biosolids. Another land application study was conducted
to assess the odor of unincorporated Class A biosolids and compare it with incorporated Class A biosolids with the soil. 相似文献
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根据实验室资质认定对于方法确认的要求,结合环境监测实验室的特点,提出了新项目方法确认的具体步骤,并分析了其中存在的常见问题。指出在方法确认过程中,应严格按照标准方法和监测技术规范进行全过程试验,尤其不能忽视采样现场实验、空白实验和检出限的测定。建议在精密度与准确度检验过程中,使用高、中、低不同浓度的有证标准样品,实际样品加标回收,比对试验(方法比对、人员比对、实验室间比对),增加分析次数等多种手段,确保新项目开展的可靠性。 相似文献
35.
从仪器精密度、方法检出限、准确度等角度对吹扫捕集浓缩仪Stratum PTC与Eclipse 4660的性能进行比较。结果表明,大部分分析物用Stratum PTC的方法检出限略高于Eclipse 4660,但精密度比Eclipse 4660稍差;Eclipse 4660用于分析极性的、水溶性物质的效果比Stratum PTC好,回收率更高。两种吹扫捕集仪的测试结果均满足《土壤和沉积物挥发性有机物的测定吹扫捕集/气相色谱-质谱法》(HJ 605-2011)标准方法的指标要求。 相似文献
36.
Arrebola JP Mutch E Rivero M Choque A Silvestre S Olea N Ocaña-Riola R Mercado LA 《Environment international》2012,38(1):54-61
The organochlorine pesticide p,p′-Dichlorodiphenyltrichloroethane (DDT) was widely used in the early 1960s-70s for vector control in tropical and subtropical areas of South America. Due to its persistence, DDT has a high potential to bioaccumulate in the food chain and living organisms and is a major public health concern, especially in South America.The main purpose of the present study was to investigate predictors of serum and adipose tissue concentrations of p,p′-DDT and its main metabolite, p,p′-dichlorodiphenyldichloroethylene (p,p′-DDE), in an adult cohort (n = 112) from Santa Cruz de la Sierra, Bolivia, using multiple linear regression models. These models explained 29.3-47.8% of the variability in adipose tissue concentrations of p,p′-DDT and p,p′-DDE, respectively, and 32.9-47.0% of that in serum. Main exposure predictors included age, occupational class, residence, diet, smoking habit, and accumulated breastfeeding time.This is one of the few studies to explore predictors of human exposure to these chemicals using a multivariate approach in a South American population. Results show that predictors of human exposure to p,p′-DDT and p,p′-DDE in Santa Cruz de la Sierra may diverge from those found in other populations of the world, due to particular sociodemographic and lifestyle characteristics of this region. 相似文献
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《Journal of environmental science and health. Part. B》2013,48(5-6):765-777
Abstract Four methods were developed for the analysis of fluroxypyr in soil samples from oil palm plantations. The first method involved the extraction of the herbicide with 0.05 M NaOH in methanol followed by purification using acid base partition. The concentrated material was subjected to derivatization and then cleaning process using a florisil column and finally analyzed by gas chromatography (GC) equipped with electron capture detector (ECD). By this method, the recovery of fluroxypyr from the spiked soil ranged from 70 to 104% with the minimum detection limit at 5 µg/kg. The second method involved solid liquid extraction of fluroxypyr using a horizontal shaker followed by quantification using high performance liquid chromatography (HPLC) equipped with UV detector. The recovery of fluroxypyr using this method, ranged from 80 to 120% when the soil was spiked with fluroxypyr at 0.1–0.2 µg/g soil. In the third method, the recovery of fluroxypyr was determined by solid liquid extraction using an ultrasonic bath. The recovery of fluroxypyr at spiking levels of 4–50 µg/L ranged from 88 to 98% with relative standard deviations of 3.0–5.8% with a minimum detection limit of 4 µg/kg. In the fourth method, fluroxypyr was extracted using the solid liquid extraction method followed by the cleaning up step with OASIS® HLB (polyvinyl dibenzene). The recovery of fluroxypyr was between 91 and 95% with relative standard deviations of 4.2–6.2%, respectively. The limit of detection in method 4 was further improved to 1 µg/kg. When the weight of soil used was increased 4 fold, the recovery of fluroxypyr at spiking level of 1–50 µg/kg ranged from 82–107% with relative standard deviations of 0.5–4.7%. 相似文献
39.
Jy S. Wu Ellis L. King Michael Wang 《Journal of the American Water Resources Association》1985,21(3):417-421
Traditionally, identification of the Muskingum routing coefficients has been based on observations of the linearity of a loop formed by graphically plotting a forward and a reverse path. This graphical procedure is time-consuming and may not minimize the error of estimation. A procedure was developed to improve the drawbacks of the graphical method. This procedure calls for (a) the use of least square regression on the forward and reverse paths to determine their respective slopes, and (b) the use of statistical t-test to evaluate the hypothesis that these two slopes are equal. The computational procedure is repeated, using incremental values of the flow weighting coefficient, x. A graph of the computed t-value versus x can be constructed. The optimal value of x, as read from the graph, occurs at the minimum computed t-value. The procedure has been demonstrated superior to the graphical method for three illustrative examples, resulting in a reduction of the error squares by factors ranging from 5 to 6. 相似文献
40.
基于道化学法的大型合成氨装置安全评价 总被引:1,自引:0,他引:1
根据道化学公司火灾、爆炸危险指数的基本原理。用VH6.0开发的安全评价软件DowSE1.0,对某大型合成氨装置进行安全评价,得出其安全措施补偿前后的火灾、爆炸指数F&EI以及危险暴露面积,危害系数,危险等级,实际可能财产损失程度等指数。结果表明。合成氨装置中实际最大可能财产损失值都没有超过200万美元,气化系统在合成氨装置中实际最大可能财产损失值占损失替换值比例高达53%,超过了10%的相对危险值界限。说明在引进国外技术时应注重其安全防范配套措施消化吸收,并结合实际采取切实可行的安全措施,降低合成氨装置的风险程度。 相似文献