电熨斗过热故障火灾痕迹特性的研究

通过火灾模拟实验,研究电熨斗发生过热故障后底板的火灾痕迹特性。根据底板的温度分布,应用DTA、TG、SEM、EDS、硬度分析和金相分析等方法,系统分析、归纳、总结电熨斗底板火灾痕迹的材料性能变化规律。研究表明,过热故障电熨斗的火灾痕迹,在宏观形貌、硬度分布和显微组织特征等方面,均显著区别于火烧电熨斗的火灾痕迹。结果为火灾原因调查提供新的技术依据,可应用在火灾现场勘验,物证提取与鉴定工作中。     

大尺度管道中煤粉爆炸的试验研究

煤粉爆炸传播特性的试验研究对于深入了解和预防矿井煤尘爆炸事故有重要意义。利用自制的长29.6 m,内径199 mm的试验管道,对煤粉-空气混合物爆炸压力波传播过程进行试验研究。采用压电传感器测量压力信号,得到爆炸压力波沿管道传播过程中不同测点处的压力时间历程曲线,探讨煤粉粒度和浓度对其爆炸超压的影响规律。结果表明:煤粉-空气混和物在弱点火条件下能够实现粉尘火焰的形成和传播。煤粉爆炸压力波传播过程中速度为400~430 m/s,峰值超压为68~72 kPa。煤粉爆炸峰值超压随着煤粉粒度的减小而增大,但煤粉粒度对其爆炸峰值超压的影响程度随着浓度的增加将逐渐减弱。     

铁对马蹄莲除磷效果的影响

采用营养液培养方法研究Fe对马蹄莲系统除磷效果的影响.实验结果显示,硫铁矿渣和FeCl3均能提高废水中磷的净化效果,FeCl3对马蹄莲净化废水中的总磷、水溶性磷效果尤为明显.与对照相比,FeCl3＋马蹄莲系统对TP平均去除率提高14.75%,水溶性磷比对照高9.25%.随着时间的延长,SOD和POD都是先上升后下降,C...     

分光光度计测量铁含量不确定度评定

文章根据GB/T 4348.3—2002《工业用氢氧化钠铁含量的测定1,10—菲啰琳分光光度法》,以测试工业用氢氧化钠中铁含量为例,依据JJF1059—1999《测量不确定度评定与表示》与CNAS—GL06:2006《化学分析中不确定度的评估指南》对测量过程中不确定来源进行分析,采用A类、B类评定方法对各种因素引起的不确定度分量、合成不确定度、扩展不确定度进行评定,并给出评定结果。对理化分析领域测量不确定度具有借鉴意义。     

浅谈钢铁工业环保设施的“投资-运营”模式

论述了钢铁工业污染防治设施的"投资-运营"模式的发展概况,介绍了该模式的优越性以及实施方式,并从交易结构的角度分析了钢铁企业污染防治设施采用"投资-运营"模式可能会出现的风险以及规避方法。     

Fe（0）/H_2O_2协同降解亚甲基蓝的研究

进行了Fe（0）和H2O2协同催化降解亚甲基蓝的研究,分析了Fe（0）投加量、H2O2投加量、溶液初始pH值和染料初始质量浓度等因素的影响。研究表明：Fe（0）和H2O2协同可有效催化降解亚甲基蓝;在pH为4.5,Fe（0）用量为2.0 g.L-1,H2O2用量为3.0 mmol.L-1时对10 mg.L-1亚甲基蓝的去除率在60 min内达到90%以上。MB的降解去除率随着Fe（0）投加量与H2O2用量的增加而增加,但随着其初始质量浓度的增大而降低。研究结果还表明,Fe（0）和H2O2可在接近中性条件下有效协同催化降解亚甲基蓝。UV-Vis光谱在反应过程的变化说明亚甲基蓝降解生成了一些小分子物质。     

ANAMMOX菌铁自养反硝化工艺的稳定性

在非严格厌氧的连续流反应器中,通过调节进水pH、外加一定浓度的Fe~(2+)以及定期更换新鲜铁粉这3种运行方式探讨维持厌氧氨氧化(ANAMMOX)菌利用零价铁去除硝酸盐反应体系长期稳定运行的适宜条件.结果表明,随着反应进行、受零价铁表面钝化的影响,该体系硝酸盐去除率逐渐下降,反应器难以持续运行.在一定范围内降低进水pH(5～7),或者额外投加一定量的Fe~(2+)对改善该反应体系的稳定性效果不显著.通过定期更换新鲜铁粉的方式,可以有效提高硝酸盐去除率、增强反应器稳定性.相比对照组可稳定运行7 d,实验组可至少稳定运行60 d,硝酸盐平均去除率提高22. 23%.因此,采取适宜措施保证体系内有足够具有活性的零价铁、消除零价铁钝化的不利影响,是ANAMMOX菌利用零价铁去除硝酸盐反应体系高效、稳定运行的关键.     

Reductive dechlorination of polychlorinated dibenzo-p-dioxins by zerovalent iron in subcritical water

A new method for reductive dechlorination of polychlorinated dibenzo-p-dioxins (PCDDs) and remediation of contaminated soils is described that uses zerovalent iron as the dechlorination agent and subcritical water as reaction medium and extractive solvent. It is found that the zerovalent iron can be applied for stepwise dechlorination of octachlorinated dibenzo-p-dioxin (OCDD) on various matrixes in subcritical water. By using iron powder as matrix higher chlorinated congeners were practically completely reduced to less than tetra-substituted homologues. A significant part of residual OCDD, when it was spiked in to soils, and formed less chlorinated congeners are extracted with water in the given conditions. The solubility of OCDD was increased by a 4–6 orders over its solubility at ambient conditions. The new method of contentious-flow extraction is described.     

含铁废料综合利用及污染防治措施

钢铁行业含铁泥浆的治理一直是个难题，文中就此给出了应用范例，即利用泥浆生产酸性炉料，用于高炉炼铁。并且对可能产生的污染进行了预测，提出了防治措施。     

Measurement of cholinesterases in amniotic fluid using a naphthyl acetate as substrate: A possible initial test for prenatal diagnosis of open neural tube defects

A quantitative method for cholinesterases in amniotic fluid using the non-specific substrate α naphthyl acetate and the cholinesterase-specific inhibitor, eserine, is described. This assay was used to test 671 samples of amniotic fluid. The diagnoses for fetal ONTDs, based on the levels of AChE + ChE, were compared with those made for the same samples by the AFP method. Correct diagnoses were made by both methods with amniotic fluid from 35 women carrying fetuses with ONTDs and 631 carrying normal fetuses. There were five false-positive test results for normal fetuses by both methods when the cut-off points were 5 standard deviations above the mean for AFP and above the upper limit of the normal range (7. 5 milliunits) for cholinesterase (AChE + ChE). None of the false-positive samples from either method had the acetylcholinesterase band of activity characteristic of ONTDs after gel electrophoresis. In addition to the above 671 samples, 37 pregnancies with serious fetal abnormalities other than ONTDs were tested. Two were identified by both the AFP and AChE + ChE methods, two more by AFP assay and one other by the AChE + ChE assay.