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61.
采用O3-H2O2氧化法对印染废水进行氧化处理,比较了O3氧化法和O3-H2O2氧化法对印染废水的处理效果,考察了初始废水pH、H2O2加入量、O3流量和反应时间对废水的色度去除率和COD去除率的影响。实验结果表明:O3-H2O2氧化法对废水的COD和色度的去除效果比O3氧化法更好;在初始废水pH为11、H2O2加入量为13mmol/L、O3流量为6g/h、反应时间为60min的最佳工艺条件下,处理后废水COD为61.50mg/L,COD去除率为95.73%,废水色度为5倍,色度去除率为99.75%,TOC为37.84mg/L,TOC去除率为85.10%,BOD5为22.76mg/L,BOD5去除率为90.20%,BOD5/COD为0.37。 相似文献
62.
Maria A. L. Milhome Lucélia K. de Lima Crisiana de A. Nobre Francisco de A. F. Lima Ronaldo F. do Nascimento 《Journal of environmental science and health. Part. B》2013,48(12):786-792
AbstractThis study investigates the oxidation of trifluralin residues during ozonation in aqueous and food matrices (tomato). Domestic ozonation equipment with average production of 23.9?mg O3 L?1 h?1 was used in the tests. Modern chromatographic systems (SPME-GC-IT/MS/MS and QuEChERS-GC-IT/MS/MS) were applied for extraction and detection of trifluralin residue in fortified samples of ultrapure water, tap water, superficial water and tomato fruit. The samples were submitted to the ozonation process during 0, 5, 10 and 20?min. Treatment at 5?min was able to degrade 71.5% of herbicide trifluralin in surface water. The removal (%) in ultrapure water reached 83.4% after 20?min of ozonation. The degradation of trifluralin in fortified tomato samples (0.025–0.1?mg kg?1) were conducted with ozonation at 20?min, and it ranged from 84.4 to 92.7%. After treatment, levels of trifluralin in tomato remained within the established MRLs to EU, USEPA and ANVISA (Brazil). The data provided evidence that ozone is effective for removing trace trifluralin from water and foods. 相似文献
63.
为了解决湿式氨法烟气脱硫生成不稳定亚硫酸铵((NH4)2SO3)副产物的问题,设计了以不锈钢弹簧和溶液分别作为高压和低压电极的沿面放电系统,对液相(NH4)2SO3的氧化进行了研究。空气从反应器上方进入后经放电区域形成活性物质,再由底部的曝气头鼓入溶液并与(NH4)2SO3发生反应。比较了沿面放电处理与传统曝气处理的氧化效率,考察了放电电压、载气气量和初始浓度等因素对(NH4)2SO3氧化的影响。结果表明,沿面放电对(NH4)2SO3有显著的氧化效果;优化条件下的(NH4)2SO3氧化率接近100%;溶液中(NH4)2SO4与(NH4)2SO3的浓度比小于1时有利于(NH4)2SO3的氧化。 相似文献
64.
在Ti(Ⅳ)和过氧化氢存在条件下,考察了臭氧化酸性苯乙酮溶液、硝基苯溶液和垃圾渗滤液(浙江衢州某垃圾填埋场)的预处理效能。结果表明,在pH2.86条件下,单独臭氧化处理对苯乙酮、硝基苯和垃圾渗滤液的COD去除率分别为10.1%、44%和28.6%。BOD,/COD值分别从原来的0.039、0.060和0.085提高到了0.130、0.158和0.174,仍属生化难降解废水。当体系加入Ti(Ⅳ)后,臭氧化苯乙酮和硝基苯的COD去除率分别达到了75.5%和65%,BOD;/COD则提高到了0.679和0.314,可生化性提升明显。对于垃圾渗滤液,只有当体系加入Ti(Ⅳ)和H22后,臭氧化COD的去除率达到66.6%,BOD、/COD提高至0.425。上述结果对酸性难降解废水的处理实际意义非常突出。 相似文献
65.
Z. Zlatev I. Dimov Tz. Ostromsky G. Geernaert I. Tzvetanov A. Bastrup-Birk 《Environmental Modeling and Assessment》2001,6(1):35-55
In order to help guide air pollution legislation at the European level, harmful air pollution effects on agriculture crops and the consequent economic implications for policy have been studied for more than a decade. Ozone has been labeled as the most serious of the damaging air pollutants to agriculture, where growth rates and consequently yields are dramatically reduced. Quantifying the effects has formed a key factor in policymaking. Based on the widely held view that AOT40 (Accumulated exposure Over Threshold of 40 ppb) is a good indicator of ozone-induced damage, the Danish Eulerian Model (DEM) was used to compute reduced agriculture yields on a 50 km×50 km grid over Europe. In one set of scenarios, a ten year meteorological time series was combined with realistic emission inventories. In another, various idealized emission reduction scenarios are applied to the same meteorological time series. The results show substantial inter-annual variability in economic losses, due in most part to meteorological conditions which varied much more substantially than the emissions during the same period. It is further shown that, taking all uncertainties into account, estimates of ozone-induced economic losses require that a long meteorological record is included in the analysis, for statistical significance to be improved to acceptable levels for use in policy analysis. In this study, calculations were made for Europe as a whole, though this paper presents results relevant for Denmark. 相似文献
66.
67.
利用保定市2015—2019年近地面O3和气象观测数据,统计分析了该地区O3变化特征及其与地面气温、相对湿度、风速和风向的关系,并确定了O3的周边源区.结果表明,2015—2019年保定市O3污染呈加重趋势,O3污染超标天数从2015年的63 d增加至2019年的95 d.由于秋冬季昼夜温差较大,导致其O3日变化相对扰动高于春夏季节.O3浓度与近地面气温呈非线性正相关关系,随相对湿度(RH)的增加呈阶段性的先增后减的变化趋势,其中当RH为40%~50%时,O3浓度及其污染超标率均达到最大.此外,风场对O3分布有重要影响,盛行偏南风时易发生O3重污染,表明影响该地区O3污染源区主要位于保定南部.潜在源贡献因子分析方法(PSCF)和浓度权重轨迹分析法(CWT)的分析结果表明,保定市春夏O3源区分布范围最大,其中贡献高值区主要分布在... 相似文献
68.
The Clean Air Act Amendments of 1977 designated national parks and wilderness areas larger than 1894 ha to be class I areas
for air quality management, setting more restrictive criteria than the National Ambient Air Quality Standards. Class I areas
are afforded the greatest degree of air quality protection under the Clear Air Act of 1970. In recent years, several studies
have documented air pollution effects in the Great Smoky Mountains National Park (GSMNP), the second-largest class I area
in the eastern United States. Air pollution problems of greatest concern in the GSMNP are effects of acid deposition, visibility
impairment, and tropospheric ozone. Several recent events have increased concerns about air quality management in the class
I area of the GSMNP. A forum, sponsored by the Southern Appalachian Man and the Biosphere Cooperative (SAMAB), was held in
March 1992, which involved representative. parties-at-interest and began to address strategies for better management of air
resources in the Southern Appalachians. This paper summarizes those discussions and recommendations and reports actions occurring
as a result of the forum. Another objective of this paper is to present a conceptual framework for more effective management
of the class I area of the GSMNP. 相似文献
69.
70.
实验研究了有机废气中的1.1-二氧乙烯(CH2=CCl2)在101.3kPa和288~308K下气相臭氧化降解过程及其反应动力学。结果表明,总的反应级数是2级,相对于臭氧和二氯乙烯浓度均为1级。反应速率常数可用方程Arrhenius(k2=8.32exp[-389.7/T])表示。 相似文献