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571.
针对目前人们对好氧脱氮中气态产物认识不清的问题,采用SBR反应器,以人工配制的NO3--N废水为处理对象,对影响好氧脱氮的COD/N进行了深入研究,测定了三种主要含氮气态产物(NO、NO2、N2O),揭示了好氧状态下生物脱氮的途径和机理。通过对COD/N分别为9、12、15、18的系统氮元素的全程跟踪测定,得到系统内各含氮化合物的变化规律。结果表明,三种气体的产生同COD/N有着密切的关系,低C/N会导致NO、NO2和N2O的积累,最多达总脱氮量的9%。研究结果还表明当进水COD/N为15时,既保证了良好的脱氮效果且抑制了NO、NO2、N2O三种有害气体的大量产生。 相似文献
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垃圾焚烧飞灰中二噁英削减技术研究 总被引:2,自引:1,他引:1
二噁英(PCDD/Fs)是多氯代二苯并二噁英和多氯代二苯并呋喃的总称,因具有生物蓄积性、高毒性、难降解等特点而备受关注。垃圾焚烧是二噁英的重要来源,而其中超过50%的二噁英以飞灰形式排出。文章综述了热分解法、光降解法、机械化学法、生物降解法等飞灰二噁英毒性削减技术的国内外研究进展,并在此基础上对飞灰二噁英削减技术研究和管理提出了建议。 相似文献
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本研究合成了一种新型高效的去除铜绿微囊藻(Microcystis aeruginosa)的氧化石墨烯/季铵盐聚乙烯亚胺(GO/QPEI)纳米复合材料.GO/QPEI在pH为4~10的条件下都具有高效去除M.aeruginosa的能力,其去除能力在2 min内可达96%以上.GO/QPEI对微囊藻的吸附更符合Freundlich方程,最大吸附量为5.58×1011cells·mg-1.吸附动力学表明GO/QPEI的假二级吸附反应.GO纳米片和QPEI的协同效应是其高效去除微囊藻的主要机制. 相似文献
579.
Catalytic oxidation is widely used in pollution control technology to remove volatile organic compounds. In this study, Pd/ZSM-5 catalysts with different Pd contents and acidic sites were prepared via the impregnation method. All the catalysts were characterized by means of N2 adsorption- desorption, X-ray fluorescence (XRF), HE temperature programmed reduction (H2-TPR), and NH3 temperature programmed desorption (NH3-TPD). Their catalytic performance was investigated in the oxidation of butyl acetate experiments. The by-products of the reaction were collected in thermal desorption tubes and identified by gas chromatography/mass spectrometry. It was found that the increase of Pd content slightly changed the catalytic activity of butyl acetate oxidation according to the yield of CO2 achieved at 90%, but decreased the cracking by-products, whereas the enhancement of strong acidity over Pd-based catalysts enriched the by-product species. The butyl acetate oxidation process involves a series of reaction steps including protolysis, dehydrogenation, dehydration, cracking, and isomerization. Generally, butyl acetate was cracked to acetic acid and 2- methylpropene and the latter was an intermediate of the other by-products, and the oxidation routes of typical by-products were proposed. Trace amounts of 3-methylpentane, hexane, 2-methylpentane, pentane, and 2-methylbutane originated from iso4merization and protolysis reactions. 相似文献
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Higher concentrations of Hg can be emitted from coal pyrolysis or gasification than from coal combustion, especially elemental Hg. Highly efficient Hg removal technology from coal-derived fuel gas is thus of great importance. Based on the very excellent Hg removal ability of Pd and the high adsorption abilities of activated carbon(AC) for H2 S and Hg, a series of Pd/AC sorbents was prepared by using pore volume impregnation, and their performance in capturing Hg and H2 S from coal-derived fuel gas was investigated using a laboratory-scale fixed-bed reactor. The effects of loading amount, reaction temperature and reaction atmosphere on Hg removal from coal-derived fuel gas were studied. The sorbents were characterized by N2 adsorption, X-ray diffraction(XRD) and X-ray photoelectron spectroscopy(XPS). The results indicated that the efficiency of Hg removal increased with the increasing of Pd loading amount, but the effective utilization rate of the active component Pd decreased significantly at the same time. High temperature had a negative influence on the Hg removal. The efficiency of Hg removal in the N2-H2S-H2-CO-Hg atmosphere(simulated coal gas) was higher than that in N2-H2S-Hg and N2-Hg atmospheres, which showed that H2 and CO, with their reducing capacity, could benefit promote the removal of Hg. The XPS results suggested that there were two different ways of capturing Hg over sorbents in N2-H2S-Hg and N2-Hg atmospheres. 相似文献