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31.
32.
高效液相色谱法测定水中7种三嗪类除草剂 总被引:1,自引:0,他引:1
采用液液萃取和固相萃取两种方法预处理,高效液相色谱二极管阵列检测器测定水中7种三嗪类除草剂,选择了合适的检测波长和梯度淋洗条件。方法在0.100 mg/L~2.00 mg/L范围内线性良好,检出限为0.06μg/L~0.15μg/L,水样平行测定的RSD为1.6%~6.5%,加标回收率为95.0%~106%。 相似文献
33.
建立了以固相萃取为前处理条件,用液相色谱法测定水中10种硝基苯酚类化合物的分析方法。实验使用HLB(6 L/150 g)固相萃取柱富集水样中的目标化合物,二氯甲烷与乙酸乙酯体积比1:2的混合溶剂洗脱,采用Phenyl柱(4.6 mm×250 mm,5 μm)分离目标化合物,以乙腈(1%甲酸)/水(1%甲酸)为流动相进行梯度洗脱,二极管阵列检测器检测。10种硝基苯酚类物质在0.02~10 mg/L范围内呈现良好的线性。方法检出限为0.1~0.3 μg/L,水样加标相对标准偏差为5.19%~18.2%,平均加标回收率为49.8%~124%。该方法适用于水中10种硝基苯酚类化合物的测定。 相似文献
34.
固相萃取-高效液相色谱法测地表水中11种酚类化合物 总被引:1,自引:1,他引:0
建立了固相萃取-高效液相色谱法同时测定地表水中11种酚类化合物的方法。水样经过全自动固相萃取仪富集,以HLB柱为萃取柱,乙腈(含1%乙酸)为洗脱剂,用高效液相色谱仪分析定量。该方法在0.5~5.0 mg/L范围内线性良好,相关系数为0.999 6~0.999 9,11种酚类化合物的纯水加标回收率为82.0%~111%,地表水加标回收率为98.5%~116%,精密度为3.58%~4.67%,检出限为1×10-4~5×10-4mg/L,该方法简单实用、准确可靠,可用于地表水中酚类化合物的同时测定。 相似文献
35.
HPLC和HPLC-MS/MS测定地表水中酚类化合物 总被引:1,自引:0,他引:1
采用高效液相色谱法(HPLC)和高效液相色谱-三重四级杆质谱联用法(HPLC-MS/MS)测定地表水及饮用水中11种酚类化合物,通过优化测定条件,使HPLC法在0.020 mg/L~50.0 mg/L范围内,HPLC-MS/MS法在0.500μg/L~250μg/L范围内线性良好,方法检出限分别为0.005μg/L~0.031μg/L和0.005μg/L~1.56μg/L。未检出的实际样品加标回收率分别为57.2%~96.7%和81.3%~113%,RSD分别为1.5%~5.3%和3.9%~17.7%。 相似文献
36.
Nabil Semmar Maurice Jay Muhammad Farman Maurice Roux 《Environmental Modeling and Assessment》2008,13(1):17-33
The quantitative assessment of plant diversity and its monitoring with time represent a key environmental issue for management
and conservation of natural resources. Assessment of plant diversity could be based on chemical analyses of secondary metabolites
(e.g. flavonoids, terpenoids), because of the substantial quantitative and qualitative between-individual variability in such
compounds. At a geographical scale, the plant populations become widely dispersed, and their monitoring from numerous routine
individual analyses could become restricting. To overcome such constraint, this study develops a multivariate calibration
model giving the relative frequency of a particular taxon from a simple high-performance liquid chromatography (HPLC) analysis
of a plant mixture. The model was built from a complete set of mixtures combining different taxons, according to an experimental
design (Scheffé’s matrix). For each mixture, a reference HPLC pattern was simulated by averaging the individual HPLC profiles
of the constitutive taxons. The calibration models, based on Bayesian discriminant analysis (BDA), gave statistical relationships
between the contributions of each taxon in mixtures and reference HPLC patterns of these mixtures. Finally, these models were
validated on new mixtures by using outside plants. This new biodiversity survey approach is illustrated on four chemical taxons
(four chemotypes) of Astragalus caprinus (Fabaceae). The more differentiated the taxon, the better predicted its contributions (in mixtures) were by BDA calibration
model. This new approach could be very useful for a global routine survey of plant diversity. 相似文献
37.
Nazan Karsavuran Mohammad Charehsaz Hayati Celik Bayram Murat Asma Cengiz Yakıncı 《毒物与环境化学》2013,95(10):1564-1570
Hydrogen cyanide (HCN) poisoning due to amygdalin (AMY) in apricot seeds is one of the public health issues in Turkey. The aim of this study was to investigate the AMY content of 13 different apricot seeds including bitter and sweet ones, and which are either sulfurized or roasted. The AMY content was determined by a high-performance liquid chromatography. Release of HCN was predicted and total amount of seeds which can cause poisoning was calculated. The mean AMY content of bitter seeds was 26 ± 14 mg g?1 and that of sweet seeds was 0.16 ± 0.09 mg g?1. The consumption of small amounts of bitter seeds may cause cyanide poisoning. 相似文献
38.
河豚毒素检测技术研究进展 总被引:2,自引:0,他引:2
对检测河豚毒素的主要方法包括生物检测方法、理化检测方法、免疫学方法、传感器方法进行了介绍,并对目前检测方法的优缺点进行比较分析。小鼠测定法是河豚毒素检测的标准方法;理化检测法方法准确,但是对设备要求高,前处理严格;免疫学方法费用较高;传感器方法是新方法,还有待进一步规范。各种检测方法都有其优缺点,河豚毒素检测时应根据要求选择方法。 相似文献
39.
J. Christopher Young Zhen‐jian Chen 《Journal of environmental science and health. Part. B》2013,48(2):93-107
Abstract The total alkaloid content and individual alkaloid composition were determined by colorimetry and high performance liquid chromatography, respectively, for Canadian triticale and barley ergot (Claviceps purpurea). The total alkaloid content was highly variable between individual sclerotia from the same or different sources and ranged from 0.042 to 0.752% for triticale and from 0.082 to 1.04% for barley; average values were 0.239% for Ottawa triticale, 0.289% for Prairie triticale, and 0.264% for barley. Ergocristine and its isomer ergocristinine were the major constituents in both grains. On average, Canadian ergot pooled from rye, wheat, triticale, and barley consists of ergocristine (31%), ergocristinine (13%), ergocristinine (13%), ergotamine (17%), ergotaminine (8%), ergocryptine (5%), ergocryptinine (3%), ergo‐metrine (5%), ergometrinine (2%), ergosine (4%), ergosinine (2%), ergocornine (4%), ergocorninine (2%), and unidentified alkaloids (3%) and an average total alkaloid content of 0.236%. With the exception of rye and barley ergot from the maritime regions, Canadian rye, wheat, triticale, and barley ergot is fairly uniform in individual alkaloid composition. 相似文献
40.
Eeva A. Mustonen Tuija Jokela Ilkka Saastamoinen Juhani Taponen Suvi Taponen Hannu Saloniemi Kristiina Wähälä 《Environmental Chemistry Letters》2006,3(4):154-159
An expedient high performance liquid chromatography (HPLC) method was developed for the quantitative analysis of environmental estrogenic isoflavonoids, particularly (S)-equol, in red clover fed ewes. We report here the phytoestrogen analysis of red clover silage and the serum of ewes fed with this feed. Ewes received daily 10.5 g of formononetin on average from red clover silage. In the serum samples a major part of formononetin had been metabolised to equol (average 7.7 μg ml−1). According to chiral HPLC analysis, the equol present in the serum of ewes was solely of the (S)-form. We also demonstrate the presence of the metabolite O-demethylangolensin (O-DMA) in ovine serum. 相似文献