首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   4109篇
  免费   582篇
  国内免费   2507篇
安全科学   316篇
废物处理   223篇
环保管理   333篇
综合类   4035篇
基础理论   942篇
环境理论   1篇
污染及防治   995篇
评价与监测   235篇
社会与环境   100篇
灾害及防治   18篇
  2024年   9篇
  2023年   89篇
  2022年   154篇
  2021年   225篇
  2020年   169篇
  2019年   227篇
  2018年   240篇
  2017年   220篇
  2016年   270篇
  2015年   309篇
  2014年   352篇
  2013年   408篇
  2012年   489篇
  2011年   481篇
  2010年   383篇
  2009年   469篇
  2008年   298篇
  2007年   333篇
  2006年   373篇
  2005年   276篇
  2004年   206篇
  2003年   213篇
  2002年   177篇
  2001年   152篇
  2000年   135篇
  1999年   108篇
  1998年   79篇
  1997年   71篇
  1996年   67篇
  1995年   62篇
  1994年   36篇
  1993年   34篇
  1992年   28篇
  1991年   20篇
  1990年   12篇
  1989年   4篇
  1988年   5篇
  1987年   6篇
  1986年   3篇
  1983年   1篇
  1982年   2篇
  1981年   1篇
  1980年   1篇
  1977年   1篇
排序方式: 共有7198条查询结果,搜索用时 625 毫秒
611.
随着农业氮肥大量施用,大量碳氮营养物质以淋溶或径流形式进入周边灌溉水体,使其成为甲烷(CH4)和氧化亚氮(N2O)的重要排放源.以我国东南部地区典型稻田灌溉河流为研究对象,于2014年9月至2016年9月连续两年原位观测表层水体CH4和N2O溶存浓度及其排放通量,旨在明确稻田灌溉河流CH4和N2O的排放特征、排放强度及其主要驱动因子.结果表明,观测期内c(CH4溶存)的年平均值为(390.57±43.95)nmol·L-1(92.80~1 577.54 nmol·L-1),c(N2O溶存)的年平均值为(40.23±3.20)nmol·L-1(10.05~75.40 nmol·L-1).CH4和N2O的排放通量(年平均)分别为(20.73±6.08)mg·(m2·h)-1和(34.30±7.12)μg·(m2·h)-1.CH4和N2O溶存浓度和排放通量整体上均呈现出春夏排放高,秋冬排放低的季节变化趋势.两年CH4累计排放总量为(3 876.30±1 153.96)kg·hm-2,N2O累计排放总量为(5.74±0.98)kg·hm-2.两者持续性全球增温潜势(SGWP,以CO2-eq计)平均为(87.99±15.73)t·(hm2·a)-1.CH4排放通量与水温、底泥可溶性有机碳(DOC)显著正相关,而与水体溶解氧(DO)显著负相关;N2O排放通量与水温、水中铵态氮(NH4+-N)和硝态氮(NO3--N)显著正相关,而与水体DO显著负相关.该研究可为科学估算我国农业灌溉流域CH4和N2O排放总量提供数据支撑和重要参考.  相似文献   
612.
CO_2地质封存技术是实现碳减排的有效措施,对鄂尔多斯盆地马家沟组马五_1亚段地层水特征进行研究,是下一步实施工程化CO_2封存的首要前提。本文依据对深部钻井取样的直观观察与实验测试,采用单项指标分类评价和多项指标综合评价的方法深入分析了马家沟组马五_1亚段地层水的物理性质、化学性质、地层水类型和水化学特征参数。结果表明:马家沟组马五_1亚段地层水密度较大、矿化度极高,属于卤水,含量最多的离子是Cl~-,其次是Ca~(2+),地层水是CaCl_2型。钠氯系数、氯镁系数、脱硫系数和镁钙系数的分析表明马五_1亚段地层水封闭性极好,处于较强的还原环境。综合分析认为马家沟组马五_1亚段地层水具备实施CO_2封存的良好条件,非常适宜进行CO_2封存。  相似文献   
613.
马心怡  黄文晶  胡凝  肖薇  胡诚  张弥  曹畅  赵佳玉 《环境科学》2023,44(4):2009-2021
目前基于排放清单估算的区域和城市尺度上的人为CO2排放不确定性较大.为了我国实现碳达峰和碳中和的目标,亟需对我国的区域尺度,特别是大城市群的人为CO2排放进行准确估算.分别利用两种先验人为CO2排放数据(EDGAR v6.0清单和EDGAR v6.0联合GCG v1.0的改进清单)作为输入数据,采用WRF-STILT大气传输模型模拟长三角地区2017年12月至2018年2月大气CO2摩尔分数,再以安徽全椒高塔观测的大气CO2摩尔分数作为参考值,通过贝叶斯反演方法得到的比例因子改进了模拟结果,并实现了长三角人为CO2排放通量的估算.结果表明:(1)在冬季,相对于基于EDGAR v6.0模拟的大气CO2摩尔分数值而言,基于改进清单模拟的大气CO2摩尔分数与观测值更为一致;(2)模拟的大气CO2摩尔分数在夜间高于观测值,白天则相反,主要因为排放清单的CO2排放数据不能表征人为...  相似文献   
614.
In this paper, the dynamic relationship between global surface temperature (global warming) and global carbon dioxide emission (CO2) is modelled and analyzed by causality and spectral analysis in the time domain and frequency domain, respectively. Historical data of global CO2emission and global surface temperature anomalies over 129 years from 1860–1988 are used in this study. The causal relationship between the two phenomena is first examined using the Sim and Granger causality test in the time domain after the data series are filtered by ARIMA models. The Granger causal relationship is further scrutinized and confirmed by cross-spectral and multichannel spectral analysis in the frequency domain. The evidence found from both analyses proves that there is a positive causal relationship between the two variables. The time domain analysis suggests that Granger causality exists between global surface temperature and global CO2emission. Further, CO2emission causes the change in temperature. The conclusions are further confirmed by the frequency domain analysis, which indicates that the increase in CO2emission causes climate warming because a high coherence exists between the two variables. Furthermore, it is proved that climate changes happen after an increase in CO2emission, which confirms that the increase in CO2emission does cause global warming.  相似文献   
615.
EDTA直接滴定测定镍   总被引:1,自引:0,他引:1  
参考磷酸在345~356℃时有强腐蚀性的特点,采有硫磷混合酸消解矿样,能使样品消解完全。本方法经加标校核证明,检测结果重现性好,准确度高。  相似文献   
616.
617.
618.
True structural chromosomal mosaicism are rare events in prenatal cytogenetics practice and may lead to diagnostic and prognostic problems. Here is described the case of a fetus carrying an abnormal chromosome 15 made of a whole chromosome 2p translocated on its short arm in 10% of the cells, in association with a normal cell line. The fetal karyotype was 46,XX,add(15)(p10).ish t(2;15)(p10;q10)(WCP2+)[3]/46,XX[27]. Pregnancy was terminated and fetus examination revealed a growth retardation associated with a dysmorphism including dolichocephaly, hypertelorism, high forehead, low-set ears with prominent anthelix and a small nose, which were characteristic of partial trisomy 2p. Possible aetiologies for prenatal mosaicism involving a chromosomal structural abnormality are discussed. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
619.
High-pressure, near-critical liquids were used as float-sink separation media for the microsortation of polyolefin mixtures and PET/PVC mixtures. Near-critical carbon dioxide was used for the refinement of the polyolefins, and sulfur hexafluoride was used to separate post-consumer PVC from PET. Preliminary experiments indicated that there was no overlap in the density ranges of post-consumer HDPE, LDPE and PP containers. There was no overlap in the PET and PVC densities, with the exception of a single PVC packaging material with a density in the PET range. These initial results indicated that a float-sink separation was a viable means of microsortation. Separations of 91% LDPE (1/8′ beads)/9% PP (1/8′ chopped strands) resin mixtures and mixed post-consumer polyolefin flakes were then conducted in a laboratory-scale, 1-I batch apparatus. This apparatus not only permitted the observation of the separation, but also enabled the separated fractions to be removed from the high-pressure environment. The results indicated that LDPE purity of greater than 98.9% was obtained in 3 min or less if (a) the fluid density was 0.018 g/cm3 greater than the PP density and only 0.002 g/cm3 less than the LDPE density, thereby providing the greatest buoyancy force for the removal of the PP, (b) the fluid was recirculated upward through the bed of mixed plastics, facilitating the upward movement of the PP, and (c) the loading was kept at levels below 40% by volume. HDPE purity of 99% was also attained with clean, dry, post-consumer mixed plastic flakes. The loadings for these separations were very low, however, due to the difficulty in agitating the mixed bed of plastics using fluid recirculation. An economic analysis of these microsortation processes indicated that the value of the sorted plastics relative to the mixed feed must increase by approx. $0.08/lb for the CO2-based separation and approx. $0.27/lb for the SF6-based separation to justify the implementation of these high-pressure processes.  相似文献   
620.
Jo WK  Park JH 《Chemosphere》2005,59(11):1557-1573
The present study performed a roadside data analysis to provide baseline data for exploring associations between environmental exposure to four gaseous pollutants and health effects on residents living near roadways. The yearly roadside concentrations of CO and SO2 showed a well-defined decreasing trend, whereas those of NO2 and O3 exhibited the reverse trend. In most cases, the diurnal trends of the roadside concentrations were well-defined for all seasons, plus the daytime concentrations were higher than the nighttime concentrations. In contrast to the other target pollutants, the daytime O3 concentrations observed at the roadside sites were lower than those observed at the residential site, likely due to high-levels of fresh NO from traffic emissions that rapidly react with O3, thereby reducing the O3 roadside level. The Sunday roadside concentrations of CO, NO2, and SO2 were similar to or somewhat lower than the weekday concentrations. Conversely, for O3, the Sunday roadside concentrations were similar to or somewhat higher than the weekday concentrations. The higher O3 concentrations on Sunday may be due to the reduced titration from a decrease in NOx emissions under VOC-limited conditions (low VOC/NOx conditions). The monthly averages of O3 concentrations exhibited the reverse seasonal variation to the other target compounds, with peak O3 concentrations between April and June, and the second peak between August and October. It is also suggested that for O3, the 8-h standard is more stringent than the 1-h standard, while for NO2 and SO2, the 1-h standard is more stringent than the 24-h standard. The multiple regression equations obtained from the relationship between the concentrations and five meteorological parameters indicated that the number and type of meteorological variables in the equations varied according to the pollutant, monitoring station, or season.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号