厚软场地上大跨径桥梁设计反应谱研究

大跨径桥梁塔高、跨径大、自振周期长,深厚、软弱场地的长周期地震动对桥体结构影响较大。我国《公路工程抗震设计规范(JT J004-89)》也只适用主跨不超过150 m的梁桥和拱桥,国内长期以来没有一个适用于大跨径桥梁的抗震设计规范或指南。本文结合大跨径桥梁工程实例,根据场地土层静、动力性能参数的原位测试和动三轴试验结果,进行厚软场地土层地震反应分析,研究厚软场地的地震动效应,讨论了不同地震动强度时厚软场地的设计反应谱特征,分析了现行规范设计反应谱应用的局限性,成果对相关工程有重要指导意义,对大跨径桥梁抗震设计规范的制定也有借鉴作用。     

油田注水泵房噪声治理

调查了油田注水泵房噪声的基本情况.根据噪声来源和特性制定了治理方案,分析了试验应用效果.     

沈阳市环境铅污染对儿童健康的影响

实地调查采样、结合GIS技术进行室内综合分析,系统研究了沈阳市大气、土壤、灰尘中铅污染对儿童健康的影响.结果表明,沈阳市环境中铅暴露普遍,铅污染较严重,铅浓度空间分异大,已形成4个高浓度中心.并且大气铅浓度有明显的日、季和年变化规律沈阳市环境铅污染已经影响了儿童健康,0～10岁儿童(ZPP＞2.3μmol/L)血铅范围是10.98～511.2μg/L,平均值是135.59μg/L,40%的儿童血铅水平超标.儿童血铅与大气铅相关性最大,其次是土壤和灰尘.实行无铅汽油之后,大气铅污染有了很大改善,但是土壤和灰尘中的铅容易以扬尘的方式再次进入大气,存在潜在风险,应引起有关部门足够的重视.     

Co-fermentation of waste activated sludge with food waste for short-chain fatty acids production: effect of pH at ambient temperature

Effect of pH ranging from 4.0 to 11.0 on co-fermentation of waste activated sludge (WAS) with food waste for short-chain fatty acids (SCFAs) production at ambient temperature was investigated in this study. Experimental results showed that the addition of food waste significantly improved the performance of WAS fermentation system, which resulted in the increases of SCFAs production and substrate reduction. The SCFAs production at pH 6.0, 7.0, 8.0, and 9.0 and fermentation time of 4 d was respectively 5022.7, 6540.5, 8236.6, and 7911.7 mg COD·L^-1, whereas in the blank tests (no pH adjustment, pH 8.0 (blank test 1), no food waste addition, pH 8.0 (blank test 2), and no WAS addition (blank test 3)) it was only 1006.9, 971.1, and 1468.5 mg COD·L^-1, respectively. The composition of SCFAs at pH from 6.0 to 9.0 was also different from other conditions and propionic acid was the most prevalent SCFA, which was followed by acetic and n-butyric acids, while acetic acid was the top product under other conditions. At pH 8.0 a higher volatile suspended solids (VSS) reduction of 16.6% for the mixture of WAS and food waste than the sole WAS indicated a synergistic effect existing in fermentation system with WAS and food waste. The influence of pH on the variations of nutrient content was also studied during anaerobic fermentation of the mixture of WAS and food waste at different pH conditions. The release of NH4+-N increased with fermentation time at all pH values investigated except 4.0, 5.0 and in blank test one. The concentrations of soluble phosphorus at acidic pHs and in the blank test one were higher than those obtained at alkaline pHs. Ammonia and phosphorus need to be removed before the SCFAs-enriched fermentation liquid from WAS and food waste was used as the carbon source.     

土地利用变化对生态系统服务的影响研究综述

土地利用/覆被变化是全球环境变化的重要组成部分和主要原因之一,不仅带来了地表结构的巨大变化,而且对生态系统服务也造成重要影响。土地利用变化和生态系统服务研究已成为国际上生态学和地理学等跨学科研究的热点之一。从土地利用变化和生态系统服务的概念及其影响因素分析入手,综述了土地利用面积变化、土地利用方式变化和土地利用空间格局变化等对生态系统服务的影响,归纳了土地利用变化对生态系统服务的影响研究的主要方法和模型,分析了相关研究的不足,并提出了加强生态系统服务动态评估方法和时空动态评估模型的研究、强化土地利用变化对生态系统服务影响的生态学机制研究和注重土地利用变化下生态系统服务评估结果的集成应用研究等建议,以期对我国的土地利用变化与生态系统服务评估研究提供科学参考。     

Estimating the uncertainty of pesticide residue analysis from mango using multi-residue analysis and validation of method

Validation of method was performed for various pesticides on mango matrix involving the processing of sample at ambient and cryogenic conditions. The linearity, limits of detection, repeatability, matrix effect, and recovery were studied as the aspects of method validation. The effect of matrix on recovery was found to be medium (20–50%) and strong (>50%). After correction by matrix-matched calibration curves, the recovery was calculated to be in the range of 80–107% and 80–105% at ambient and cryogenic processing, respectively. The precision estimated for the recovery of pesticides obtained from both solvent- and matrix-matched calibration curves and at both the processing conditions was determined to be >20% except for chlorpyrifos and atrazine. The uncertainty established for the methodology was >20%, which substantiates the efficiency and reliability of methodology used for pesticide residue analysis in mango in this study.     

Removal of methylene blue by coupling black carbon adsorption with TiO2 photodegradation

In this study, the removal of methylene blue (MB) by the coupling of black carbon (BC) and TiO₂ was investigated. The effects of different parameters such as catalyst dose, sorbent, initial concentrations of dye, pH of the solutions, recycles on discoloration, and chemical oxidation demand (COD) reduction of MB were monitored to optimize the reaction conditions. The discoloration and COD conversation rate of MB obtained by the coupling process were 100% after 90?min irradiation. The synergistic effect of MB-adsorption on BC followed by degradation through TiO₂ photocatalysis was proved by FT–IR spectrophotometer. The BC as by-product of natural materials is a promising adsorbent for waste water treatment.     

Polarographic investigations on the complexation of cadmium and zinc by thiol peptides

Complex formation of Cd²⁺ and Zn²⁺ with thiol derivatives has been investigated by differential pulse polarography. The binding of Cd²⁺ and Zn²⁺ with cysteine (CySH), glutathione (GSH) and the model peptide N‐acetyl‐cysteine‐methylamide (ASH) reveals different stoichiometry. Thus, Cd²⁺ forms 1:1 and 1:2 complexes with CySH while 1:2 and 1:4 complexes have been observed with GSH and ASH, respectively. Overall formation constants of Cd²⁺ with CySH (Iogβ ₂ 15.3) and with GSH (Iogβ5₂ 14.4) have been estimated using competitive complexation with nitrilotriacetic acid (NTA). Investigation of competition between Zn²⁺ and Cd²⁺ for the thiol complexation has underlined the role played by the amino group in CySH for the stabilization of Zn complexes in contrary to Cd complexes.     

Structural effect on photocatalytic degradation of metallised azo dyes in aqueous TiO2 suspension

Three metallised azo dyes were investigated under TiO₂‐photocatalytic and photosensitised conditions in aqueous buffering solutions. The degradation follows apparent first‐order kinetics. The size and strength of intramolecular conjugation determine the light‐fastness of the investigated dyes. Compared with ¹O₂ produced in photosensitised process, the more powerful *OH radicals in TiCO₂ photocatalytic process are highly reactive towards the investigated azo dyes. And as a result, the TiO₂‐photocatalysis makes little less distinction in the degradation kinetic data of the azo dyes compared with the photosensitised degradation of them.     

多米诺事故情景下的区域环境风险评价

将多米诺效应纳入化工区环境风险评价中,采用扩展概率模型和蒙特卡洛模拟的方法计算多米诺事故的概率,运用大气和水扩散模型模拟污染事故的后果,进而利用地理信息系统分析在多米诺事故情景下的区域环境风险水平.结果表明,研究区域67.5%的风险源能引发二次事故,平均每个初始事故引发9.58次二次事故、17.21次三次事故.二次事故情景和三次事故情景下的区域环境风险值分别是一次事故的6.40倍和12.33倍,多米诺效应明显放大了区域环境风险值,应成为今后风险防范的重点.