全球气候变化的研究与进展

论述了全球气候变化的研究目标、方法、主要科学问题及近10年来国内外的研究进展和存在的主要问题。指出中国是全球的一个组成部分,又是人类活动最为强烈的地区之一,在全球气候变化、特别是人类活动诱发的气候变化的研究中占有十分重要的地位。建议大力加强全球气候变化的研究,增加研究经费的投入,积极参与国际科学合作,把当前较为分散的研究有效地组织到一些有前景的、能出高水平成果的课题上去,为全球气候变化研究做更大的贡献。     

多种农药对胎儿发育的联合作用分析

分析了应城农村１２万确定人群中１９８８－１９８９年２年期间出现妊娠出现妊局的妇女的前瞻性流行病学调查资料。共调查了５６７４位妇女。按照期家中使用的药品种数目,将研究对象分为０、１、２、３、４、５、≥和总组,计算了各组发生各种不良妊娠结局的相对度,结果表明。所暴露的农药品种数愈多,发生自然流产和出生缺陷的危险度愈大。农药品种数与它们对胎儿发育的不良影响之间存在“剂量－效应关系”。由此得出结论;多种农     

非点源污染的管理及控制

非点源污染是指溶解的或固体污染物从非特定的地域,在降水和径流冲刷作用下,通过径流过程而汇入受纳水体引起的水体污染,主要起源于土壤侵蚀,农药与化肥的施用,农村家畜粪便与垃圾,农田污水灌溉,城镇地表径流,林区地表径流和大气干湿沉降等污染源。     

气象因素对杭州城市空气质量的影响

利用杭州城市环境空气中污染物浓度与气象观测数据的相关性，分析气象因素对环境空气质量的影响情况，提出在杭州市区大气污染防治中必须首先予以考虑并着力解决的几个问题。     

氮肥使用对北方夏玉米季氨挥发的影响

氨挥发是农田作物生产中氮肥损失的主要途径之一,对空气质量有重要影响.为研究我国北方地区化肥类型、施用数量、施氮时期以及采样方法等因素对夏玉米季氨挥发的影响,本研究收集了1980~2018年发表的北方地区夏玉米生产中氨挥发的研究文献,并对数据进行统计分析.结果发现,随着化肥施氮量的增加,氨挥发总量呈指数型增长,净氨挥发量呈幂函数型增长.基肥/追肥施氮量为1/1时,追肥期氨挥发总量和净氨挥发量显著高于基肥期（P<0.05）,氨挥发总量分别约占总生育期的58.4%和41.6%.随着施氮量的增加,激发效应先表现为负效应后逐渐转变为正效应,转折点施氮量为297 kg ·hm^-2.采用抽气法与海绵法测定的氨挥发量存在显著差异（P<0.01）,且抽气法测定数据更为稳定.施用缓释尿素相较于普通尿素可降低氨挥发约20%~50%.我国北方夏玉米生产中,合理控制追肥期施氮量更有助于减少氨挥发,且高氮肥条件下抽气法比海绵法更适合于氨挥发的测定.     

Evaluation of the impact of matrix effects in LC/MS measurement on the accurate quantification of neonicotinoid pesticides in food by isotope-dilution mass spectrometry

The use of isotope-labeled internal standards is the most widely accepted approach to overcome the matrix effects on quantification of pesticides in food by LC/MS. We evaluated the impact of the matrix effects on quantification of six neonicotinoid pesticides, acetamiprid, clothianidin, dinotefuran, imidacloprid, thiacloprid, and thiamethoxam, in food by using deuterated internal standards. The calibration curves for each pesticide were obtained by using matrix-free and matrix-matched calibration solutions with blank brown rice, carrot, and green onion extracts. For brown rice and carrot, the matrix effects were not observed. In contrast, the slopes of calibration curves for each pesticide were influenced by presence of green onion extracts in calibration solutions (variability of the slopes was 4–9%), because the ratios of peak area for native pesticide to those for internal standards were influenced by matrix. The spike-and-recovery test with green onion was also performed. The analytical values obtained by using matrix-free calibration solution were biased from the spiked concentration, whereas those obtained by using matrix-matched calibration solution were comparable to the spiked concentration. These results indicate that matrix-matched calibration solution should be used for accurate quantification of neonicotinoid pesticides in food by LC/MS using deuterated internal standards.     

Evaluating the usability of a commercial cooling vest in the Hong Kong industries

Objective. The provision of appropriate personal cooling vests is recognized as an effective measure to combat heat stress. However, personal cooling vests are not widely implemented in the Hong Kong industries. The current study aims to evaluate the usability of a hybrid cooling vest that is associated with the success of its application in industrial settings. Methods. A self-administrated questionnaire focusing on 10 subjective attributes of cooling effect, ergonomic design and usability of a hybrid cooling vest was administered with 232 occupational workers in the construction, horticultural and cleaning, airport apron services and kitchen and catering industries. Results. A structural equation model estimated by analysis of moment structures was constructed to evaluate the usability of the cooling vest, as influenced by cooling effect and ergonomic design. Results showed that cooling effect (path coefficient?=?0.69, p?p?Conclusions. The structural equation model is feasible to examine the complex nature of the structural relationships among the subjective perceptions of personal cooling vests. The empirical findings furnish sound evidence for further optimization of the hybrid cooling vest in terms of cooling effect and ergonomic design for occupational workers.     

转盘式光催化燃料电池处理染料废水

采用阳极氧化法制备转盘式TiO_2阳极,设计并开发了转盘式光催化燃料电池(PFC),探讨了圆盘转速对PFC中染料降解效果的影响。实验结果表明:随着圆盘转速的提高,污染物和光电界面反应产物的传质作用得以强化,罗丹明B降解率提高;在圆盘转速为1 600 r/min、反应时间为60 min的条件下,罗丹明B降解率达90.8%,是圆盘转速为0 r/min时的8.5倍;光电流也随着圆盘转速的提高而提高,但提高幅度远小于罗丹明B降解率的提高幅度;同时,加强传质作用后再外加电压对PFC催化降解性能的提高作用有限。     

杭州快速路、主次干道植物群落降噪功能比较研究

城市绿地是城市生态系统的重要组成部分,在改善城市生态系统方面有重要作用。现今交通是城市环境中的主要噪声来源,城市道路绿地是交通噪声治理的有效方式之一。本文选取杭州市西湖区不同等级的三条道路(紫金港路、天目山路和丰潭路)作为研究对象,利用手持噪声测量仪测量实时噪声对不同道路等级和距离的绿地降噪效果进行分析。研究发现,杭州市三条道路存在以下问题:(1)噪声距离道路越远越低,且噪声平均衰减率表明绿地降噪效果为主干道次干道快速路;(2)配置模式为乔木+灌木+地被的绿地植物群落的降噪效果最佳,且乔木和灌木交错的种植形式在降噪效果上优于灌木在前、乔木在后的排列式种植;(3)当道路绿地宽达到15m时,植物群落降噪效果会有大幅度提升,且快速路与次干道在距离为15m处,植物群落降噪能力最佳。     

易分解碳输入模式对沉积物共代谢效应的影响

通过构建室内微宇宙系统,运用稳定碳同位素示踪法,解析混合处理组中各有机组分代谢释放的CO2含量,探讨相对易分解碳源的输入对湖泊沉积物有机碳矿化过程的影响.结果表明:添加相对易分解碳源的处理组中,CO2排放量明显升高,较对照组分别提高了45.49％(单次添加组)、52.61％(重复添加组)和57.65％(连续添加组),分...