高压低流电化学深度处理砷氟废水技术研究

为解决企业外排生产废水砷氟超标问题,采用高压低流电化学技术对某矿山企业外排的含砷氟废水进行深度处理,研究考察进水pH值,电流密度,电化学反应时间、极板材料、絮凝反应、pH等工艺条件对处理效果的影响。得到2最佳工艺条件为进水pH5.5左右、絮凝pH6.5~7.0、电化学反应时间6 min,铁铝极板比例为1:2,电流密度10.9 m A/cm。处理出水中的砷、氟能稳定达到《地表水环境质量标准》(GB3838—2002)Ⅲ类水体水质标准要求。     

AHP-FUZZY综合评价法在确定清洁生产审核重点中的应用研究——以武汉市某电源公司为例

清洁生产审核是将清洁生产理念转变为企业层次上操作的具体程序,在进行审核时首要步骤是确定审核重点。现阶段确定审核重点主要运用权重总和计分排序法,该方法易受审核者主观影响,审核质量不易控制。AHP-Fuzzy综合评价法作为一种系统分析方法很好地弥补了权重总和计分排序法的不足,在系统工程的很多领域都有广泛应用。通过确定银泰电源公司清洁生产审核重点,建立七工段层次模型:确立目标,明确问题;建立系统的层次结构;构造判断矩阵;进行层次的单排序及一致性检验;进行层次总排序一致性检验;根据排序结果,提出决策建议,验证了该综合评价法在清洁生产审核应用中的科学性、可行性和准确性,能将比较复杂、不够确定的多因素问题转化为有数字依据的简单易行的评价模式,为企业清洁生产的定量考核和指标化管理提供了一个科学的评价方法。     

氢化物发生-原子荧光光谱法测定废水中砷探讨

砷是对人体有害的元素,当人体每天的摄入量超过100ug或更高时,对人体就会产生严重的危害,而有些工业废水中合有一定量的砷元素,如果这些工业废水不经处理排放到水中会我们的身体造成很大程度的伤害,所以我对某工厂的工业废水进行检测,检测其排放废水中所含有砷元素的多少。火焰原子荧光和石墨炉原子荧光的检测能力无法满足测定的要求,...     

近地面臭氧污染过程和相关气象因子的分析

为了了解₃的污染过程,进行了包括全天24h₃浓度和气象参数的观测。分析了高浓度₃日的气象条件,表明高压天气形势、晴天少云、日照持续、气温升高、湿度低、温度垂直梯度和Ri数较高等是形成高浓度₃的有利条件。从₃浓度全天24h的观测结果发现,除12:00～14:00的主峰外,在0:00～4:00还有一个次峰。所有例子都表明₃浓度日变化和各气象因子有着很好的对应关系,值得注意的是,当风速和太阳辐射同步增减时,共同促使₃浓度增大,使₃在中午出现显著的峰值,当风速值出现在其他时间时,也可以使₃出现次峰。      

铝土矿改性方法的研究

以廉价的铝土矿为原料,辅以适当添加剂,经简单处理,在７００℃－８００℃的温度下灼烧３ｈ,即可制成能够去除水中高浓度ＳＯ＾２－４的高效净水剂。将该净水剂加到适量的高浓度ＳＯ＾２－４水中,处理３０ｍｉｎ,就能达到国家饮用水标准。     

Impact of Fly Ash from Coal-Fired Power Stations in Delhi, with Particular Reference to Metal Contamination

Indraprastha Power Station (IPP Stn) and Rajghat Power House (RPH), owned by Delhi Electric Supply Undertaking, are both coal-fired power stations located on Ring Road in New Delhi. Ash content of the coal used ranges between 38–47%. The ash is collected in electrostatic precipitators which have an efficiency of 99.3% (IPP station), and 99.7% (RPH). There are instances of major dust pollution around the power stations from fly ash dispersal. The main method of disposal of fly ash from the power stations is by mixing with water, the resultant slurry is pumped through pipes to ash disposal ponds. The supernatant from these ponds is discharged into River Yamuna. Field studies have revealed large quantities of fly ash being deposited into the river. Local populations of Eichhornia crassipes have reduced dramatically between 1987–1995, with a marked reduction in the year 1994–1995. Field studies, conducted in January, 1995 have investigated the impact of fly ash dispersal in the Delhi region with particular reference to metal contamination. Elemental concentrations for a range of elements are determined by ICP-AES in fly ash and top soils along four transects from the power stations up to a distance of 8 km. The effects of fly ash leachates from the ash settling ponds on the river are determined by analyzing river overbank soils and vegetation for their elemental contents. It is concluded that fly ash dispersal from the stacks are a source of alkali, alkaline-earth and to some extent heavy metals in soils in the vicinity of the power stations, and enrichment of elements in river overbank soils are a result of discharge of fly ash leachates from ash disposal ponds. However, the impact from both these sources of metal contamination is not large enough to give cause for concern. Marked reduction in populations of Eichhornia crassipes downstream of the river where it receives leachates from the ash disposal ponds are attributed to turbidity of the ash pond leachates and metal toxicity. Elemental enrichment in the floodplain soils, as a result of fly ash particle deposition during monsoons, may enhance the horticultural value of these soils as is shown by a healthy cultivated crop of Brassica juncea.     

高压静电应用在饮食业油烟净化上的设计

饮食业油烟排放时对大气产生较严重污染 ,本文介绍了高压静电在油烟净化上应用的原理和净化器的设计参数。     

A pyrazine based metal-organic framework for selective removal of copper from strongly acidic solutions

● pz-UiO-66 was synthesized facilely by a solvothermal method. ● Efficient capture of copper from highly acidic solution was achieved by pz-UiO-66. ● pz-UiO-66 exhibited excellent selectivity and capacity for copper capture. ● Pyrazine-N in pz-UiO-66 was shown to be the dominant adsorption site. The selective capture of copper from strongly acidic solutions is of vital importance from the perspective of sustainable development and environmental protection. Metal organic frameworks (MOFs) have attracted the interest of many scholars for adsorption due to their fascinating physicochemical characteristics, including adjustable structure, strong stability and porosity. Herein, pz-UiO-66 containing a pyrazine structure is successfully synthesized for the efficient separation of copper from strongly acidic conditions. Selective copper removal at low pH values is accomplished by using this material that is not available in previously reported metal–organic frameworks. Furthermore, the material exhibits excellent adsorption capacity, with a theoretical maximum copper uptake of 247 mg/g. As proven by XPS and FT-IR analysis, the coordination of pyrazine nitrogen atoms with copper ions is the dominant adsorption mechanism of copper by pz-UiO-66. This work provides an opportunity for efficient and selective copper removal under strongly acidic conditions, and promises extensive application prospects for the removal of copper in the treatment for acid metallurgical wastewater.     

电力配电房在火灾下的有限元模拟分析

针对钢框架结构形式的电力配电房在基本荷载组合工况下构件承载能力的关键问题,运用ABAQUS有限元分析软件对模型进行空间静力分析,得出电力配电房在各种工况下的最不利荷载及其位置;针对电力配电房在火灾工况下构件耐火性能的关键问题,运用ABAQUS模拟分析其在火灾工况下的温度场分布和钢框架结构的承载能力和力学性能,并对这两类工况对比分析。研究结果表明:在基本荷载工况下,电力配电房在恒荷载与活荷载形成的组合效应下产生的沿X、Y、Z方向的剪力和弯矩最大,且其形成的竖向位移也最大;在火灾工况下,电力配电房最大应力位置与普通荷载工况大致相同,但最大位移位置不同;虽有局部钢材应力超限,但钢框架结构仍具备承载能力,设计人员可将应力超限的构件替换为屈服强度更高的钢材而非全部替换,既保证了整体结构的安全性,又达到节约材料降低造价的目的。     

高氟饮用水脱氟技术

综合了国内目前使用的高氟饮用水脱氟技术，重点介绍两种已用于设备制作的脱氟技术－－活性氧化铝和活化沸石。目的介绍了于高氟地区。对饮用水进行脱氟，对氟的地方病进行治理。