全文获取类型
收费全文 | 737篇 |
免费 | 17篇 |
国内免费 | 55篇 |
专业分类
安全科学 | 87篇 |
废物处理 | 8篇 |
环保管理 | 98篇 |
综合类 | 397篇 |
基础理论 | 65篇 |
污染及防治 | 45篇 |
评价与监测 | 71篇 |
社会与环境 | 28篇 |
灾害及防治 | 10篇 |
出版年
2024年 | 3篇 |
2023年 | 8篇 |
2022年 | 15篇 |
2021年 | 19篇 |
2020年 | 17篇 |
2019年 | 17篇 |
2018年 | 11篇 |
2017年 | 17篇 |
2016年 | 24篇 |
2015年 | 20篇 |
2014年 | 26篇 |
2013年 | 31篇 |
2012年 | 23篇 |
2011年 | 43篇 |
2010年 | 21篇 |
2009年 | 33篇 |
2008年 | 24篇 |
2007年 | 34篇 |
2006年 | 38篇 |
2005年 | 39篇 |
2004年 | 32篇 |
2003年 | 26篇 |
2002年 | 37篇 |
2001年 | 35篇 |
2000年 | 20篇 |
1999年 | 26篇 |
1998年 | 16篇 |
1997年 | 15篇 |
1996年 | 7篇 |
1995年 | 25篇 |
1994年 | 15篇 |
1993年 | 10篇 |
1992年 | 12篇 |
1991年 | 6篇 |
1990年 | 11篇 |
1989年 | 10篇 |
1988年 | 6篇 |
1987年 | 6篇 |
1986年 | 8篇 |
1985年 | 4篇 |
1984年 | 7篇 |
1983年 | 6篇 |
1982年 | 3篇 |
1979年 | 1篇 |
1978年 | 2篇 |
排序方式: 共有809条查询结果,搜索用时 589 毫秒
41.
42.
采用固相萃取/高效液相色谱-三重四级杆质谱法同时测定医疗废水中的20种超痕量抗生素残留,通过优化试验条件,使方法在100μg/L~100μg/L范围内线性良好,方法检出限为024ng/L~122ng/L。空白水样和实际水样3个质量浓度水平的加标回收率分别为80.2%~108%和75.8%~114%,6次测定结果的RSD分别为2.4%~8.4%和1.7%~8.1%。将该方法用于测定重庆市2家三甲医院医疗废水中的超痕量抗生素残留,结果有11种抗生素检出,其余均为未检出。 相似文献
43.
44.
This study has indicated that there is close relationship between development density and environmental quality; therefore,
it is necessary to decide the form of development carefully beforehand. The form of development is shaped either by new development
or urban renewal which is a major tactic nowadays adopted by the Hong Kong Government to improve the living condition of the
citizens and the quality of the built environment. This study is limited to urban renewal and aims to find out the major urban
design considerations for sustaining the environment. Through a questionnaire survey carried out in Hong Kong, the opinions
of architects, planners, property development managers, and local citizens were sought and evaluated, and critical design
factors for enhancing environmental sustainability of urban renewal projects are highlighted. The results derived from factor
analysis indicated that certain design considerations should be incorporated for sustaining the urban environment. “Land Use
Planning”, “Quality of Life”, “Conservation & Preservation”, “Integrated Design”, “Provision of Welfare Facilities”, and “Conservation
of Existing Properties” were believed to be the significant underlying factors for achieving environmental sustainability
of local urban renewal projects.
Readers should send their comments on this paper to: BhaskarNath@aol.com within 3 months of publication of this issue. 相似文献
45.
M. Reza Ghanbarpour Keith William Hipel 《Environment, Development and Sustainability》2009,11(2):241-253
Environmental disputes arise due to opposing views of various groups about their environmental concerns and their economic
or developmental interests. Development and protection of the environment constitute two main contradictory objectives within
the sustainable development paradigm, which are often in conflict. The decision support system, GMCR II, which implements
the graph model for conflict resolution, is employed to model and analyze an environmental dispute arising over the construction
of a new freeway between the Iranian capital, Tehran, and the city of Chalous located in the north of the country. This study
demonstrates that the graph model for conflict resolution can be used as a methodology to promote a reasonable balance between
economic development and environmental protection from a strategic viewpoint. In addition to systematically modelling the
conflict by putting the existing information into proper perspective, it is shown how conflict analysis can be used for comparing
alternative scenarios and predicting possible future outcomes.
Readers should send their comments on this paper to: BhaskarNath@aol.com within 3 months of publication of this issue. 相似文献
46.
Sarah B. Gewurtz Nilima Gandhi Guttorm N. Christensen Anita Evenset Dennis Gregor Miriam L. Diamond 《Environmental science and pollution research international》2009,16(2):176-190
Background, aim, and scope
Lake Ellasjøen, located in the Norwegian high arctic, contains the highest concentrations of polychlorinated biphenyls (PCBs) ever recorded in fish and sediment from high arctic lakes, and concentrations are more than 10 times greater than in nearby Lake Øyangen. These elevated concentrations in Ellasjøen have been previously attributed, in part, to contaminant loadings from seabirds that use Ellasjøen, but not Øyangen, as a resting area. However, other factors, such as food web structure, organism growth rate, weight, lipid content, lake morphology, and nutrient inputs from the seabird guano, also differ between the two systems. The aim of this study is to evaluate the relative influence of these factors as explanatory variables for the higher PCB fish concentrations in Ellasjøen compared with Øyangen, using both a food web model and empirical data.Methods
The model is based on previously developed models but parameterized for Lakes Ellasjøen and Øyangen using measured data wherever possible. The model was applied to five representative PCB congeners (PCB 105, 118, 138, 153, and 180) using measured sediment and water concentrations as input data and evaluated with previously collected food web data.Results
Modeled concentrations are within a factor of two of measured concentrations in 60% and 40% of the cases in Lakes Ellasjøen and Øyangen, respectively, and within a factor of 10 in 100% of the cases in both lakes. In many cases, this is comparable to the variability associated with the data as well as the efficacy of the predictions of other food web model applications.Discussion
We next used the model to quantify the relative importance of five major differences between Ellasjøen and Øyangen by replacing variables representing each of these factors in the Ellasjøen model with those from Øyangen, in separate simulations. The model predicts that the elevated PCB concentrations in Ellasjøen water and sediment account for 49%–58% of differences in modeled fish PCB concentrations between lakes. These elevated sediment and, to a lesser extent, water concentrations in Ellasjøen are due to PCB loadings from seabird guano. However, sediment–water fugacity ratios of PCBs are consistently greater in Ellasjøen compared with Øyangen, which suggests that internal lake processes also contribute to differences in sediment and water concentrations. We hypothesize that the nutrients associated with guano influence sediment–water fugacity ratios of PCBs by increasing the stock of pelagic algae. As both these algae and the guano settle, their organic carbon content is degraded faster than PCBs, which causes an extra magnification step in Ellasjøen before these detrital particles are consumed by benthic organisms, which are in turn consumed by fish. The model predicts that the remaining ~50% of the differences in PCB concentrations observed between the fish of these lakes are due to other subtle differences in their food web structures.Conclusions
In conclusion, based on the results of a food web model, we found that the most dominant factors influencing the higher PCB fish concentrations in Lake Ellasjøen compared with Øyangen are the higher sediment and water concentrations in Ellasjøen, caused by seabird guano. Together, sediment and water are predicted to account for 49%–58% of differences in fish concentrations between lakes. Although seabird guano provides a source of nutrients to the lake, in addition to contaminants, empirical data and indirect model results suggest that nutrients are not leading to decreased bioaccumulation, in contrast to what has been observed in temperate, pelagic food webs.Recommendations and perspectives
The results of this study emphasize the importance of considering even small differences in food web structure when comparing bioaccumulation in two lakes; although the food web structures of Ellasjøen and Øyangen differ only slightly, the model predicts that these differences account for most of the remaining ~50% of the differences in PCB fish concentrations between the two lakes. This study further demonstrates the utility of food web models as we were able to predict and tease apart the influence of various factors responsible for the elevated concentrations in the fish from Lake Ellasjøen, which would have been difficult using the field data alone. 相似文献47.
高压密闭消解土壤砷、汞、铅、镉酸体系比较 总被引:5,自引:1,他引:4
采用高压密闭消解系统消解土壤,氢化物发生-原子荧光光谱法(HG-AFS)测定As和Hg,石墨炉原子吸收光度法(GF-AAS)测定Pb和Cd,对比了不同消解酸体系对国家土壤标准参考样中As、Hg、Pb、Cd的消解效果。结果表明,盐酸-硝酸体系对As、Hg、Pb和Cd的消解平均回收率分别为26.1%、100.6%、69.7%、87.3%;硝酸-高氯酸-氢氟酸体系中As、Hg、Pb和Cd消解平均回收率分别为109.9%、84.7%、87.5%、90.1%;硝酸-双氧水体系对Hg、Pb、Cd消解平均回收率分别为104.8%、95.1%、93.3%,对As的回收率虽只有69.2%,但数据精密度最好。此外,从简化试验步骤,减少误差,提高检测效率及减少试验危险性等方面综合评价,认为硝酸-双氧水消解体系是采用高压密闭系统消解土壤重金属的最理想酸体系。 相似文献
48.
Mingming Lu Prabhat Lamichhane Fuyan Liang Eric Imerman Ming Chai 《Water, Air, & Soil Pollution: Focus》2008,8(3-4):359-367
The odorous air emissions from confined animal feeding operations (CAFOs), such as swine, poultry and dairy farms, are increasingly
raising community complaints. Odorous emissions can result in health damages, psychological discomforts and adverse aesthetic
effects in the community. However, these emissions are not well characterized up to now due to the lack of legislation, the
limitations in sampling and instrumentation techniques, and the complexity of the emissions themselves. This study is aimed
at the development of a high volume sampler and sorbent assembly to identify the odor causing compounds from a diary CAFO.
The sorbent was custom designed to target the potential compounds that may exist in a dairy farm and was validated in laboratory
with a synthetic odor from the swine manure. The actual samples at the diary farm were collected in spring and summer of 2005.
The sorbents were solvent extracted and individual odor compounds were identified using GC–MS (gas chromatography–mass spectroscopy).
The data obtained indicated that high volume sampling can shorten the sampling time from days to within 4 h. Both volatile
organic compounds (VOCs) and volatile fatty acids (VFAs) have been identified from the dairy farm, such as phenol, methylphenol,
4-ethyl phenol, indole, methyl indole, benzyl alcohol, hexanoic acid, valeric acid and iso-valeric acid, together with some nitrogen containing compounds that have not been reported before. 相似文献
49.
以硝酸银和硫酸铬钾代替硫酸汞来消除 COD 测定中的氯离子干扰,同时将重铬酸钾溶液的浓度降低为0.100 mol/L,并用硫磷混酸代替硫酸,该方法经过对标准样品和实际样品的测定,表现出对于测定氯离子含量低于25000 mg/L的高氯低 COD 值水样具有较好的准确度和精密度,同时可以实现银盐的回收再利用。 相似文献
50.
北京市某高层建筑高空电磁辐射环境影响分析 总被引:1,自引:0,他引:1
王璟 《环境监测管理与技术》2014,26(1):61-65
选取北京市某代表性高层居民楼顶平台作为高空电磁辐射环境水平监测点进行综合场强和选频监测,评价总体电磁辐射环境水平,并分析监测区域电磁辐射能量的来源。结果表明:该高空监测区域的电磁辐射环境总体水平低于国家规定的公众照射导出限值,但高于地面水平。监测区域主要受30 km 外的中波台影响,其次是9 km 外的中央电视塔。影响最大的是639 kHz频率的中波信号,占100 kHz~300 MHz总场强的95%以上,其次是1.28 MHz频率的中波信号。提出,开展敏感建筑物规划建设时,应考虑中波的传播特性和对环境的影响。 相似文献