Attenuation of N2O emission rates from agricultural soil at different dicyandiamide concentrations

An experiment was conducted to assess the role of different concentrations of dicyandiamide (DCD), a potent nitrification inhibitor, on temporal changes in nitrous oxide emission from sandy loam agricultural soil. It was found that with increasing concentration of DCD i.e. from 6 to 12% of nitrogen applied in the form of urea, there was a decrease in the both average and peak N₂O emissions. However, from 14% DCD treated soil, there was a non-significant alteration in the N₂O emission. Maximum average N₂O efflux of 217.55 μg m⁻² h⁻¹ was noted from control plots. As compared to control, there was an attenuation of 50, 58, 65, and 91% average N₂O efflux from 6, 8, 10 and 12% DCD applied pots, respectively, whereas, there was a negative average of N₂O efflux from the soil with 14% DCD treatment. The soil N content also showed a significant correlation with N₂O emission. Therefore, 12% DCD treatment has been found to be the best with regard to attenuation of nitrous oxide from sandy loam agricultural soils.     

A spatial multicriteria decision making tool to define the best agricultural areas for sewage sludge amendment

Sewage sludge amendment on agricultural soils has recently become a practice of heightened interest, as a consequence of sewage sludge production increase. This practice has benefits to soil and crops, however it may also lead to environmental contamination, depending on the characteristics of the fields. In order to define the suitability of the different agricultural fields to receive sewage sludge, a spatial tool is proposed. This tool, elaborated in GIS platform, aggregates different criteria regarding human exposure and environmental contamination.The spatial tool was applied to a case study in the region of Catalonia (NE of Spain). Within the case study, each step of the tool development is detailed. The results show that the studied region has different suitability degrees, being the appropriate areas sufficient for receiving the total amount of sewage sludge produced. The sensitivity analysis showed that “groundwater contamination”, “distance to urban areas”, “metals concentration in soil” and “crop type” are the most important criteria of the evaluation.The developed tool successfully tackled the problem, providing a comprehensive procedure to evaluate agricultural land suitability to receive sewage sludge as an organic fertilizer. Also, the tool implementation gives insights to decision makers, guiding them to more confident decisions, based on an extensive group of criteria.     

Effects of municipal solid waste compost and mineral fertilizer amendments on soil properties and heavy metals distribution in maize plants (Zea mays L.)

Soil amendments based on crop nutrient requirements are considered a beneficial management practice. A greenhouse experiment with maize seeds (Zea mays L.) was conducted to assess the inputs of metals to agricultural land from soil amendments. Maize seeds were exposed to a municipal solid waste (MSW) compost (50 Mg ha⁻¹) and NPK fertilizer (33 g plant⁻¹) amendments considering N plant requirement until the harvesting stage with the following objectives: (1) determine the accumulation of total and available metals in soil and (2) know the uptake and ability of translocation of metals from roots to different plant parts, and their effect on biomass production. The results showed that MSW compost increased Cu, Pb and Zn in soil, while NPK fertilizer increased Cd and Ni, but decreased Hg concentration in soil. The root system acted as a barrier for Cr, Ni, Pb and Hg, so metal uptake and translocation were lower in aerial plant parts. Biomass production was significantly enhanced in both MSW and NPK fertilizer-amended soils (17%), but also provoked slight increases of metals and their bioavailability in soil. The highest metal concentrations were observed in roots, but there were no significant differences between plants growing in amended soil and the control soil. Important differences were found for aerial plant parts as regards metal accumulation, whereas metal levels in grains were negligible in all the treatments.     

Distribution, source and risk assessment of polychlorinated biphenyls (PCBs) in urban soils of Beijing, China

The concentration of PCBs in urban soils of Beijing across six land types including business districts (BD), cultural and educational areas (CE), classical gardens (CG), public green (PG), residential areas (RA), and roadsides (RD) was investigated. The total concentrations of PCBs ranged from below method detection limit (M.D.L.) to 37.11 × 10⁻³ mg kg⁻¹ dry weight (mean: 11.70 × 10⁻³ mg kg⁻¹; median: 13.28 × 10⁻³ mg kg⁻¹), which was at a medium level compared with other cities around the world. In general, the levels of PCBs decreased from the center of Beijing city to the suburb, suggesting the increasing PCBs concentrations with the age of the urban area. For different types of land use, the highest level of PCBs was observed in CG soils which have the oldest age, and the homologue profiles were similar, which were predominated by lowly chlorinated congeners including di-, tri- and tetra-CBs. Principal component analysis indicated that local sources such as Aroclor 1016, 1242, and 1248 were important sources in addition to long-range transport of PCBs all over the world. Although the toxic equivalency (TEQ) concentrations of dioxin-like PCBs in all soil samples of Beijing were higher than those in other urban areas of China, they met the Canadian soil quality standard.     

Fast Track Land Reform Programme,tenure security and investments in soil conservation: Micro‐evidence from Mazowe District in Zimbabwe

The government of Zimbabwe launched the Fast Track Land Reform Programme (FTLRP) in 2000 as part of its ongoing land reform and resettlement programme which aims to address a racially skewed land distribution. Its goal has been to accelerate both land acquisition and redistribution, targeting at least five million hectares of land for resettlement. This paper investigates the impact of the FTLRP on its beneficiaries' perceptions of land tenure security, and how these subsequently impacted soil conservation investments. Evidence suggests that the programme created some tenure insecurity, which adversely affected soil conservation investments among its beneficiaries. We find support for the contention that households make land‐related investments to enhance security of tenure. The results underscore the need for the government of Zimbabwe to clarify and formalize land tenure arrangements within the programme.     

Evidence of hydrocarbon contamination from the Burgan oil field, Kuwait: interpretations from thermal remote sensing data

The paper presents the application of thermal remote sensing for mapping hydrocarbon polluted sites. This has been achieved by mono-window algorithm for land surface temperature (LST) measurements, using multi-date band 6 data of Landsat Thematic Mapper (TM). The emissivity, transmittance and mean atmospheric temperature were used as critical factors to estimate LST. The changes in the surface emissivity due to oil pollution alter the apparent temperature, which was used as a recognition element to map out oil polluted surfaces. The LST contrast was successfully used to map spatial distribution of hydrocarbon pollution in the Burgan Oil field area of Kuwait. The methodology can be positively used to detect waste dumping, oil spills in oceans and ports, besides environmental management of oil pollution at or near the land surface.     

Multi-scale analysis of oxygen demand trends in an urbanizing Oregon watershed, USA

Human alteration of the landscape has an extensive influence on the biogeochemical processes that drive oxygen cycling in streams. We estimated trends from the mid-1990s to 2003, using the seasonal Mann-Kendall's test, for percent saturation dissolved oxygen (DO), chemical oxygen demand (COD), total Kjeldahl nitrogen (TKN), and ammonia-nitrogen (NH(3)-N) for 12 sites in the Rock Creek watershed, northwest Oregon, USA. In order to understand the influence of landscape change, scale, and stormwater runoff management on dissolved oxygen trends, we calculated land cover change through aerial photo interpretation at full-basin, local (near sample point) basin, and 100m stream buffer scales, for the years 1994 and 2000. Significant (p < or = 0.05) trends occurred in DO (increasing at five sites), COD (decreasing at seven sites), TKN (decreasing at five sites, increasing at one site), and NH(3)-N (decreasing at one site, increasing at one site). Significant land cover change occurred in agricultural land cover (-8% for the entire basin area) and residential land cover (+10% for the entire basin area) (p < or = 0.05). Correlation results indicated that: (1) forest cover negatively influenced COD at the full basin scale and positively influences NH(3)-N at local scales, (2) residential land cover influenced oxygen demand variables at local scales, (3) agricultural land cover did not influence oxygen demand, (4) local topography negatively influenced TKN and NH(3)-N, and (5) stormwater runoff management infrastructure correlated positively with COD at the local scale. This study indicates that landscape factors influencing DO conditions for the study streams act at multiple scales, suggesting that better knowledge of scale-process interactions can guide watershed managers' decision making in order to maintain improving water quality conditions.     

Technological options for the management of biosolids

BACKGROUND, AIM, AND SCOPE: Large quantities of biosolids (sewage sludge), which are produced from municipal wastewater treatment, are ever-increasing because of the commissioning of new treatment plants and continuous upgrades of the existing facilities. A large proportion of biosolids are currently landfilled. With increasing pressure from regulators and the general public, landfilling of biosolids is being phased out in many countries because of potential secondary pollution caused by leachate and the emission of methane, a potent greenhouse gas. Biosolids contain nutrients and energy that can be used beneficially. Significant efforts have been made recently to develop new technologies to manage biosolids and make useful products from them. In this paper, we provide a review of the technologies in biosolids management. MATERIALS AND METHODS: A survey of literature was conducted. RESULTS: At present, the most common beneficial use of biosolids is agricultural land application because of inherent fertilizer values found in biosolids. Expansion of land application, however, may be limited in the future because of more stringent regulatory requirements and public concern about food chain contamination in some countries. Perceived as a green energy source, the combustion of biosolids has received renewed interest. Anaerobic digestion is generally a more effective method than incineration for energy recovery, and digested biosolids are suitable for further beneficial use through land application. Although conventional incineration systems for biosolid management generally consume more energy than they produce because of the high moisture content in the biosolids, it is expected that more combustion systems, either monocombustion or cocombustion, will be built to cope with the increasing quantity of biosolids. DISCUSSION: Under the increasingly popular low-carbon economy policy, biosolids may be recognized as a renewable fuel and be eligible for 'carbon credits'. Because ash can be used to manufacture construction materials, combustion can provide a complete management for biosolids. A number of advanced thermal conversion technologies (e.g., supercritical water oxidation process and pyrolysis) are under development for biosolids management with a goal to generate useful products, such as higher quality fuels and recovery of phosphorus. With an ever-increasing demand for renewable energy, growing bioenergy crops and forests using biosolids as a fertilizer and soil amendment can not only contribute to the low-carbon economy but also maximize the nutrient and carbon value of the biosolids. CONCLUSIONS: Land application of biosolids achieves a complete reuse of its nutrients and organic carbon at a relatively low cost. Therefore, land application should become a preferred management option where there is available land, the quality of biosolids meet regulatory requirements, and it is socially acceptable. Intensive energy cropping and forest production using biosolids can help us meet the ever-increasing demand for renewable energy, which can eliminate the contamination potential for food sources, a common social concern about land application of biosolids. In recent years, increasing numbers of national and local governments have adopted more stringent regulations toward biosolid management. Under such a political climate, biosolids producers will have to develop multireuse strategies for biosolids to avoid being caught because a single route management practice might be under pressure at a short notice. Conventional incineration systems for biosolids management generally consume more energy than they produce and, although by-products may be used in manufacturing, this process cannot be regarded as a beneficial use of biosolids. However, biosolids are likely to become a source of renewable energy and produce 'carbon credits' under the increasingly popular, low-carbon economy policy. RECOMMENDATIONS AND PERSPECTIVES: To manage biosolids in a sustainable manner, there is a need for further research in the following areas: achieving a higher degree of public understanding and acceptance for the beneficial use of biosolids, developing cost-efficient and effective thermal conversions for direct energy recovery from biosolids, advancing technology for phosphorus recovery, and selecting or breeding crops for efficient biofuel production.     

Land Claims and Comanagement of Protected Areas in South Africa: Exploring the Challenges

Comanagement has recently become the most popular approach for reconciling land claims and biodiversity conservation in South Africa and beyond. Following the resolution of land claims on protected areas in South Africa, comanagement arrangements have been created between the relevant conservation authorities and the land claimant communities who are legally awarded tenure rights to the land. However, it is doubtful that these partnerships constitute success for the former land claimants. Using the case of a “resolved” land claim in Mkambati Nature Reserve, Eastern Cape Province, as well as insights from comanagement literature, this paper identifies and discusses three key possible reasons for the unimpressive performance of comanagement in reconciling land restitution and conservation. The first one is the origins of the comanagement idea in the conservation of high value natural resources (e.g., fisheries, forestry), rather than in or including concerns for resource rights. The second reason is the neglect of key conditions for successful comanagement, as discussed in the comanagement literature. The final reason is the ambiguity in settlement agreements, including the use of terminology and concepts that reinforce unequal power relationships, with the state emerging as the powerful partner. This paper concludes that, unless there is a serious reassessment of the comanagement idea as a way of reconciling land reform and conservation, and a possible review of settlement agreements that have relied on comanagement, both the integrity of the “successful land claimant’s rights” and that of conservation remain under threat.     

Impacts of Off-Road Vehicles (ORVs) on Macrobenthic Assemblages on Sandy Beaches

Sandy beaches are the prime sites for human recreation and underpin many coastal economies and developments. In many coastal areas worldwide, beach recreation relies on the use of off-road vehicles (ORVs) driven on the shore. Yet, the use of ORVs is not universally embraced due to social conflicts with other beach user groups and putative environmental consequences of vehicle traffic on sandy shores. Such ecological impacts of ORVs are, however, poorly understood for endobenthic invertebrates of the intertidal zone seawards of the dunes. Consequently, this study quantified the degree to which assemblages of intertidal beach invertebrates are affected by traffic. The study design comprised a series of temporally replicated spatial contrasts between two reference sites (no ORVs) and two beaches with heavy ORV traffic (in excess of 250,000 vehicles per year) located in South-East Queensland, Australia. Macrobenthic assemblages on ORV-impacted beaches had significantly fewer species at substantially reduced densities, resulting in marked shifts in community composition and structure. These shifts were particularly strong on the middle and upper shore where vehicle traffic was concentrated. Strong effects of ORVs were detectable in all seasons, but increased towards the summer months as a result of heavier traffic volumes. This study provides clear evidence that ORVs can have substantial impacts on sandy beach invertebrates that are manifested throughout the whole community. Demonstrating such an ecological impact caused by a single type of human use poses a formidable challenge to management, which needs to develop multi-faceted approaches to balance environmental, social, cultural, and economic arguments in the use of sandy shores, including management of “beach traffic.”