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51.
典型静电放电火花点燃危险性评价方法研究 总被引:5,自引:2,他引:5
通过研究典型静电放电火花的实际点燃能力 ,对实际生产工艺工程中的静电放电火花的点燃危险性进行定量评价。静电放电火花的放电相当能量、放电火花空间分布范围和放电火花持续时间 ,决定了静电放电火花实际点燃可燃物的可能性大小 ,因此不同类型的静电放电火花点燃可燃物的差异性很大。根据数据序列理论分析 ,引入静电放电火花点火源序列和可燃物危险性序列之间存在的关联性 ,反映了静电放电火花点燃可燃物的危险程度 ,可用于对静电放电火花的实际点燃危险性进行量化评价。对聚烯烃粉体生产工艺过程中典型和频发性的静电放电火花的点燃危险性进行了定量评价。 相似文献
52.
Dust explosion severities are closely associated with dust dispersion behaviors. To characterize the dispersion process of dust cloud, visualization experiments were conducted by using a transparent Siwek 20-L chamber. Dispersion processes of typical carbonaceous dust were recorded by a high-speed camera and, with the image processing technique, the qualitative analysis based on the transmission of dust cloud was carried out. Results have evidenced the three consecutive stages of dust dispersion process: the fast injection stage of dust particles, the stabilization stage and the sedimentation stage of dust cloud. The motion of dust particles and the variations of dust cloud in space and time can be clearly distinguished. In the stabilization stage, the good uniformity of dust dispersion is achieved when the deviation of transmission data at different locations reaches to the minimum value. Under different nominal dust concentrations, the time periods for dust dispersion stabilization are found to be significantly different, suggesting that different dust concentrations should correspond to different ignition delay in order to accurately measure the explosion characteristics in the Siwek 20-L chamber. Moreover, it is found that the decrease trend of transmission with increasing nominal dust concentration will become gradually leveling off, different from the inversely proportional relationship according to the Bouguer's law, and this indicates that the actual dust concentration will be lower than the nominal concentration or the dust cannot be fully dispersed at the case of high dust concentration. According to the experiment, when the nominal dust concentration exceeds to 1000 g/m3, the transmission will no longer vary visibly. 相似文献
53.
To accurately predict the development degree of coal spontaneous combustion (CSC), the CSC process was investigated using a programmed high-temperature-heating experimental system, and the variation law of index gas concentration in the holistic process of CSC and oxidation is formulated. Additionally, the accuracy of the experimental system was evaluated using experimental design for thermal analysis, and the correlation between gas index and apparent activation energy was determined using grey correlation analysis. The results indicated the following. In the critical temperature stage (0–100 °C), φ(CO)/φ(CO2) should serve as the main index and C2H4 should serve as the auxiliary index; in the crack-active-speedup temperature stage (100–260 °C), CO and φ(C2H4)/φ(C2H6) should serve as the main index and R1, the Graham index, and φ(C2H4)/φ(CH4) should serve as auxiliary indexes; in the speedup-ignition temperature stage (260–370 °C), R2 and the Graham index should serve as main indexes and φ(CO)/φ(CO2), C2H4, and R1 should serve as auxiliary indexes; in the ignition temperature (370–500 °C), R3 should serve as the main index and R2, the Graham index and C2H4 should serve as auxiliary indexes. Among them, the grey correlation degrees among the Graham index, Grignard fire coefficient, and apparent activation energy were the highest, reaching 0.91. 相似文献
54.
In this study, the dependence of minimum ignition energies (MIE) on ignition geometry, ignition source radius and mixture composition is investigated numerically for methane/air and iso-octane/air mixtures. Methane and iso-octane are both important hydrocarbon fuels, but differ strongly with respect to their Lewis numbers. Lean iso-octane air mixtures have particularly large Lewis numbers. The results show that within the flammability limits, the MIE for both mixtures stays almost constant, and increases rapidly at the limits. The MIEs for both fuels are also similar within the flammability limits. Furthermore, the MIEs of iso-octane/air mixtures with a small spherical ignition source increase rapidly for lean mixtures. Here the Lewis number is above unity, and thus, the flame may quench because of flame curvature effects. The observations show a distinct difference between ignition and flame propagation for iso-octane. The minimum energy required for initiating a successful flame propagation can be considerably higher than that required for initiating an ignition in the ignition volume. For iso-octane with a small spherical ignition source, this effect was observed at all equivalence ratios. For iso-octane with cylindrical ignition sources, the phenomenon appeared at lower equivalence ratios only, where the mixture's Lewis number is large. For methane fuel, the effect was negligible. The results highlight the significance of molecular transport properties on the decision whether or not an ignitable mixture can evolve into a propagating flame. 相似文献
55.
56.
To the previously developed and implemented new criterion for the shipping safety of activated carbons is added a consideration of ignition times. It is shown that there is considerable support for the view that in the past shipments of such materials deemed on the basis of the IMCO/ISO test procedures to be subcritical have actually been supercritical, but that the long ignition times, exceeding voyage times, have prevented fire from developing. 相似文献
57.
机器学习技术近年来在许多传统科学领域取得了应用,针对火灾中炭化可燃物着火时间与物性参数及环境参数之间关系复杂的特点,提出了一种基于极限学习机的预测方法以实现不同物性及环境参数时着火时间的快速准确预测,为防治及扑救火灾提供参考。首先建立炭化可燃物热解数值模型,考虑了可燃物热解过程中的含水率以及热解反应、气体流动等复杂物理化学反应过程,然后搭建极限学习机,以数值模拟数据为基础进行训练及验证工作。结果表明基于极限学习机的预测方法能够有效实现炭化可燃物着火时间的快速准确预测,平均相对误差小于3%。 相似文献
58.
59.
An experimental investigation of flammability limits of hydrogen, methane and propane in air and oxygen at reduced pressures was carried out. A slow influence of sizes of an experimental vessel of a diameter higher than 125 mm on the flammability limits was revealed, but an influence of a type of an oxidizer (air or oxygen) and an ignition energy is significant. Critical values of an initial pressure for a possibility of a flame propagation were determined. The limiting values of the ignition energy were determined, for which an elevation of this parameter does not influence the critical pressure and the flammability region. A qualitative interpretation of obtained experimental results is given, which is based on a peculiarities of a flame initiation. 相似文献
60.