钢管混凝土柱耐火性能和抗火设计的特点

简要论述了按ISO－834和GS9978－88规定的标准升温曲线升温作用下钢管混凝土柱耐火性能的特点,分析了影响钢管混凝土柱耐火极限的因素,说明了由于钢管和混凝土的共同工作且核心混凝土具有较好的吸热性能,从而使钢管混凝土柱具有较好的耐火性能。在进行钢管钢混凝土柱的抗火设计时,柱子外围只需进行适当的防火涂料保护,即可达到《高层用民建筑设计防火规范（GB50045－95）》对柱结构所要求的耐火极限。《高层用民建筑设计防火规范（GB50045－95）》中对钢结构柱防火保护层厚度的确定方法不适合于钢管混凝土。     

六铝酸盐催化剂的催化还原脱硫脱硝性能

采用共沉淀法制备Cu和Fe掺杂的六铝酸盐催化剂(SrCuxFe1-xAl11O19-δ,x为0,0.2,0.4,0.5,0.6,0.8,1),通过XRD、TPR、BET等技术方法对催化剂的结构及性质进行了研究,并考察了以CO为还原剂的催化脱硝活性。结果表明,用碳酸铵作为沉淀剂在1 200℃焙烧4 h可以形成完整的六铝酸盐晶型,Cu和Fe能够取代Al3+,很好地促进六铝酸盐晶体结构的形成;SrCuxFe1-xAl11O19-δ催化剂有很好的脱硫脱硝催化活性,此类型的催化剂均使SO2、NO的转化率在空速为6 000 h-1下达到了80%和90%以上。向体系中加入氧气会对催化活性有较大影响。     

Impact of soil quality on elemental uptake by,and distribution in,Colocasia esculenta (Amadumbe), an edible root

In this study the elemental distribution of selected essential (Ca, Mg, Al, Mn, Cu, Fe, Co, Cr, Zn, Ni and Se) and the non-essential (Pb, Hg and As) elements were determined in the bulb and peel of Amadumbe (Colocasia esculenta) samples from eight different sites in KwaZulu-Natal, South Africa. The concentration of Se and As in the soil and in the Amadumbe bulbs were below the detection limit of 0.09 μg g^?1. The total and bioavailable concentrations of the elements in conjunction with pH, soil organic matter (SOM) and cation exchange capacity (CEC) were determined in the soil samples from the eight sites. Statistical analysis was done to evaluate the impact of soil quality parameters on the chemical composition of the Amadumbe root. The results show accumulation or exclusion of certain elements by the bulb as evidenced by the noticeable increase or decrease of the concentrations of elements, respectively. Ca and Mg were found to be major elements in the range (2000–12000 μg g^?1), whilst Mn, Zn, Fe and Al were found to be minor elements in the range (20–400 μg g^?1). A general trend observed was that the plant favours the absorption of Zn over Cu. A positive correlation between Mg & Ca, Cu & Fe and Co & Ni was also observed. Statistical analysis revealed that the plant tended to accumulate Mg, Ca, Co, Cr and Pb whilst it excluded Hg and Fe, to a lesser extent.     

Corrosion and polarization behavior of carbon steel in MEA-based CO2 capture process

This work reveals levels of corrosion rate and polarization behavior of carbon steel immersed in aqueous solutions of monoethanolamine (MEA) used in the absorption-based carbon dioxide (CO₂) capture process for greenhouse gas reduction from industrial flue gas streams. Such information was obtained from electrochemical-based corrosion experiments under a wide range of the CO₂ capture process conditions. The corrosion of carbon steel was evaluated in respect to process parameters including partial pressure of oxygen (O₂), CO₂ loading in solution, solution velocity, solution temperature, MEA concentration and metal surface condition. Results show that the aqueous MEA solution containing CO₂ provides a favorable condition for the corrosion of carbon steel to proceed. Corrosion rate is increased by all tested process parameters. These parametric effects were explained by the electrochemical kinetic data obtained from polarization curves and by the thermodynamic data obtained from Pourbaix diagram.     

钢铁企业无组织排放特征污染物的监测分析

东部老工业区是济南市大气污染重点防控区域。工业区大型企业的无组织排放废气对区域及周边大气环境质量产生的影响,一直没有引起人们的足够重视,因对其排放量大小和污染物种类不清楚,难以进行监管。本文以济南东部老工业区一家大型钢铁企业为例,选取五项有代表性的特征污染物(苯、甲苯、二甲苯、非甲烷总烃和氨)进行布点监测,在不同气象条件下,分析特征污染物的浓度变化,了解钢铁企业无组织排放特征。经对监测数据的分析得出:与上风向相比,下风向各污染物监测的小时浓度和日均浓度均有不同程度的增加,表明该厂区污染源对周边环境空气质量有一定影响。最后,提出防范或改进措施,如应加严相应的无组织排放标准,增加大气在线监测点位及监测项目,建议企业加强对生产工艺环节无组织排放废气的收集和处理。     

Effect of Heavy Metals on the Blood Protein Biochemistry of the Fish CYPRINUS CARPIO AND ITS USE AS A BIO-INDICATOR OF POLLUTION STRESS

Cyprinus carpio were exposed to two non-essential (Hg and Pb)and two essential (Cu and Ni) heavy metal salts at lethal andsub-lethal concentrations. Blood serum total protein, serum globulinand serum albumin was analysed every 2 hr for 24 hrs andagain at 48 and 72 hrs. Serum protein and globulin level showedan intial sharp increase from 2 to 20 hrs, followed by decline thatextend over a period of 72 hrs. Serum albumin showed an initialimmediate decline from 2 to 4 hrs, followed by an intermittent period of recovery and decline that extend over a period of 72hrs. Both lethal and sub-lethal concentrations of metal salts elicited asimilar pattern of response varying only in magnitude. The use offish blood serum protein, albumin and globulin measurements as general indicators of pollutant stress response isdiscussed.     

部分预应力混凝土梁疲劳性能及工程经济性分析

为解决那些由于早期桥梁的设计标准低或服役时间过长,导致破损、承载力不足以及老化严重的问题,对部分已建桥梁提出改扩建计划。对桥梁改扩建工程,在满足当前设计要求的基础上合理选择钢筋与混凝土等级,可以有效节约成本,体现环保理念。通过对两组共8根不同钢筋与混凝土等级组合下的PPC梁分别进行静力试验和疲劳试验研究,分析不同组合形式下试验梁的力学性能,并结合其工程造价进行全面的研究。结果表明,提高混凝土等级能有效提高试验梁的疲劳性能,并可节约成本,为改扩建桥梁工程中钢筋混凝土等级的选择提供参考依据。     

吹吸式通风法在冷轧带钢氧化铁皮除尘中的应用

依据吹吸式通风原理,设计了一种氧化铁皮粉尘污染控制装置,通过对吹气、吸气罩的理论计算及实验分析,提出了具体的设计参数,为冷轧带钢氧化铁皮粉尘的控制提供了依据。     

Effect of heavy metal contaminated shooting range soils on mycorrhizal colonization of roots and metal uptake by leek

We grew leek (Allium porrum) in soils of two shooting ranges heavily contaminated with heavy metals in the towns of Zuchwil and Oberuzwil in Switzerland as a bioassay to test theactivity of arbuscular mycorrhizal (AM) fungi in these soils.Soil samples were taken from (1) front of the shooting house(HOUSE), (2) the area between house and target (FIELD) and (3) the berm (BACKSTOP). Samples of Ribwort plantain (Plantagolanceolata) growing naturally within the shooting ranges werealso collected and the colonization of its roots by mycorrhizalfungi was measured. The number of AM spores in the soils wassignificantly reduced concomitant with the increase in thedegree of soil contamination with metals. In Zuchwil,mycorrhizal fungi equally colonized roots of Ribwort plantainsampled from BACKSTOP and HOUSE. In Oberuzwil, however, plantsfrom BACKSTOP had lower colonization when compared with thosesampled from HOUSE. Colonization of leek was strongly reducedin the BACKSTOP soil of Zuchwil and slightly reduced in theBACKSTOP soil of Oberuzwil when compared with plants grown inrespective HOUSE soil. Concentrations of Cd, Cr, Cu, Ni, Pb andZn in the leaves of leek grown in the BACKSTOP soil was withinthe range considered toxic for human consumption. This pointsto the high degree of bio-availability of these metal in thesesoils. Significant decrease in the number of mycorrhizal sporesin the BACKSTOP soils in Zuchwil and the low colonization ofleek roots grown in these soils point to possible changes inthe species diversity of mycorrhizal fungi in these soils.     

中国钢材生命周期清单分析

采用生命周期清单分析方法分析了我国普通钢材生产过程中的能源消耗，物料消耗以及对环境的排放，研究表明我国钢铁生产生命周期过程中值得关注的环境问题有：能源消耗远高于发达国家平均水平，其主要存在于各相连工艺间及内部的运输过程水循环利用率较低，造成大量淡水资源浪费；废气排放主要是CO2和SOx，其主要来源于煤的燃烧和工艺过程，十分巨大的工业固体废弃物将造成严峻的局地环境问题。