硝基苯类废水的预处理技术研究

Fe(OH)2对硝基苯具有强烈的还原作用，短时间内可把硝基苯还原为苯胺。催化铁屑法处理硝基苯类废水，除了包括铁屑法处理废水的各种反应外，还能使硝基苯在其表面直接还原，且反应在弱碱性条件下效果较好。m(Fe)：m(Cu)为10：1，pH为9．5，废水硝基苯进水质量浓度为250mg／L，反应时间为30min，硝基苯的去除率达100％。     

Estimation and characterization of PCDD/Fs and dioxin-like PCBs from Chinese iron foundries

The iron foundry industry is considered to be a potential source of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs). This study investigated the emission factors and total emission amounts of PCDD/Fs and dioxin-like polychlorinated biphenyls (DL-PCBs) from iron foundries in China. The concentrations and the World Health Organization toxicity equivalents (WHO-TEQs) are presented and the congener profiles are discussed in this paper.In the present work, 26 fly ash samples were collected and tested to quantify the PCDD/Fs and DL-PCBs generated by 14 plants of different scales, and five stack gas samples were collected from two (named as EFG and LFG) of those plants. The emission levels of PCDD/Fs and DL-PCBs indicated that hot-air cupolas had lower emissions than cold-air cupolas. When iron ore lump and sinter were used as raw material, the emission factors were about 250 ng TEQ t⁻¹ of product. However, if the raw material was scrap, the emission factors varied owing to the different contents of organic materials in the raw materials. It was found that the mean WHO-TEQ values of PCDD/Fs and DL-PCBs were 144 and 34.2 pg Nm⁻³ in stack gas and 20.0 and 1.58 pg g⁻¹ in fly ash. In multiple tests, it was estimated that the mean emission factors of PCDD/Fs and DL-PCBs were 365 and 10.9 ng WHO-TEQ t⁻¹ released to residue and 2719 and 555 ng TEQ t⁻¹ released to air. The total emission amounts of PCDD/Fs and DL-PCBs from Chinese iron foundries with cupola furnaces released to residue and air were 16.8 and 146 g WHO-TEQ in 2008, respectively.     

碎石土边坡破坏机理的敏感性分析

在碎石土类边坡中常常发育稳定的地下水管网排泄系统,它们对控制地下水水位上升,保持边坡稳定十分重要。以官家滑坡为例,通过对滑坡稳定性系数有关的各因素敏感性分析,发现地下水是影响边坡变形破坏以及复发破坏的最主要因素。当坡脚开挖或坡体堆载时,会破坏管道状地下水排泄系统,降雨入渗导致地下水水位升高,从而引起坡体内孔隙压力比、水头高度和水力坡度增大,使潜在滑面上的孔隙水压升高,影响碎石土边坡的稳定性;同时,地下水位的升高降低了土体的内摩擦角,而因素敏感性分析发现,内摩擦角对边坡失稳具有极其重要的影响。在官家滑坡的后期治理中,治水作为主要工程措施的理念已经得到很好的贯彻,效果十分明显。     

城市给水管网优化设计研究

研究了几种典型的城市给水管网优化设计数学模型,并给出了求解方法,指出在给水管网系统的优化设计中进一步完善广义简约(GRG)算法的必要性.     

The explosion of non-nano iron dust suspension in the 20-l spherical bomb

The understanding of dust explosion is still incomplete because of the lack of reliable data and accurate models accounting for all the physic-chemical aspects. Besides, most of the experimental data available in the current literature has been accumulated on the 20-l spherical bomb tests, which gives coarse results for the pressure history that cannot be easily converted into fundamental combustion parameters. Nevertheless, the large amount of experimental data available in the spherical bomb is attractive. In this work, the explosion of non-nano iron dust in the standard spherical vessel is analyzed, aiming at evaluating the burning velocity from the theoretical point of view and the simple experiments performed by the standard explosion tests. The choice of iron is of relevance because its adiabatic flame temperature is below the boiling temperature of both the reactants and oxidized gaseous, liquid, or solid (intermediate and final) products and for the negligible particle porosity, which instead is typical of organic dust. Therefore, a non-nano iron dust explosion can be reconducted to a reduced mechanism since heterogeneous (surface) combustion may be determinant, and the diffusion mechanism for oxygen is the only relevant. The laminar burning velocity is strongly dependant on the particle diameter, whereas little effects are due to the dust concentration. The reported final value was found in agreement with typical limiting laminar burning velocity, adopted for the estimation of flammability limits.     

中国钢铁工业职业卫生40年回顾和今后展望

通过对中国钢铁工业职业卫生四十年的回顾,笔者认为:钢铁工业卫生管理体制已基本形成,但管理水平急需提高;主要的传统职业危害有所抑制,而今后任务仍十分艰巨;随着钢铁工业生产技术的发展广大职工又面临新的职业危害的挑战。本文最后对90年代钢铁工业职业卫生的形势进行了展望,提出了新的对策。在执行「八五」职业卫生规划的基础上,还需加强职业互生服务机构,扩大服务覆盖面,提高专业素质、开展普及教育、加强专业队伍的自身建设,这些任务是实现十年战略目标的重要保证。     

小直径锥形管成形工艺研究

通过对小直径锥形管的工艺分析 ,介绍了一种成形的工艺方法和措施 ;并就成形、加工模具作了详细说明     

竖直弯管中含固体颗粒分散泡状流冲蚀预测

目的研究竖直弯管在含固体颗粒分散泡状流下的冲蚀规律,探究管内气液分布、颗粒分布及三维冲蚀形貌之间的关系。方法提出基于VOF模型和DPM模型的瞬态冲蚀数值计算方法,利用Oka等人提出的冲蚀模型及Grant和Tabakoff提出的颗粒-壁面碰撞模型计算管壁冲蚀速率。结果基于VOF和DPM模型的CFD冲蚀计算结果与经验模型及简化CFD模型的计算结果相比,更接近实验值。分散泡状流中,固体颗粒大部分分散在液相中,管道不同截面处的含液率与颗粒粒含量相关性较大,下游直管段和弯头处固体颗粒的粒含量大于上游直管段。含固体颗粒弯管在分散泡状流作用下,冲蚀区域较大,冲蚀最严重位置出现在弯头出口处附近。结论含砂分散泡状流冲蚀条件下,竖直弯管冲蚀形貌与管内气液固分布直接相关,多相流冲蚀瞬态仿真方法可较准确计算气液固分布并预测管道冲蚀。     

铁屑内电解法处理含油废水的研究

在研究铁屑内电解法基本原理的基础上,研究各工艺因素对处理效果的影响,并找出最佳反应条件.结果显示,当pH值为4,反应时间为20min,铁屑用量为1.6%,铁炭比为1.5∶1时,处理效果最好,COD和油的去除率分别在90.4%和92.4%左右.     

烟道式脱硫装置处理冶炼厂高浓度SO2烟气的工程实践

本文介绍了烟道式脱硫装置的特点及工艺原理 ,采用该装置处理某冶炼厂高浓度SO2 烟气 ,其脱硫率达 90 %以上 ,净化后的烟气可直接达标排放 ,并年产合格脱硫石膏近万吨。烟道式脱硫装置解决了常规脱硫除尘装置共同存在的结垢和堵塞问题 ,在冶炼烟气治理方面具有一定的推广应用价值。