基于设计暴雨强度城市河道排涝与管渠排水标准关系研究

城市化地区河道排涝系统与管渠排水系统,分属不同的管理部门,遵循不同的行业规范。该文分析了城市河道排涝与城市管渠排水的功能及关系,从排水系统的特点及计算方法探析了城市河道排涝与管渠排水的区别。还讨论了排涝标准三个主要因素暴雨历时、排涝时间和设计暴雨重现期的拟定,探讨了城市河道排涝与城市管渠排水标准的衔接方法,并以合肥市十五里河为例,通过推求设计暴雨强度拟定河道排涝和管渠排涝设计暴雨重现期之间的定量关系,为城市排水工程规划提供了参考依据。     

铁和铝离子对土壤水溶性氟化物检测的干扰研究

通过离子选择电极法测定Fe3+和Al3+不同含量的土壤样品中水溶性氟化物试验,研究Fe3+和Al3+对测定的干扰与消除方法,证实了在总离子强度调节缓冲溶液共存下,Fe3+和Al3+对土壤提取液中水溶性氟化物检测结果存在不同程度的负干扰。选择6种代表性土壤样品,在水溶性氟化物提取液中加入20 mg/L的Al3+和100 mg/L的Fe3+做干扰试验,比较了分取不同体积土壤提取液对氟化物检测结果的影响,结果表明,对水溶性ρ(Fe3+)和ρ(Al3+)高的土壤样品,可选择减少提取液取样体积来消除干扰。选取的5种标准样品测试结果与标准值相符,干扰消除方法具有良好的适用性。     

A review on sustainable reuse applications of Fenton sludge during wastewater treatment

• The sustainable approaches related to Fenton sludge reuse systems are summarized. • Degradation mechanism of Fenton sludge heterogeneous catalyst is deeply discussed. • The efficient utilization directions of Fenton sludge are proposed. The classical Fenton oxidation process (CFOP) is a versatile and effective application that is generally applied for recalcitrant pollutant removal. However, excess iron sludge production largely restricts its widespread application. Fenton sludge is a hazardous solid waste, which is a complex heterogeneous mixture with Fe(OH)₃, organic matter, heavy metals, microorganisms, sediment impurities, and moisture. Although studies have aimed to utilize specific Fenton sludge resources based on their iron-rich characteristics, few reports have fully reviewed the utilization of Fenton sludge. As such, this review details current sustainable Fenton sludge reuse systems that are applied during wastewater treatment. Specifically, coagulant preparation, the reuse of Fenton sludge as an iron source in the Fenton process and as a synthetic heterogeneous catalyst/adsorbent, as well as the application of the Fenton sludge reuse system as a heterogeneous catalyst for resource utilization. This is the first review article to comprehensively summarize the utilization of Fenton sludge. In addition, this review suggests future research ideas to enhance the cost-effectiveness, environmental sustainability, and large-scale feasibility of Fenton sludge applications.     

Based on material flow analysis: Value chain analysis of China iron resources

Iron is an important basic resource for national economic development in China. It is of great strategic importance for the sustainable development of China's economy to study the utilization and circulation status of iron resources. In this paper, using the material flow and value chain analysis method, we quantitatively analyzed the value flow of iron resources in China. According to the value chain and price theory of element M, a value stream diagram of iron resources corresponding to the substance flow chart was plotted. Based on the previous material flow analysis result of iron resources, the diagram quantitatively depicted the value of the circulating flow of iron resources in China in 2011. The results show that by recycling materials, the value of the circulating flow of iron resources can bring considerable economic benefits to both producers and consumers. In the production stage, the expenditures of the entire economic system was reduced by 91.77 billion RMB by circulating iron and the income increased by 95 billion RMB by recycling home scrap, which was generated in the crude steel production stage. In the use stage of iron and steel products, the recycling of old scrap enabled the entire economic system to recover 370.78 billion RMB. It should be noted that analysis within a single framework of physical and economic characteristics of iron resources in the economic system can further extend the research chain of substance flow and value flow at the macro level, enhancing the economic value of substances flow research. In addition, by tracking and depicting the value flow cycle of elements, the improvement potentials and the value situations can be determined to provide useful information for conducting processing and technological innovation for waste minimization.