膜-生物反应器处理餐饮废水过程中溶解性有机物的迁移变化特性研究

借助于凝胶过滤色谱(GFC)分子量测定技术和三维荧光(EEM)光谱技术,对膜一生物反应器(MBR)处理餐饮废水过程中溶解性有机物(DOM)的迁移变化特性进行了研究.结果表明,GFC分析中,在析出的前12 min,除了调节池出水,其他各工艺阶段(原水、气浮池出水、MBR出水)水样中均有大分子有机物(分子量＞400 ku)...     

Different analysis techniques for fluorescence excitation-emission matrix spectroscopy to assess compost maturity

Assessment of compost maturity is essential for achieving high quality compost. In this study, fluorescence excitation-emission matrix spectroscopy combined with different analysis techniques was applied to improve the sensitivity of compost maturity assessment. Results showed that composts in two parallel piles could be believed mature after 37 d when combined with the evolution of temperature, chemical and biological indices in the two piles. Pearson correlation between the common maturity indices and fluorescence analysis parameters demonstrated that fluorescence regional integration (FRI) had a higher correlation coefficient than that of fluorescence intensities and the ratios of peaks, suggesting that FRI technique is more suitable to characterize the maturity of compost than the other two analysis techniques, i.e., peak intensity and peak ratio. Furthermore, the fluorescence spectroscopy combined with FRI analysis could be used as a valuable industrial and research tool for assessing compost maturity.     

A risk-estimation methodological framework using quantitative assessment techniques and real accidents’ data: Application in an aluminum extrusion industry

The risk estimation presumably is the most crucial part of the entire procedure of assessing hazards/unsafe situations in the work, and especially in the industries’ and constructions’ worksites, where the working conditions are unstable. We can consider the risk as a quantity, which can be estimated and expressed by a mathematical relation, under the help of real accidents’ data. The aim of this work is quadruplicate: (a) the development, elaboration and explanation of two new quantitative risk-assessment techniques, (b) the improvement of specific points of other scientific works, as far as concerns quantitative risk estimation, (c) the application of these techniques on an industrial productive procedure (as a case study) and (d) the comparison of their outcome risk-estimation results. Particularly, we develop and analyze the theoretical background of the two techniques, which we call as “proportional technique” and “decision matrix technique”, and apply them on an aluminum extrusion industry's worksite, which is situated in Greece, by using real data of potential sources of hazards, recorded by safety managers, during the 5.5-year time period of 1999–2004. Comparing the results of the two quantitative risk-assessment techniques, we infer that they are compatible. Therefore, the most important hazard source in the aluminum industry is the “squeezing and hits by dropping objects (transported by derricks)”, and imposes that immediate suppressive measures must be taken place to abolish the danger source.     

基于模糊层次分析法的民用机场安全风险管理

以某一民用机场为例,基于"人-机-环境-管理"的系统工程理论,分析该机场影响飞行安全的各影响因素。利用三角模糊数来表征专家判断信息,构造三角模糊数互补判断矩阵。依据模糊层次分析法,对各影响因素进行单排序和总排序,得到其重要性的排序。模糊层次分析法可以更加客观地描述专家判断的模糊性,并且计算过程简单。基于模糊层次分析法的安全风险管理不仅能够客观地评估民航的安全状态,而且对于有重点地改善民用机场安全有着积极的作用。     

应急与日常状态下的责任配置一致性研究

针对各部门在应急与日常状态下的责任存在不一致的问题,因而导致在应急过程中无法有效进行责任转换,影响应急工作开展,借鉴遥感影像分类精度评价中常用的混淆矩阵方法,通过确定标准任务、应急责任矩阵、日常相关责任、责任一致性原则等步骤,建立了应急预案混淆矩阵。笔者以2007年《××市雪天道路交通保障应急预案》为例,对应急预案在应急与日常状态下的责任一致性进行了分析。结果表明,各部门以及应急预案整体的混淆矩阵,能够直观而定性地反映应急预案的责任一致性;对混淆矩阵责任一致性指数p的计算,可进一步定量化地评价应急预案。定性与定量相结合的方法是全面分析和评价应急预案所必需的手段,同时可以为应急预案的责任配置调整提供依据。     

泰州全市及生态红线区“十二五”土地利用变化探究

以土地利用转移矩阵为基础,通过计算土地利用净变化量、交换变化量和绝对变化总量,对泰州市及生态红线区2010—2014年土地利用空间变化特征做分析。结果显示:耕地转化为建设用地及水域湿地景观为主要变化趋势,生态红线区域内土地开发利用受到较严格的限制,保护措施成效较好,其自然生态环境得到持续的修复和改善。     

经济增长和环境规制对雾霾的区际影响差异

为探究不同省级区域雾霾、经济增长和环境规制之间的空间关联效应,本文提出针对雾霾的引力模型空间权重矩阵,并利用该矩阵建立了空间杜宾模型,分别对全国、西部、中部和东部省区的面板数据进行了空间计量检验。实证结果显示:全国雾霾的莫兰指数值显著,且取值介于0.367—0.460之间;雾霾"重心"呈现先向东南再向西北移动的趋势,移动距离为76 557 m;雾霾的莫兰指数值为东部省区最大,西部省区最小,中部省区介于二者之间。全国的雾霾与经济增长之间呈显著的"U"型曲线,而西部、中部和东部省区则呈倒"U"型曲线,其中中部省区的曲线最为陡峭,西部省区次之,东部省区最为平缓。环境规制每增加1%,只有西部和东部的雾霾相应减少,且各自相应下降0.009和0.010个百分点。西部和东部经济增长的溢出效应均显著,而环境规制的溢出效应不显著。研究结果表明:(1)雾霾在空间上表现出集聚的特点,全国和三个区域的雾霾都存在显著的正向空间溢出效应,这种空间依赖性在时间维度上大致呈加强的趋势;雾霾的空间相关性表现为东部省区最强,西部省区紧随其后,中部省区最低。(2)西部和东部省区部分省市还未过拐点,全国意义上的环境库茨涅兹假说是不存在的,或者是至少还未出现。(3)西部和东部环境规制效果较为理想,而中部省区的环境规制效果不佳;从全国总体来看,当前的环境规制整体上对雾霾并未起到有效的抑制作用。(4)东西部省区和中部省区经济增长对雾霾溢出效应分别表现为正向和反向;环境规制对雾霾的溢出效应并不显著。建议加强对雾霾的区域协同治理,重点推进西部和东部省区经济结构的转型升级,调整和完善西部、中部和东部省区的环境规制政策。     

Validation of QuEChERS method for the determination of some pesticide residues in two apple varieties

This study was undertaken to validate the “quick, easy, cheap, effective, rugged and safe” (QuEChERS) method using Golden Delicious and Starking Delicious apple matrices spiked at 0.1 maximum residue limit (MRL), 1.0 MRL and 10 MRL levels of the four pesticides (chlorpyrifos, dimethoate, indoxacarb and imidacloprid). For the extraction and cleanup, original QuEChERS method was followed, then the samples were subjected to liquid chromatography-triple quadrupole mass spectrometry (LC-MS/MS) for chromatographic analyses. According to t test, matrix effect was not significant for chlorpyrifos in both sample matrices, but it was significant for dimethoate, indoxacarb and imidacloprid in both sample matrices. Thus, matrix-matched calibration (MC) was used to compensate matrix effect and quantifications were carried out by using MC. The overall recovery of the method was 90.15% with a relative standard deviation of 13.27% (n = 330). Estimated method detection limit of analytes blew the MRLs. Some other parameters of the method validation, such as recovery, precision, accuracy and linearity were found to be within the required ranges.     

基于Leslie模型的产业链废物产生量预测研究

利用1987-2002年中国工业行业投入产出数据,在对产业间经济技术联系分析的基础上,构建了一个循环经济模拟产业链,且以2005年该产业链上各产业废物产生量为基期数据,模拟Leslie动物繁衍模型,分别对2010年、2015年和2020年该产业链上各产业废物产生总量进行了预测和分析。可为构建循环经济产业链,以及评价循环经济产业链运行效率提供必要的方法和数据参考。     

Effects of ultrasonic pretreatment on sludge dewaterability and extracellular polymeric substances distribution in mesophilic anaerobic digestion

Effect of ultrasonic pretreatment on sludge dewaterability was determined and the fate of extracellular polymeric substances (EPS) matrix in mesophilic anaerobic digestion after ultrasonic pretreatment was studied. Characteristics of proteins (PN), polysaccharides (PS), excitation-emission matrix (EEM) fluorescence spectroscopy and molecular weight (MW) distribution of dissolved organic matters (DOM) in different EPS fractions were evaluated. The results showed that after ultrasonic pretreatment, the normalized capillary suction time (CST) decreased from 44.4 to 11.1 (sec·L)/g total suspended solids (TSS) during anaerobic digestion, indicating that sludge dewaterability was greatly improved. The normalized CST was significantly correlated with PN concentration (R2 = 0.92, p 0.01) and the PN/PS ratio (R2 = 0.84, p 0.01) in the loosely bound EPS (LB-EPS) fraction. Meanwhile, the average MW of DOM in the LB- EPS and tightly bound EPS (TB-EPS) fractions also had a good correlation with the normalized CST (R2 0.66, p 0.01). According to EEM fluorescence spectroscopy, tryptophan-like substances intensities in the slime, LB-EPS and TB-EPS fractions were correlated with the normalized CST. The organic matters in the EPS matrix played an important role in influencing sludge dewaterability.