Seasonal Variations and Chemical Forms of Heavy Metals in Soils and Dusts from the Satellite Cities of Seoul, Korea

This research investigated heavy metal pollution of soils and dusts in two representative satellite cities of Seoul, Korea and studied the seasonal variations in metal concentrations through the rainy season and the chemical forms of metals using a sequential extraction analysis. The metal dispersion pattern was illustrated to match with urban structure. Soil and dust samples were collected from the cities of Uijeongbu and Koyang, which are the northern and northwestern satellite cities of Seoul (the capital), before and after rainy season. Concentrations of Cu, Pb and Zn were higher than those of the world averages for soils, and their levels decreased after rain, particularly in highly contaminated samples. Relatively high pH values were found in roadside soils, but no seasonal variation was found after the rainy season. The three metals (Cu, Pb and Zn) in soils and dusts were associated with various chemical fractions of soils and dusts as distinguished by the sequential extraction scheme, and a strong similarity of metal association between soils and dusts was found, which indicates that airborne dust may be a principle source of soil contamination. Copper is uniformly distributed, and Pb is largely associated with the reducible phase. There is an appreciable proportion of total Zn in the exchangeable/water-acid soluble fraction. After the rainy season, the most soluble fractions in soils and dusts were leached away. In terms of mobility and bioavailability of metals in soils and dusts, the order Zn >> Cu > Pb is suggested. Geographical variations of total metals corresponded well with urbanised areas of cities, especially the industrial complex and major motorways.     

朝鲜晚奥陶世——志留纪和泥盆纪地层发现的启示

本文在比较系统介绍朝鲜于60-70年代发现泥盆纪临律群和晚奥陶世—志留纪地层的基础上,论证前者西延登上山东半岛,后者指向辽东、冀东的可能性。     

Cause and consequence of landscape fragmentation and changing disturbance by socio economic development in mountain landscape system of South Korea

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Potential Tree Species for Use in the Restoration of Unsanitary Landfills

Given that they represent the most economical option for disposing of refuse, waste landfills are widespread in urban areas. However, landfills generate air and water pollution and require restoration for landscape development. A number of unsanitary waste landfills have caused severe environmental problems in developing countries. This study aimed to investigate the colonization status of different tree species on waste landfills to assess their potential for restoring unsanitary landfills in South Korea. Plot surveys were conducted using 10 × 10-m quadrats at seven waste landfill sites: Bunsuri, Dugiri, Hasanundong, Gomaeri, Kyongseodong, Mojeonri, and Shindaedong. We determined the height, diameter at breast height (DBH), and number of tree species in the plots, and enumerated all saplings ≤1 m high. Because black locust, Robinia pseudoacacia, was the dominant tree species in the waste landfills, we measured the distance from the presumed mother plant (i.e., the tallest black locust in a patch), height, and DBH of all individuals in black locust patches to determine patch structure. Robinia pseudoacacia, Salix koreensis, and Populus sieboldii formed canopy layers in the waste landfills. The basal area of black locust was 1.51 m²/ha, and this species had the highest number of saplings among all tree species. The diameter of the black locust patches ranged from 3.71 to 11.29 m. As the patch diameter increased, the number of regenerated saplings also tended to increase, albeit not significantly. Black locust invaded via bud banks and spread clonally in a concentric pattern across the landfills. This species grew well in the dry habitat of the landfills, and its growth rate was very high. Furthermore, black locust has the ability to fix nitrogen symbiotically; it is therefore considered a well-adapted species for waste landfills. Eleven woody species were selected for screening: Acer palmatum, Albizzia julibrissin, Buxus microphylla var. koreana, Ginkgo biloba, Hibiscus syriacus, Koelreuteria paniculata, Ligustrum obtusifolium, Liriodendron tulipifera, Pinus koraiensis, Pinus thunbergii, and Sophora japonica. As a result of a comparison of the total ratio (sum of shoot extension and diameter growth at the landfill relative to a reference site) and mortality, six species (Liriodendron tulipifera, Albizzia julibrissin, Ligustrum obtusifolium, Buxus microphylla var. koreana, Hibiscus syriacus, and Sophora japonica), which had a total ratio >1 and experienced low mortality, are recommended as potentially suitable species for waste landfill remediation. We suggest that mixed plantations of ubiquitous adaptable species and naturally occurring black locust will enhance the landscape through synergistic effects.     

Humanitarian Crises: What Determines the Level of Emergency Assistance? Media Coverage,Donor Interests and the Aid Business

This paper proposes a basic hypothesis that the volume of emergency assistance any humanitarian crisis attracts is determined by three main factors working either in conjunction or individually. First, it depends on the intensity of media coverage. Second, it depends on the degree of political interest, particularly related to security, that donor governments have in a particular region. Third, the volume of emergency aid depends on strength of humanitarian NGOs and international organisations present in a specific country experiencing a humanitarian emergency. The empirical analysis of a number of emergency situations is carried out based on material that has never been published before. The paper concludes that only occasionally do the media play a decisive role in influencing donors. Rather, the security interests of Western donors are important together with the presence and strength of humanitarian stakeholders, such as NGOs and international organisations lobbying donor governments.     

PCBs contributions to the total TEQ released from Korean municipal and industrial waste incinerators

Non-ortho and mono-ortho polychlorinated biphenyls (PCBs) were determined in the stack gases and the fly-ash from nine Korean municipal solid waste incinerators (MSWIs). Soil samples collected near MSWI and industrial waste incinerator (IWI) sites were also examined for PCBs. The PCBs levels in the stack gas samples ranged between 0.0046 and 12.0 TEQ-ng/Nm³. The PCB homologue profiles were distinct for the stack gas samples and different from the fly-ash. PCBs levels in soil samples collected near MSWIs and IWI ranged between 0.86 and 19.73 TEQ-ng/g with background levels of 0.17 TEQ-ng/g. The lower chlorination PCBs were dominant in the soil samples. The stack emission PCBs homologue patterns were compared to those detected in the soil samples. The findings suggest that localized point sources as well air mass movement contribute to the deposition of PCBs onto soil.     

Historical trends in human dietary intakes of endosulfan and toxaphene in China, Korea and Japan

Recently, the Stockholm Convention prohibited the use of toxaphene and has been reviewing endosulfan. The historical use of these pesticides may contaminate food and tend to accumulate in the food chain. In this study, to evaluate the spatial and temporal trends of food contamination, the endosulfan and toxaphene levels were measured in pooled 24-h food composite samples from Chinese (n = 10), Korean (n = 10) and Japanese (n = 40) adults in the 1990s and 2007-2009. Endosulfan was detected in 32 of 40 samples from Japan, but its levels (sum of α- and β-isomers) were low in both the 1990s and 2009 (range as geometric mean (geometric standard deviation) [GM (GSD)]: 0.96 (1.6)-1.42 (1.4) ng kg⁻¹ d⁻¹). The dietary intakes of endosulfan in Seoul as GM (GSD) were 38.68 (1.3) ng kg bw⁻¹ d⁻¹ in 1994 and 92.17 (4.4) ng kg bw⁻¹ d⁻¹ in 2007, and significantly higher than those in Japan (p < 0.05). The samples from Beijing showed a 50-fold increase in the endosulfan levels from 1993 (GM: 0.58 ng kg⁻¹ d⁻¹) to 2009 (GM: 24.91 ng kg bw⁻¹ d⁻¹) (p < 0.05). Toxaphene was detected in 33 of 40 samples from Japan. The dietary intake of toxaphene in Japan (sum of Parlars #26, #50 and #62) was 0.32-1.21 ng kg bw⁻¹ d⁻¹ (range as geometric mean) and no temporal trend was observed. The dietary intake of toxaphene in Seoul increased significantly from 0.2 ng kg bw⁻¹ d⁻¹ (GM) in 1994 to 3.6 ng kg bw⁻¹ d⁻¹ (GM) in 2007 (p < 0.05). Only one of 10 pooled samples from Beijing contained a detectable level of toxaphene (0.3 ng kg bw⁻¹ d⁻¹). For the entire population, the risk of adverse health effects from dietary intakes of endosulfan and toxaphene is unlikely. However, the concentrations of endosulfan in several samples exceeded 10% of the acceptable daily intake limit value of 6 μg kg bw⁻¹ d⁻¹ set by the World Health Organization (WHO). It appears important to refine dietary intake estimates targeting food types and source identification to ensure safe food for consumers.     

Determining dioxin-like compounds in selected Korean food

To measure the levels of dioxin-like compounds, pork, mackerel, cheese and milk were analyzed. The food samples were obtained at three different markets in Seoul. All the samples were animal origin and their lipid contents ranged from 4% to 34%. After extraction, extracts were cleaned up by sulfuric acid impregnated silica gel, purified on a series of silica gel, alumina, carbon column chromatography and then analyzed by high resolution gas chromatography/high resolution mass spectrometry. The levels of polychlorinated dibenzo-p-dioxins/furans for pork, mackerel, cheese and milk were 0.0008, 0.8663, 0.002 and 0.0236 pgTEQ/g wet weight, respectively. In addition, the levels of non-ortho coplanar polychlorinated biphenyls for pork, mackerel, cheese and milk were 0.0041, 1.5781, 0.0259 and 0.0353 pgTEQ/g wet weight, respectively. Among food samples analyzed, pork showed the lowest level of dioxin-like compounds.     

中韩土壤修复技术筛选重金属耐受性和超富集植物方法比较

比较中国、韩国土壤修复技术中筛选重金属耐受性植物、重金属超富集植物方法的差异。实际操作中采用哪种方法取决于污染区域的实地状况、修复目标和拟修复时间的长短。对于土壤修复而言,耐受性植物,超富集植物的筛选是非常重要的环节,两国技术方法的差异可以作为制定修复措施的有益参考。     

Application of Likelihood Ratio and Logistic Regression Models to Landslide Susceptibility Mapping Using GIS

For landslide susceptibility mapping, this study applied and verified a Bayesian probability model, a likelihood ratio and statistical model, and logistic regression to Janghung, Korea, using a Geographic Information System (GIS). Landslide locations were identified in the study area from interpretation of IRS satellite imagery and field surveys; and a spatial database was constructed from topographic maps, soil type, forest cover, geology and land cover. The factors that influence landslide occurrence, such as slope gradient, slope aspect, and curvature of topography, were calculated from the topographic database. Soil texture, material, drainage, and effective depth were extracted from the soil database, while forest type, diameter, and density were extracted from the forest database. Land cover was classified from Landsat TM satellite imagery using unsupervised classification. The likelihood ratio and logistic regression coefficient were overlaid to determine each factors rating for landslide susceptibility mapping. Then the landslide susceptibility map was verified and compared with known landslide locations. The logistic regression model had higher prediction accuracy than the likelihood ratio model. The method can be used to reduce hazards associated with landslides and to land cover planning. Note: This version was published online in June 2005 with the cover date of August 2004.