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51.
水中化学耗氧量的快速测定法 总被引:3,自引:0,他引:3
利用烘箱法测定水中的化学耗氧量是国内外在微量分析测定方法上较为先进的分析,优点是仪器、设备简便、操作简单、分析快速、节省大量化学试剂,可以大批量地进行试验.实验中不加入硫酸汞试剂,避免或减少了汞污染.方法的空白值较好,提高了实验的精密度和准确度,是一种易推广的方法 相似文献
52.
《环境科学学报(英文版)》2023,35(4):517-530
Graphite carbon nitride has many excellent properties as a two-dimensional semiconductor material so that it has a wide application prospect in the field of photocatalysis. However, the traditional problems such as high recombination rate of photogenerated carriers limit its application. In this work, we introduce nitrogen deficiency into g-C3N4 to solve this problem a simple and safe in-situ reduction method. g-C3N4/CaCO3 was obtained by a simple and safe one-step calcination method with industrial-grade micron particles CaCO3. Cyano group modification was in-situ reduced during the thermal polymerization process, which would change the internal electronic structure of g-C3N4. The successful combination of g-C3N4 and CaCO3 and the introduction of cyanide have been proved by Fourier transform infrared spectroscopy and X-ray photoelectron spectrometer. The formation of the cyano group, an electron-absorbing group, promotes the effective separation of photogenic electron hole pairs and inhibits the recombination of photogenic carriers. These advantages result in the generation of more •O2− and 1O2 in the catalytic system, which increases the photocatalytic efficiency of nicotine degradation by ten times. Furthermore, the degradation process of nicotine has been studied in this work to provide a basis for the degradation of nicotine organic pollutants in the air. 相似文献
53.
报道了胡椒基丁醚生产中5-丙基-1,3-苯并二氧杂茂的氯甲基化的废水处理,该废水经蒸馏可回收94%的盐酸,此酸吸收氯化氢后浓度在36%以上,可再用于氯甲基化反应。蒸馏残液经分油、Fenton试剂处理和五次生炭柱吸附后CODCr等项指标均可国家二类污染物的一级排放标准。 相似文献
54.
采用垃圾填埋堆体模拟装置,对杭州市城市生活垃圾在1998年2月至1998年10月期间稳定化过程中的垃圾渗滤液水质指标变化、堆体内部温度变化、垃圾减量化、沉降高度和产气量进行了研究,装入模拟装置的221kg生活垃圾经8个月的降解后,垃圾减量化显著,总量降至127kg,其中有机组分由94.8kg(42.9%)降至20.93kg(16.5%),无机组分由72.71kg(32.9%)降至53.65kg(4 相似文献
55.
Klaassien J. Ganzeveld Annechien van Hagen Martin H. van Agteren Wim de Koning Anton J. M. Schoot Uiterkamp 《Journal of Cleaner Production》1999,7(6):690
Two types of fermented organic waste (trade and industry waste and fruit and vegetable waste) were successfully used as a sole carbon source to produce poly-3-hydroxybutyrate-co-valerate (PHBV) by Ralstonia eutrophus (formerly Alcaligenes eutrophus) via oxygen limitation.The production of PHBV could be optimized by optimizing the oxygen transfer through the fermentor. Thereby, a peak concentration of 1.1 g PHBV per liter cell suspension, 40 w% of cell dry weight, was obtained at an aeration rate of 0.24 mol O2/h·kg biomass. The yield of PHBV on the fatty acid concentration in the organic waste was 0.16 g polymer/g volatile organic matter. The process obtained, compares well with the commercial production process of PHBV based on glucose. 相似文献
56.
水体中亚硫酸协还原菌的孢子,能在水中生存较长时间,容易在水池或管道中滋生,产生黑臭,可作为水体长期或周期性污染的一种指示,但目前国内尚无测定该菌的完整方法,作者建立了一种比较适合我国国情的测定方法,以国产蛋白陈替代胶胨型的水解液,结果阳性特征明显,精密度,重现性均较好。 相似文献
57.
58.
Zhe Feng Lin Zeng Qingle Zhang Shifeng Ge Xinyue Zhao Hongjun Lin Yiming He 《环境科学学报(英文版)》2020,32(1):149-162
A graphite carbon nitride(g-C_3N_4) modified Bi_4O_5I_2 composite was successfully prepared insitu via the thermal treatment of a g-C_3N_4/Bi OI precursor at 400°C for 3 hr.The as-prepared g-C_3N_4/Bi_4O_5I_2 showed high photocatalytic performance in Methyl Orange(MO) degradation under visible light.The best sample presented a degradation rate of 0.164 min~(-1),which is 3.2 and 82 times as high as that of Bi_4O_5I_2 and g-C_3N_4,respectively.The g-C_3N_4/Bi_4O_5I_2 was characterized by X-ray powder diffractometer(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),Raman,X-ray photoelectron spectroscopy(XPS),ultraviolet-visible diffuse reflectance spectra(DRS),electrochemical impedance spectroscopy(EIS) and transient photocurrent response in order to explain the enhanced photoactivity.Results indicated that the decoration with a small amount of g-C_3N_4 influenced the specific surface area only slightly.Nevertheless,the capability for absorbing visible light was improved measurably,which was beneficial to the MO degradation.On top of that,a strong interaction between g-C_3N_4 and Bi_4O_5I_2 was detected.This interplay promoted the formation of a favorable heterojunction structure and thereby enhanced the charge separation.Thus,the g-C_3N_4/Bi_4O_5I_2 composite presented greater charge separation efficiency and much better photocatalytic performance than Bi_4O_5I_2.Additionally,g-C_3N_4/Bi_4O_5I_2 also presented high stability.·O_2~-and holes were verified to be the main reactive species. 相似文献
59.
活性炭吸附低浓度SO_2烟气的研究 总被引:2,自引:0,他引:2
利用水洗再生活性炭吸附法,对模拟火力发电厂烟气及克劳斯炉尾气进行脱除SO2的试验研究,SO2脱除率大于90%. 相似文献
60.
介绍位于纽约州北汉姆斯特城的PortWashington城市固体废弃物填埋场填埋气体的排放、监测和处理系统及其有关测试数据和从中得到的启示. 相似文献