Degradation of a Terephthalate-containing Polyester by a Thermophilic Microbial Consortium

Biomax^® is an aliphatic-aromatic polyester. The biodegradability of Biomax^® was studied at 58 °C using a laboratory scale bioreactor. The bioreactor was inoculated with bacteria derived from compost and supplemented with powdered Biomax^® and an additional energy source. After a period of acclimation, the microorganisms in the bioreactor were capable of metabolizing the major components of the polymer, i.e., TPA and ethylene glycol. TPA and ethylene glycol were detected in the bioreactor only when they were added. Degradation and disintegration of the powdered Biomax^® was monitored by laser diffraction. The particle size distribution of the powdered polymer progressively shifted toward smaller sizes until the diameters of the polymer particles were indistinguishable from bacteria. The types of microbes in the bioreactor were determined by analyzing 16S rRNA gene sequences. The bacteria belonged to 35 different groups, and the majority of the bacteria appeared to represent new species.     

液化气球罐应力腐蚀开裂试验研究

由于炼制进口高硫原油,在炼油球罐检验中发现越来越多的内表面应力腐蚀裂纹。对球罐应力腐蚀开裂的原因和主要影响因素进行分析。从液化石油气球罐的安全性出发,采用线弹性断裂力学方法,针对16MnR和SPV50Q球罐所用钢材,在分析湿硫化氢环境下应力腐蚀开裂形式的基础上,通过改进的WOL预裂纹试样的应力腐蚀开裂试验,对不同球罐所用钢材、不同硫化氢浓度、不同焊接状态条件下的应力腐蚀开裂进行研究,并对设备所采用的材料、所处的介质浓度、材料的热处理状况等进行分析,并提出了防止对策。该方法也适用于液化石油气球罐应力腐蚀开裂,以预测事故的发生。     

某工程机械厂电焊工作场所职业卫生学调查

为了解工程机械电焊工作场所存在的职业病危害因素及危害程度,采用定点及个体采样方法对某大型工种机械厂电焊车间进行采样分析,结果显示,该工作场所锰及其化合物、电焊烟尘时间加权平均浓度超出了国家职业接触限值,危害了工人身体健康,局部通风措施对控制电焊烟尘尤为重要。     

电焊作业人员尘肺病的预防

通过某检修安装企业从事焊接作业人员职业健康检查.对肺功能及X线高仟伏胸片检查结果进行分析评价,探讨电焊烟尘对作业人员肺部X线改变和肺通气功能的影响,提出电焊工尘肺的预防措施.     

FN1000m~2换热器管板与球封焊接结构安全性分析

以JB 4732标准对某企业FN1 000 m2换热器进行管板与球封焊接结构疲劳寿命计算,校核其疲劳寿命是否满足企业要求。疲劳寿命计算是在有限元应力分析结果满足JB 4732对强度要求的前提下,依据JB 4732中附录C疲劳寿命计算准则,计算FN1 000 m2换热器在交变载荷下允许最大应力循环次数。计算结果大于企业所规定的应力循环次数,满足了企业对换热器管板与球封焊接结构安全性疲劳寿命要求,节约了疲劳试验的时间与成本,对企业进行换热器结构优化具有指导意义。     

焊接工程质量与焊接工程文件

焊接质量只能是过程控制作为国际焊接标准体系中的核心标准ISO 3834给出过程控制手段就是焊接工程文件对不同质量等级对应的文件要求不同,等级越高的焊接产品,其过程控制的文件也越多,控制点更细,保证产品达到高品质要求.与之对比某事故工程的反例,该工程的焊接文件漏项多,过程控制不能保障焊接工程的安全.通过对比国际标准,发现由于国内产品焊接标准不够成熟,没有规定产品GB/T 12467质量等级(类似ISO 3834-2,3,4),因此文件分级欠专业要求.焊接制造业升级必然是标准先行,焊接标准明确质量等级,焊接工程文件体系也将完善,从而为保障焊接工程的安全运行保驾护航.     

Monitoring and assessment of toxic metals in Gulf War oil spill contaminated soil using laser-induced breakdown spectroscopy

Laser-induced breakdown spectroscopy (LIBS) was applied for the detection of toxic metals in oil spill contaminated soil (OSCS). The OSCS samples were collected from Khursania Saudi Arabia along the coast of Persian Gulf exposed to oil spills in 1991 Gulf war. Environmentally important elements like Aluminum Magnesium, Calcium, Chromium, Titanium, Strontium, Iron, Barium, Sodium, potassium, Zirconium and Vanadium from the contaminated soil have been detected. Optimal experimental conditions for analysis were investigated. The LIBS system was calibrated using standard samples containing these trace elements. The results obtained using Laser-Induced Breakdown Spectroscopy (LIBS) were compared with the results obtained using Inductively Coupled Plasma Emission Spectroscopy (ICP). The concentrations of some elements (Ba and Cr) were found higher than permissible safe limits. Health risks associated with exposure to such toxic elements are also discussed.     

Safety management by use of laser mass spectrometry of polychlorinated biphenyls (PCBs) in the processed gas and work environment of a PCB disposal plant

This study demonstrates the applicability of laser mass spectrometry for safety management of the processed gas and the work environment in a polychlorinated biphenyl (PCB) disposal plant. By utilization of laser ionization/ion trapping storage/time-of-flight mass spectrometry (LI-IT-TOFMS), we analyzed gaseous PCBs from scrap capacitors with on-line detection. It was confirmed that few contaminants were detected in the spectrum. By the effect of laser-induced selective ionization, it was considered that there was little interference with the mass range of PCBs. The accuracy of LI-IT-TOFMS when analyzing environmental gas was almost the same as that for the PCB standard gas. It was possible to perform on-line analysis of the work environment for over 2000 h (120 000 data points). LI-IT-TOFMS was thus shown to be a very useful method for ensuring the safety of the work environment in disposal plants for PCBs.     

袋式除尘器结构优化设计与虚拟装配关键技术

针对袋式除尘器大型化后在结构轻质化、模块化结构的可靠装配和焊接变形控制等方面面临的诸多问题,开展了系统的研究,发展了不同结构类型袋式除尘器快速参数化建模、整体和局部联合计算、梁柱连接节点的简化设计、整体计算中复杂花板结构简化、非线性多约束结构优化等复杂关键技术,开发了袋式除尘器结构计算和优化设计软件;提出了基于世界树的实体层次系统结构建模框架,开发了大型模块化袋式除尘器虚拟装配软件;分析了主要结构焊接变形、应力和应变分布及变化规律,提出了反变形法消除焊接变形的控制方法,并开展了实验验证。     

多参数环境试验舱焊接残余应力的有限元计算及分析

在钢结构舱体制造中,焊接是最主要的加工手段。焊接变形一方面导致结构变异,尺寸精度和承载能力下降,另一方面,在温度大幅度周期性变化过程中,应力集中等因素引起的早期结构失效是工程实践中的重大隐患。采用有限元方法,分析了一种步入式多参数环境试验舱焊接结构在焊接过程中的瞬态三维应力和形变,同时给出了在-70℃工况下的三维应力与变形分布,具有一定的参考意义。