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681.
Tait Chirenje L. Q. Ma A. G. Hornsby K. Portier W. Harris S. Latimer 《Environmental Forensics》2013,14(2):141-153
Knowledge of arsenic background concentrations in urban soils is important for making remediation decisions. The soil cleanup target level (SCTL) for arsenic in Florida lies within the range of arsenic background concentrations. The residential SCTL is also near the practical quantification limits using analytical procedures. Currently no standard protocols are available for determining arsenic background concentrations in urban soils, apart from site-specific cases. Therefore, a pilot study was conducted to develop and employ appropriate protocols to determine arsenic distribution in urban soils. This involved: site selection (e.g. size and sampling frame), sample collection (e.g. sampling technique), and statistical considerations (e.g. design). Factors such as ease of sample collection and maintaining anonymity of private properties were also considered as they influence the successful implementation of the study. Forty surface soil samples each were collected from five categories in three land use classes (residential-yard and right-of-way, commercial and public land-parks and public building), digested using EPA method 3051a and analysed using graphite furnace atomic absorption spectrometry. Experiences from the pilot study (e.g. complications during sample selection, digestion, data censoring etc.) were used in the development of the final protocol to be used in determining the distribution of arsenic in urban areas. 相似文献
682.
683.
Radon-222 and carbon dioxide concentrations have been measured during several years at several points in the atmosphere of an underground limestone quarry located at a depth of 18 m in Vincennes, near Paris, France. Both concentrations showed a seasonal cycle. Radon concentration varied from 1200 to 2000 Bq m−3 in summer to about 800-1400 Bq m−3 in winter, indicating winter ventilation rates varying from 0.6 to 2.5 × 10−6 s−1. Carbon dioxide concentration varied from 0.9 to 1.0% in summer, to about 0.1-0.3% in winter. Radon concentration can be corrected for natural ventilation using temperature measurements. The obtained model also accounts for the measured seasonal variation of carbon dioxide. After correction, radon concentrations still exhibit significant temporal variation, mostly associated with the variation of atmospheric pressure, with coupling coefficients varying from −7 to −26 Bq m−3 hPa−1. This variation can be accounted for using a barometric pumping model, coupled with natural ventilation in winter, and including internal mixing as well. After correction, radon concentrations exhibit residual temporal variation, poorly correlated between different points, with standard deviations varying from 3 to 6%. This study shows that temporal variation of radon concentrations in underground cavities can be understood to a satisfactory level of detail using non-linear and time-dependent modelling. It is important to understand the temporal variation of radon concentrations and the limitations in their modelling to monitor the properties of natural or artificial underground settings, and to be able to assess the existence of new processes, for example associated with the preparatory phases of volcanic eruptions or earthquakes. 相似文献
684.
A number of recent studies have suggested that black carbon (BC), the light-absorbing fraction of soot, is next to CO2 one of the strongest contributors to the global climate change. BC heats the air, darkens the snow and ice surfaces and could contribute to the melting of Arctic ice, snowpacks, and glaciers. Although soot is the oldest known pollutant its importance in climate modification has only been recently recognized. In this article, we trace the historical developments over about three decades that changed the view of the role of BC in the environment, from a pollutant of marginal importance to one of the main climate change agents. We also discuss some of the reasons for the initial lack of interest in BC and the subsequent rigorous research activity on the role of aerosols in climate change. 相似文献
685.
Occurrence of polybrominated diphenyl ethers in soil from the central Loess Plateau, China: role of regional range atmospheric transport 总被引:3,自引:0,他引:3
Very few studies were conducted in highland and depositional areas in studying the transport and behavior of polybrominated diphenyl ethers (PBDEs). In this study, surface soils were collected from Huan County to investigate the level, profile, and potential influence of PBDEs via regional range atmospheric transport in the central part of the Loess Plateau (CLP) of China, one of the most extensive areas of loess deposition in the world. PBDEs were ubiquitous and log-normally distributed in soils from the CLP with mean concentrations of 0.91 and 0.54 ng g−1 for ΣPBDEs (sum of PBDE congeners except for BDE-209) and BDE-209, respectively. BDE-209 was predominated congener (43.5%), followed by BDE-47 (15.7%), 99 (10.7%), and 153 (7.5%). Further principal component analysis on congener profiles showed that PBDEs in the CLP originated from similar source(s). Additionally, significant differences in the ratios of BDE-47 to 99 and BDE-153 to 154 were found between soil samples and commercial products, indicating that they have undergone fractionation during the process of regional range atmospheric transport. The deposition of PBDEs in the CLP could be influenced by the sources from surrounding regions. For example, Xi’an may have potential influence to the CLP based on geographical analysis and concentrations comparison of PBDEs in gaseous. Therefore, more studies are needed to clarify the atmospheric transport and fate of PBDEs in this region. 相似文献
686.
The diurnal atmospheric phosphine (PH3) concentrations and fluxes at the water-air interface in Lake Taihu were reported. The results showed that the PH3 flux at the water-air interface ranged from −69.9 ± 29.7 to 121 ± 42 ng m−2 h−1, with a mean flux of 14.4 ± 22.5 ng m−2 h−1. The fluxes were both negative and positive during the diurnal period, indicating that the lake can act as a sink and a source of PH3. In addition, the PH3 fluxes were positively correlated with water temperature, total soluble phosphorus and soluble reactive phosphorus, while they were negatively correlated with water redox potential. A similar diurnal variation curve of atmospheric PH3 concentrations was observed during all four seasons, with the maximum level occurring in early morning and the minimum appearing around midday. These findings suggest that light plays an important role in the elimination of atmospheric PH3. A significant positive correlation was also found between air temperature and atmospheric PH3 concentration. The mean flux of PH3 in Lake Taihu was higher than in other reported wetlands, with an estimated annual emission of PH3 to the atmosphere of 2.94 × 105 g y−1. 相似文献
687.
The gas phase atmospheric degradation of diazinon has been investigated at the large outdoor European Photoreactor (EUPHORE) in Valencia, Spain. The rate constant for reaction of diazinon with OH radicals was measured using a conventional relative rate method with di-n-buthylether as reference compound being k = (3.5 ± 1.2) × 10−11 cm3 molecule−1 s−1 at 302 ± 10 K and atmospheric pressure. The available evidence indicates that tropospheric degradation of diazinon is mainly controlled by reaction with OH radicals, and that the tropospheric lifetime with respect to the OH reaction is estimated to be around 4 h whereas its lifetime with respect to the photolysis is higher than 1 d under our conditions. Significant aerosol formation was observed following the reaction of diazinon with OH radicals, and the main carbon-containing products detected in the particle phase were hydroxydiazinon, hydroxydiazoxon and 2-isopropyl-6-methyl-pyrimidinyl-4-ol. 相似文献
688.
Xiao HY Wu LH Zhu RG Wang YL Liu CQ 《Environmental pollution (Barking, Essex : 1987)》2011,159(2):363-367
Nitrogen isotopic composition of new, middle-aged and old camphor leaves in upper and lower canopies has been determined in a living area, near a motorway and near an industrial area (Jiangan Chemical Fertilizer Plant). We found that at sites near roads, more positive δ15N values were observed in the camphor leaves, especially in old leaves of upper canopies, and ?δ15N = δ15Nupper − δ15Nlower > 0, while those near the industrial area had more negative δ15N values and ?δ15N < 0. These could be explained by two isotopically different atmospheric N sources: greater uptake from isotopically heavy pools of atmospheric NOx by old leaves in upper canopies at sites adjacent to roads, and greater uptake of 15N-depleted NHy in atmospheric deposition by leaves at sites near the industrial area. This study presents novel evidence that 15N natural abundance of camphor leaves can be used as a robust indicator of atmospheric N sources. 相似文献
689.
Atmospheric nitrogen deposition: revisiting the question of the importance of the organic component 总被引:2,自引:0,他引:2
Cornell SE 《Environmental pollution (Barking, Essex : 1987)》2011,159(10):2214-2222
The organic component of atmospheric reactive nitrogen plays a role in biogeochemical cycles, climate and ecosystems. Although its deposition has long been known to be quantitatively significant, it is not routinely assessed in deposition studies and monitoring programmes. Excluding this fraction, typically 25-35%, introduces significant uncertainty in the determination of nitrogen deposition, with implications for the critical loads approach. The last decade of rainwater studies substantially expands the worldwide dataset, giving enough global coverage for specific hypotheses to be considered about the distribution, composition, sources and effects of organic-nitrogen deposition. This data collation and meta-analysis highlights knowledge gaps, suggesting where data-gathering efforts and process studies should be focused. New analytical techniques allow long-standing conjectures about the nature and sources of organic N to be investigated, with tantalising indications of the interplay between natural and anthropogenic sources, and between the nitrogen and carbon cycles. 相似文献
690.
Heimbürger LE Migon C Cossa D 《Environmental pollution (Barking, Essex : 1987)》2011,159(6):1629-1634
Under stratified oligotrophic conditions (May-November), the surface mixed layer of the Northwestern Mediterranean constitutes a homogeneous water volume of 10-30 m depth. In other respects, the mean residence time of Ligurian surface waters (0-200 m) is 102 days. It is therefore possible to quantify the extent to which atmospheric deposition of trace metals affects surface waters. On the basis of literature data on anthropogenic and natural trace metals, we demonstrate that the ratios between total seawater labile atmospheric deposition during 102 days (Δc) and dissolved TM concentrations in Ligurian surface waters (c) illustrate the impact of atmospheric deposition on surface seawater (Δc/c). High ratios indicate surface TM enrichments, while low ratios indicate surface TM depletion, due to the quasi-complete sorption and removal of TMs by plankton during spring bloom. The simple box model proposed here may be used for other marine regions where hydrodynamical and physico-chemical constraints are well defined. 相似文献