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121.
阳离子交换树脂生产中废酸的回收利用及树脂质量控制 总被引:3,自引:0,他引:3
采用 酸套洗工艺代替传统的加水稀释洗涤工艺,成功地解决了阳离子交换树脂生产中废酸的回收利用问题,研究了采用新洗涤工艺后树脂变红的机理和防止对策,结果表明,树脂发红帅微生物的参与而引起的。采以完善洗涤 灭菌措施可防止树脂 ,从而确保了稀酸套洗工艺的顺利实施。 相似文献
122.
123.
测定了国产高分子小球GDX-102对水中微量有机氯农药(β-666、p,p’-DDE和p,p’-DDT)的吸附容量和富集效率,选取了动态富集最佳水样流速.结果表明,GDX-102对上述三种有机氯农药均有较大的吸附容量,其数值分别为14.2mg/g(β-666)、22.3mg/g(p,p’-DDE)和31.4mg/g(p,p’-DDT).在实验条件下,水样流速在0—60ml/min范围内变化时,对GDX-102的富集效率影响甚小,富集效率接近100%,因此,GDX-102可应用于环境水样中微量有机氯农药的现场采样富集. 相似文献
124.
125.
废旧电路板与碳酸钙共热解脱卤的研究 总被引:4,自引:1,他引:3
采用热重分析仪和石英管式炉热解反应器,分别对以酚醛树脂为基板的废旧电路板和混合碳酸钙后的废旧电路板进行热解实验研究,着重考察了添加碳酸钙后的酚醛树脂基板废旧电路板热解特性及添加量不同对卤素脱除效果的影响。实验结果表明,碳酸钙的加入对废旧电路板的降解行为和热解油的基本组成没有明显的影响,但热解油的各组分含量有所差异;随着热解温度的提高或者CaCO3含量的增多,卤素可以更多地由有机卤向无机卤转变并束缚在固体残渣中,由此得到较好的脱卤效果。当60%PR-WPCBs与40%CaCO3共热解,热解油中的溴化物也减少了7.6% 。在600℃等量CaCO3与PR-WPCBs共热解时生成75.6%无机卤,其中70.62%束缚于固体残渣中,可见达到较好的脱卤效果。 相似文献
126.
Matthias H.A. Jungck Jean-Louis Andrey Pascal Froidevaux 《Journal of environmental radioactivity》2009
The evaluation of radioactivity accidentally released into the atmosphere involves determining the radioactivity levels of rainwater samples. Rainwater scavenges atmospheric airborne radioactivity in such a way that surface contamination can be deduced from rainfall rate and rainwater radioactivity content. For this purpose, rainwater is usually collected in large surface collectors and then measured by γ-spectrometry after such treatments as evaporation or iron hydroxide precipitation. We found that collectors can be adapted to accept large surface (diameter 47 mm) cartridges containing a strongly acidic resin (Dowex AG 88) which is able to quantitatively extract radioactivity from rainwater, even during heavy rainfall. The resin can then be measured by γ-spectrometry. The detection limit is 0.1 Bq per sample of resin (80 g) for 137Cs. Natural 7Be and 210Pb can also be measured and the activity ratio of both radionuclides is comparable with those obtained through iron hydroxide precipitation and air filter measurements. Occasionally 22Na has also been measured above the detection limit. A comparison between the evaporation method and the resin method demonstrated that 2/3 of 7Be can be lost during the evaporation process. The resin method is simple and highly efficient at extracting radioactivity. Because of these great advantages, we anticipate it could replace former rainwater determination methods. Moreover, it does not necessitate the transportation of large rainwater volumes to the laboratory. 相似文献
127.
Size and resin fractionations of dissolved organic matter and trihalomethane precursors from four typical source waters in China 总被引:3,自引:0,他引:3
Wei Q Wang D Wei Q Qiao C Shi B Tang H 《Environmental monitoring and assessment》2008,141(1-3):347-357
Dissolved organic matter (DOM) and its potential to form disinfection by-products (DBPs) during drinking water treatment raise
challenges to water quality control. Understanding both chemical and physical characteristics of DOM in source waters is key
to better water treatment. In this study, the DOM from four typical source waters in China was fractionated by XAD resin adsorption
(RA) and ultrafiltration (UF) techniques. The trihalomethane formation potential (THMFP) of all fractions in the DOM were
investigated to reveal the major THM precursors. The fraction distributions of DOM could be related to their geographical
origins in a certain extent. The dominant chemical fraction as THM precursors in the DOM from south waters (East-Lake reservoir
in Shenzhen and Peal rivers in Guangzhou) was hydrophobic acid (HoA). The size fraction with molecular weight (MW) <1 kDa
in both south waters had the highest THMFP. The results of cluster analysis showed that the parameters of fractions including
DOC percentage (DOC%), UV254%, SUVA254 (specific UV254 absorbance) and THMFP were better for representing the differences of DOM from the studied waters than specific THMFP (STHMFP).
The weak correlation between SUVA254 and STHMFP for either size or XAD fractions suggests that whether SUVA254 can be used as an indicator for the reactivity of THM formation is highly dependent on the nature of organic matter. 相似文献
128.
A new approach for isolation and identification of elecrtophilic mutagens from complex matrix was developed.Thiosulfonic anion was immobilized onto polystyrene beads and used as separation media.Potassium polystyryl-thiosulfonate,prepared from polystyryl- sulfonyl chloride and KHS,was observed to selectively react with model electrophilic mutagens such as alkyl halides,α-chloroketones andα-chloroesters to produce polystyryl-thiosulfonic esters.After separation from other nonreactive organic compounds,the beads then reacted with ethanethiol to produce unsymmetrical ethyl disulfides which are easily detected by GC/MS.For one mutagenic compound,only one unsymmetrical disulfide was found to contain its structure part.Thus,the structure of the parent mutagens could be deduced from that of the unsymmetrical disulfides.The degree of functionaiization of the potassium polystyryl-thiosulfonate resin was 1.11 mmol/g.Its reactivity was discussed and its recycling method was reported here. 相似文献
129.
130.