Catalytic performance of Fe3O4-CoO/Al2O3 catalyst in ozonation of 2-(2,4-dichlorophenoxy)propionic acid, nitrobenzene and oxalic acid in water

Fe3O4-CoO/Al2O3 catalyst was prepared by incipient wetness impregnation using Fe(NO3) 3·9H2O and Co(NO3) 2·6H2O as the precursors,and its catalytic performance was investigated in ozonation of 2-(2,4-dichlorophenoxy) propionic acid(2,4-DP) ,nitrobenzene and oxalic acid.The experimental results indicated that Fe3O4-CoO/Al2O3 catalyst enabled an interesting improvement of ozonation eciency during the degradation of each organic pollutant,and the Fe3O4-CoO/Al2O3 catalytic ozonation system followed a radical-type mechanism.The kinetics of ozonation alone and Fe3O4-CoO/Al2O3 catalytic ozonation of three organic pollutants in aqueous solution were discussed under the mere consideration of direct ozone reaction and OH radical reaction to well investigate its performance.In the catalytic ozonation of 2,4-DP,the apparent reaction rate constants(k) were determined to be 1.456×10-2 min-1 for ozonation alone and 4.740×10-2 min-1 for O3/Fe3O4-CoO/Al2O3.And O3/Fe3O4-CoO/Al2O3 had a larger Rct(6.614×10-9) calculated by the relative method than O3 did(1.800×10-9) ,showing O3/Fe3O4-CoO/Al2O3 generated more hydroxyl radical.Similar results were also obtained in the catalytic ozonation of nitrobenzene and oxalic acid.The above results demonstrated that the catalytic performance of Fe3O4-CoO/Al2O3 in ozonation of studied organic substance was universal to a certain degree.     

粮食蔬菜与土壤和大气中苯并（a）芘含量的相关性研究

对山西省运城市盐湖区不同区域内小麦、西红柿、白菜和土壤中B（a）P含量的空间一时间分布及大气、土壤与粮食、蔬菜中B（a）P含量关系进行了调查研究,结果表明,粮食和蔬菜中的B（a）P主要来自大气污染的“贡献”,土壤中的B（a）P的含量也直接影响粮食和蔬菜中B（a）P的含量。当小麦子实中B（a）P的含量达到一定水平后,并不随土壤中B（a）P含量的增加而增加。     

毛竹遗态 Fe2O3／Fe3O4／C 复合材料对水中锑（III）的吸附研究

以毛竹遗态Fe2 O3／Fe3 O4／C复合材料为吸附剂,锑（III ）初始含量、溶液初始pH值、吸附剂投加量以及吸附剂粒径为影响因素开展吸附影响研究。结果表明,随着锑（III ）初始浓度的升高,毛竹遗态Fe2 O3／Fe3 O4／C复合材料对锑（III ）的吸附量逐渐增加;初始溶液pH为7时,对锑（III ）的吸附效果最好,吸附量为4．7821 mg／g;块状吸附剂对水中锑（III ）的去除率和吸附量与粉末状吸附剂吸附效果相当。     

Bi/Fe_3O_4催化NaBH_4还原水中对硝基苯酚

以磁性Fe_3O_4为载体负载Bi(NO_3)_3,再用NaBH_4还原Bi~(3+)制备了Bi/Fe_3O_4催化剂。采用XRD和紫外-可见光谱对催化剂进行表征。考察了Bi负载量、NaBH_4加入量和Bi/Fe_3O_4加入量对Bi/Fe_3O_4催化NaBH_4还原对硝基苯酚(4-NP)效果的影响。表征结果显示:当催化剂中Bi含量较少时,Bi分散良好;当Bi含量较多时,会形成纳米颗粒。实验结果表明:当反应温度为25℃,初始4-NP浓度为4.0 mmol/L时,在Bi负载量为5%(w)、Bi/Fe_3O_4催化剂加入量为500 mg/L,NaBH_4加入量为6.0 g/L的条件下,反应速率常数为0.581 min~(-1),4-NP的去除率为99.7%;Bi/Fe_3O_4催化剂稳定性好,重复使用15次后,活性基本不变。     

S型皮托管截面受损与皮托管系数变化的实验研究

污染源排放废气流速通常在7～15m／s之间。通过S型皮托管在低速风洞中与标准皮托管的对比实验说明,在10m／s,15m／s两种情况下,皮托管迎风面截面变化对皮托管系数却的影响很大,实验结果可供污染源废气监测和皮托管定期检定进行参考。     

江西葛源黄山铌（钽）矿床地质特征及成因分析

江西葛源黄山铌（钽）矿床位于灵山花岗岩体西侧的内外接触带上,受赣东北深大断裂及其次级北东向和北西西向断裂的控制。围岩蚀变主要为角岩化、矽卡岩化和黑鳞、铁锂云母岩化等。总体矿化特征,近岩体富铌,远岩体而富钽。     

稀土元素与辣根过氧化物酶相互作用机理的论述

叙述了稀土元素的化学结构及其在农业方面的应用,系统介绍了植物辣根过氧化物酶(HRP)的结构及其在植物体内的功能,并以重稀土元素Tb(Ⅲ)为例,通过探讨其对HRP的酶活和生态毒理效应等影响的研究,对两者相互作用的可能性机理进行了研究。     

公众参与环评听证法律问题研究

对于比较敏感或涉及面较广建设项目的环境影响评价公众参与的表达途径,一般采用听证会。在中国,公众参与环评听证会,在听证公告、代表遴选、政府回应方面都面临困境,需要分别找寻出路:对于听证公告,要明确适用范围、确立合理期限、完善内容规定、采用合理方式来应对;对于代表遴选,建立一整套行之有效的制度势在必行;对于政府回应,建立一个合理的评估系统、启动司法审查不失为良策。     

钢铁企业节水评价指标体系的构建

针对中国钢铁行业尚未建立节水评价指标体系的现状,在广泛查阅资料的基础上,遵循科学合理性、目标导向性、实用性和可比性的原则,构建了钢铁企业节水评价指标体系。指标体系的建立使钢铁企业的节水成效具有横向和纵向可比性,有利于调动企业的节水积极性,促进节水技术的发展和推广,为钢铁企业开展节水工作指明目标和方向。     

Ferric citrate-induced photodegradation of dyes in aqueous solutions

The photooxidation of dye solutions containing Fe(III)-citrate complexes was studied. The photodegradation under near-UV light of the five dyes, C. I. reactive red 2, C. I. reactive blue 4, C. I. reactive black 8, C. I. basic red 13 and C. I. basic yellow 2, in aqueous solutions at pH2.0 containing Fe(III)-citrate complexes was found to follow pseudo-first order kinetics. The photodegradation rates of the dye, C. I. reactive red 2, decreased with increasing the initial dye concentration in range of 20 – 60 mg/L . A comparatively higher photodegradation efficiency of the dye was gained under the condition of pH2.0 and the Fe(III) to citrate ratio 1:2.