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61.
G. G. D. Silva P. J. A. Sobral R. A. Carvalho P. V. A. Bergo O. Mendieta-Taboada A. M. Q. B. Habitante 《Journal of Polymers and the Environment》2008,16(4):276-285
The aim of this work was to develop biodegradable films based on blends of gelatin and poly (vinyl alcohol) (PVA), without a plasticizer. Firstly, the effect of five types of PVA with different degree of hydrolysis (DH) on the physical properties of films elaborated with blends containing 23.1% PVA was studied. One PVA type was then chosen for the study of the effect of the PVA concentration on the mechanical properties, color, opacity, gloss, and water solubility of the films. The five types of PVA studied allowed for films with different characteristics, but with no direct relationship with the DH of the PVA. Therefore, the PVA Celvol®418 with a DH = 91.8% was chosen for the second part, because they produced films with greater tensile strength. The PVA concentration affected all studied properties of films. These results could be explained by the results of the DSC and FTIR analyses, which showed that some interactions between the gelatin and the PVA occurred depending on the PVA concentration, affecting the crystallinity of the films. 相似文献
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63.
《Journal of Manufacturing Processes》2014,16(3):363-372
The dimpling process is a novel cold-roll forming process that involves dimpling of a rolled flat strip prior to the roll forming operation. This is a process undertaken to enhance the material properties and subsequent products’ structural performance while maintaining a minimum strip thickness. In order to understand the complex and interrelated nonlinear changes in contact, geometry and material properties that occur in the process, it is necessary to accurately simulate the process and validate through physical tests. In this paper, 3D non-linear finite element analysis was employed to simulate the dimpling process and mechanical testing of the subsequent dimpled sheets, in which the dimple geometry and material properties data were directly transferred from the dimpling process. Physical measurements, tensile and bending tests on dimpled sheet steel were conducted to evaluate the simulation results. Simulation of the dimpling process identified the amount of non-uniform plastic strain introduced and the manner in which this was distributed through the sheet. The plastic strain resulted in strain hardening which could correlate to the increase in the strength of the dimpled steel when compared to plain steel originating from the same coil material. A parametric study revealed that the amount of plastic strain depends upon on the process parameters such as friction and overlapping gap between the two forming rolls. The results derived from simulations of the tensile and bending tests were in good agreement with the experimental ones. The validation indicates that the finite element analysis was able to successfully simulate the dimpling process and mechanical properties of the subsequent dimpled steel products. 相似文献
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To improve the mechanical properties of the electrospun nanofibrous membrane, the nonwoven fabrics and spacer fabrics were employed as support substrates to fabricate polyvinylidene fluoride(PVDF) nanofibrous composite membranes. The influences of the substrate on membrane morphology, hydrophobicity, pore size and pore size distribution,porosity, mechanical strength and permeability were comprehensive evaluated. The electrospun composite membranes had a three dimension bead-fiber interconnected open structure and a rough membrane surface. The membrane surface presented a multilevel re-entrant structure and all the water contact angles were above 140°. In contrast with the pure PVDF nanofibrous membrane, the stress at break and the elastic modulus of the composite membranes increased by 4.5–16 times and 17.5–37 times, respectively. Since the spacer fabrics had less resistance to mass transfer, the membranes composited with spacer fabrics exhibited greater permeate fluxes compared with the composite membranes with the nonwoven fabrics as substrates.During the membrane distillation test, the highest permeate flux was up to 49.3 kg/m~2/hr at the feed temperature of 80°C. The long-time and repeat operation of membrane distillation desalination indicated the fabricated membrane with a good resistance to scaling and wetting.The results suggested the potential of the electrospun composite membrane for membrane distillation application. 相似文献
67.
采用铝合金厚壁圆筒进行了二次机械自紧实验研究,获得的结果充分表明,二次机械自紧技术作为降低冲头推力为目的的工艺方法,效果是明显的和有效的,可满足不同口径厚壁筒机械自紧的要求. 相似文献
68.
城市地下车库联络通道作为一种新型的地下交通联络通道,可净化地面交通,提高土地利用率,解决城市交通拥堵问题。然而这种通道兼有地下车库和城市交通隧道的特点,结构复杂,一旦发生火灾,损失较大。其防火设计的难点在于如何定性并选择合适的规范条文,因此有必要系统研究其消防安全问题并提出有效解决方案。以某城市地下车库联络通道为例,研究该通道的火灾危险性,提出防火分隔、探测报警、排烟以及人员安全疏散等消防设计方案和管理对策,并通过数值模拟方法验证了该方案的有效性和可行性。 相似文献
69.
Ham PA Prommer H Olsson AH Schotting RJ Grathwohl P 《Journal of contaminant hydrology》2007,93(1-4):304-315
A model-based interpretation of laboratory-scale experimental data is presented. Hydrolysis experiments carried out using thin glass tanks filled with glass beads to construct a hypothetical and inert, homogeneous porous medium were analysed using a 2D numerical model. A new empirical formula, based upon results for non-reactive (tracer) experiments is used to calculate transversal dispersivity values for a range of grain sizes and any flow velocities. Combined with effective diffusion coefficients calculated from Stokes-Einstein type equations, plume lengths arising from mixing between two solutes can be predicted accurately using numerical modelling techniques. Moreover, pH and ion concentration profiles lateral to the direction of flow of the mixing species can be determined at any given point downstream, without the need for result fitting. In our case, this approach does not lead to overpredictions of lateral mixing, as previously reported when using parameters derived from non-reactive tracer experiments to describe reactive solute transport. The theory is based on the assumption of medium homogeneity. 相似文献
70.
一家机械加工厂采用先进的工艺和设备代替落后的工艺和设备,并且撤消了一些工序和对生产车间进行了重新布局,不仅提高了工作效率,而且减少了环境污染,促进了清洁生产,对此,从废水,废气,噪声和废渣四个方面进行了详细评述。 相似文献