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841.
通过室内静态模拟浸泡试验,文章探讨了平煤集团十二矿附近的土壤对该矿煤矸石井下填充过程中地下水溶出的F-和SO42-的吸附性能.研究发现:土壤对F-吸附效果较好,而对SP42-较差;改性土壤对F-和SO42-的吸附效果均较好,均能使其在地下水中的含量达到地下水Ⅲ类标准;F-和SO42-在改性土壤上的吸附等温模型分别符合Freundlich、Temkin等温式;改性土壤对F-和SO42-的解吸过程分为快速和慢速两个反应阶段.通过试验数据分析得出:井下填充时煤矸石和改性土壤的最佳配比为1∶0.26. 相似文献
842.
Thuan Van Tran Duyen Thi Cam Nguyen Hanh T.N. Le Dai-Viet N. Vo Sonil Nand Trinh Duy Nguyen 《环境科学学报(英文版)》2020,32(7):137-150
Aquatic contamination of diclofenac (DCF), an emergent non-steroidal anti-inflammatory drug (NSAIDs), can result in adverse effects to many ecosystems through biomagnification. Hence, introducing effective remediation techniques to sequester the pharmaceutical wastes is highly fundamental to prevent their accumulation in the environment. Generally, adsorption has been presented as a green and efficient approach. Herein, we report the characterization and application of the novel magnetic nanocomposite ([email protected]2O4) derived from cobalt-based ferrite (CoFe2O4) and graphene oxide (GO) for DCF adsorption. For the optimization procedure, the response surface methodology (RSM) was adopted to investigate the impacts of DCF concentration (1.6–18.4 mg/L), DCF dosage (0.08–0.92 g/L), and solution pH (2.6–9.4) to find the optimum conditions for DCF removal, at 10.5 mg/L, 0.74 g/L, and pH 4, respectively. For the adsorption experiments, the kinetic, isotherm, thermodynamic, and intraparticle diffusion models were systematically studied. Moreover, we have elucidated the role of functional groups on the surface of [email protected]2O4 in enhancing the adsorption of DCF drug. With good removal efficiency (up to 86.1%), high maximum adsorption capacity (32.4 mg/g), [email protected]2O4 can be a potential candidate to eliminate DCF drug from water. 相似文献
843.
军港舰船油污水间歇式处理系统的研究 总被引:1,自引:0,他引:1
阐述了军港油污水间歇式处理系统的组成和处理工艺流程;较详细地分析了该系统用的无机一有机复合混凝剂和高效亲脂吸附过滤材料的性能,以及在舰船油污水处理中发挥的重要作用;试验研究表明,该处理系统工艺不复杂、操作方便,而且科技含量高、处理效果好。 相似文献
844.
Adsorption-desorption behavior of acetochlor to soils in the presence of some environmental substances 总被引:5,自引:0,他引:5
IntroductionAlthoughtheherbicideacetochlor [2 chloro N (ethoxymethyl) N (2 ethyl 6 methylphenyl)acetamide]hasbeenusedfortenyearsinChina,limitedinformationhasbeencollectedtodetermineitsfateandtransportintheenvironment.Formulationsaregenerallysoldasemulsifiabl… 相似文献
845.
Assessment of labile phosphorus fractions and adsorption characteristics in relation to soil properties of West African savanna soils 总被引:2,自引:0,他引:2
O. C. Nwoke B. Vanlauwe J. Diels N. Sanginga O. Osonubi R. Merckx 《Agriculture, ecosystems & environment》2003,100(2-3):285
A large proportion of total P in the soils of the area is unavailable to plants and consequently P is the second most limiting nutrient. The labile and moderately labile phosphorus fractions and adsorption characteristics of surface and subsurface horizons of eleven soil profiles in the derived savanna (DS) and the northern Guinea savanna (NGS) of West Africa were assessed. The labile P fractions are the resin and HCO3-extractable inorganic (Pi) and organic (Po) P. The moderately labile fractions are the NaOH-extractable portion of soil P in the Hedley sequential procedure. In the DS soils, the resin P, considered the most readily available fraction, varied from 1 to 14 mg kg−1, HCO3-Pi ranged from 3.3 to 11, and HCO3-PO was between 4 and 12 mg kg−1 in the surface horizon. In the NGS, the topsoil contained 1.5–3 mg kg−1 of resin P, 5–8 mg kg−1 of HCO3-Pi, and 7.5–9.7 mg kg−1 of HCO3-Po. Sodium hydroxide-Po was the largest of the fractions in all the soils studied. It ranged from 23 to 55 mg kg−1 in the topsoil. In general, the labile P levels were higher in soils of the DS than of the NGS and were related to the oxalate-extractable Fe (Feox), and Al (Alox) as well as to soil texture. The subsoil of Kasuwan Magani (profile KS 9–21 cm) required 153 mg P kg−1 to maintain 0.2 mg P l−1 in solution (standard P requirement), and Danayamaka (profile DD 7–32 cm) required 145 mg P kg−1. These could translate to 214 and 200 kg P ha−1 if a plow layer of 10 cm is assumed. Because these are within the plow layer, more P fertilizer would be needed for crop production than in the other soils. The standard P requirement and the adsorption maxima were related to Feox and Alox, dithionite-Fe (Fed), and texture. The increase in labile P content with decreasing Feox and Alox could imply that management practices capable of reducing the activities of Fe and Al in solution might improve P availability. 相似文献
846.
IntroductionChromium ,whichistoxictomanandotherlivingorganisms,presentspotentiallyseriousenvironmentalproblemsthroughouttheworld .ChromiummainlyexistsintwoformsasCrⅢ andCrⅥ .CrⅢisoflesspoisonousness,butCrⅥ exhibitsastrongtoxicity .WhenCrⅥisdischargedintowa… 相似文献
847.
848.
天然水颗粒电动电位的化学模型 总被引:1,自引:0,他引:1
结合表面络合化学和双电层物理理论建立天然水颗粒电动电位(即ζ电位)与颐粒表面固有的化学性质及天然水化学条件之间的定量关系。在不同化学条件下,对均匀胶体颗粒(包括聚苯乙烯Latex颗粒和α-Fe_2O_3颗粒)进行电泳测定来验证该模型。结果表明,颗粒表面ζ电位与颗粒表面离子化官能团(—COOH或—OH)的化学性质、天然水pH值和专属吸附的阴阳离子(Ca~(2+)和PO_4~(3-))有密切关系。 相似文献
849.
In this work,hydrothermal technique combined with KOH activation were employed to develop a series of porous carbons (NPCK-x) using tobacco stem as a low-cost carbon source and (NH4)2C2O4 as a novel nitrogen-doping agent.Physicochemical properties of NPCK-x were characterized by Brunauer-Emmett-Teller,field emission scanning electron microscopy,X-ray diffraction,Raman microscope,elemental analysis,and X-ray photoelectron spectroscopy.Results showed tha... 相似文献