砷矿尾砂污染及其治理研究

调查了广东省连南瑶族自治县寨岗铁屎坪土法炼砷废墟及其周边砷污染状况.发现渗流水含砷高达43.72 mg/L,渗流水随雨水沿山坡、溪流流入下游,对周边的水体、土壤、农作物等造成严重污染.同时发现全缘凤尾蕨、龙船蕨、野苎麻、白芒草和接骨草是耐砷植物.模拟试验证实在炼砷废墟和高砷尾砂上种植这些植物可减少砷的迁移,且不致引起二次污染.1998年对铁屎坪土法炼砷废墟进行治理,经一年多跟踪观察,周边水体中砷含量从原来的约0.048 mg/L下降到0.001 06 mg/L.结果表明用植被治理尾砂的砷污染是一种价廉、有效的方法.     

Ecotypes diversity in autumn olive (Elaeagnus umbellata Thunb): A single plant with multiple micronutrient genes

Elaeagnus umbellata, a member of the Elaeagnaceae family, is native to Pakistan, China, India, Korea, and Japan. It is found commonly at altitudes ranging from 1200 to 2100 m and thrives on eroded and degraded land due to its ability to fix nitrogen. The plant also grows under variable pH (4-8) and drought, and is used locally as fuel wood, fencing, fodder, basket making, and shelterbelts. The fruit of the plant is well known for its essential nutrients and medicinal compounds such as vitamins, minerals, essential fatty acids, carotenoids (lycopene), soluble solids, and sugars. Medicinally, it is widely believed to protect against myocardial infections, pulmonary infections, and various forms of cancers. Ten ecotypes from variable microclimatic conditions were investigated for their morphological, molecular and biochemical diversity improvement and commercialization purposes. Comparisons and disabilities indicated significant variability in terms of morphological (plant height, number of branches, thorn size and number, leaf area, fruit size, 100 fruit weight, and yield), molecular (SDS-PAGE), and micro- and macronutrient (vitamin C, Fe, mg, P, Na, K, essential oils, and sugar) bases among the ecotypes. This variability will be helpful in developing commercial varieties of the plant utilizing the conventional techniques of selection and hybridization for economic activities. The plant has ample quantities of multiple micronutrients, thus indicating their expression through a powerful promoter at one place (fruit mesocarp). Efforts to identify and isolate the micronutrient genes (vitamin A, C, E, and Fe), the deficiency of which causes malnutrition and disabilities within the population of developing countries. Micronutrient genes have also been initiated for their characterization and future transformation into staple food crops for stable bio-fortification.     

The growth of develop-for-import projects

This article examines develop-for-import projects financed by development loans and mixed credits supplied by export-import banks and other financial institutions of the central governments of France, Japan and the Federal Republic of Germany. The projects discussed are those producing bauxite, alumina, aluminium, chromium, copper, iron, manganese, molybdenum, nickel and tungsten, in developing market economies, Australia and Canada. The article estimates the volume of these metals committed to France, Japan and FRG to pay for loans and credits, examines the types of financial arrangement involved in develop-for-import projects, and considers the compatibility of these arrangements with the multilateral liberalized world trading system developed by the General Ageement on Tariffs and Trade (GATT) over the past 40 years. To the extent that these arrangements do not fully reflect changes in international market forces, world trade in metals will tend to be distorted and discriminatory.     

Landowner equity in Papua New Guinea's minerals sector: Review and policy issues

The involvement of local communities as equity holders in major mineral resource developments dates back over a decade in Papua New Guinea. This article reviews the history and result of landowner equity at two of Papua New Guinea's major mines (Porgera and Lihir), with a particular focus on the contribution of these equity holdings to local sustainable development. It is found that while an equity holding can provide significant returns to a local community, it also exposes them to significant financial risk. A second major area of concern is the structures and instruments by which revenues generated from the equity are distributed and utilized within the local community. Further research and policy redirection is required before local equity holding can be viewed as making a significant contribution to local sustainable development.     

From the Whitehorse Mining Initiative Towards Sustainable Mining: lessons learned

Much debate has taken place within the mineral policy community about whether or not meaningful progress has been made towards more sustainable practices. This paper investigates the changing approaches towards sustainable development undertaken by the Mining Association of Canada (MAC) over a period of approximately 20 years. The analysis begins in the early 1990s when MAC initiated the Whitehorse Mining Initiative (WMI) and concludes in 2010 when the association was operating under a strategy entitled Towards Sustainable Mining (TSM). The goal is to consider the nature of the learning that has taken place towards sustainability within the mineral industry using the case of a leading national mining association. The investigation was undertaken through a literature review as well as key informant interviews with stakeholders affected by the Canadian Mining Industry. Findings suggest that MAC’s approach to sustainable development has shifted from an ambitious and holistic partnership involving a range of stakeholders to a focused, member-specific agenda that addresses a few performance issues. The transition to TSM was based on lessons learned through working with the WMI and subsequent efforts. It reflects broader corporate tendencies to address social and ecological issues through corporate social responsibility initiatives. The implications of these trends suggest that voluntary initiatives in and of themselves should not be expected to replace the comprehensive regulatory responsibilities historically provided by government.     

Cadmium adsorption on vermiculite, zeolite and pumice: batch experimental studies

Batch experiments were performed to evaluate the combined effects of ionic activity, pH, and contact time on the cadmium sorption in three different minerals, vermiculite, zeolite, and pumice, commonly employed as substrata in nurseries and recently considered for their potential use in remediation methods. The extent of cadmium sorption was vermiculite>zeolite>pumice, as shown by the Langmuir and Freundlich parameters, and it was highly dependent on mineral characteristics. The percentage of cadmium sorption in zeolite and vermiculite did not depend on cadmium concentration, while in pumice this percentage was positively correlated to the initial cadmium concentration. At low cadmium concentrations (30-120 microM), the metal sorbed on zeolite was mainly present in the nonexchangeable form (70%) at levels much higher than those found for vermiculite and pumice. The primary variable responsible for determination of cadmium mobility in these minerals was confirmed to be pH. The ionic concentrations of Hoagland nutrient solution were significantly modified by both pH and mineral composition, while the presence of cadmium caused no changes. With vermiculite and zeolite, the time-course of cadmium sorption was related to mineral composition to a greater extent than to cadmium concentration. While with pumice, the percentage of cadmium sorbed after 6 weeks was lower than with the other two minerals, and it was inversely correlated to the initial cadmium concentration.     

Challenges to the implementation of a sustainable development certification programme for the minerals and metals industry

Private, voluntary eco-labelling and certification programmes are being developed for a number of industries to promote and verify higher environmental, economic and social standards. In some cases, these initiatives have developed regardless of whether there is initial, broad support within industry. This article seeks to identify some of the challenges inherent in the implementation of a sustainable development certification programme for the minerals and metals industry. The article looks for guidance from initiatives that are drawn for the most part from other resource industries, most notably forestry. While the article takes a Canadian perspective, many of the challenges raised in the article are also applicable internationally. The article concludes that stakeholders can learn from other resource industries if a decision is made to develop a certification programme for the minerals and metals industry. Crucial to the long-term success of such a programme will be the establishment of a true partnership among stakeholders throughout the initiative's development. Crown Copyright.     

The steel industry, abiotic resource depletion and life cycle assessment: a real or perceived issue?

Time and again, there has been a hue and a cry that the world is running out of natural resources and the most prominent among those is the famous study entitled ‘The Limits to Growth’ by the ‘Club of Rome’. Since then the fear of scarcity of abiotic resources has been challenging human societies around the globe, particularly the research community. In this paper we will examine the case of the steel industry to argue how and why mineral resources depletion is an issue that needs to be addressed through life cycle assessment in more detail. This paper shows that a more comprehensive understanding about the current production trends of iron ore and steel, which also requires several vital metals such as copper, manganese, nickel and so on, can provide useful insights in assessing the potential future threat of shortages due to depletion of abiotic mineral resources.     

Adsorption of nutrients and cadmium by different minerals: experimental studies and modelling

This work analyses cadmium sorption by natural vermiculite, zeolite, and pumice, which have been recently considered for their potential use in remediation of contaminated soils. Batch experiments were performed to investigate the interactions between the mineral surfaces and the main nutritive cations of Hoagland solution. In addition to their ameliorative effect of reducing metal mobility, these minerals are able to interact to different extents with various components of the nutrient solution and can change the availability of essential nutrients in solution. Therefore, the minerals were also exposed to a range of cadmium doses to compare their different affinities for this element and to analyse the cadmium–nutrient interactions. The results showed that the nutrient solution composition was significantly modified by contact with zeolite and vermiculite, and to a minor extent with pumice. The ionic equilibrium between the solid and aqueous phases was attained at several time points depending on the cation. Ammonium and potassium ions were almost entirely absorbed by zeolite, while in vermiculite endogenous magnesium ions were exchanged with the liquid phase calcium ions. The amount of cadmium adsorbed on mineral surfaces equilibrated with the nutrient solution showed the following sequence zeolite>vermiculite>pumice, and the cation concentrations of the fluid phase were sensitive to cadmium addition.     

A relationship between the natural radioactivity and mineralogical composition of the Ponnaiyar river sediments, India

The natural radiation level has been determined for the sediment samples of Ponnaiyar River, India with an aim of evaluating the radiation hazard. The average activity concentrations are within the world and Indian average values although some extreme values have been determined. The magnetic susceptibility measurement has been carried out to know the magnetization nature of the sediments. More downstream (mouth) of the river has quite higher magnetic susceptibility values. The mineralogical characterizations of the sediments have been carried out using Fourier Transform Infrared (FTIR) spectroscopic and XRD technique. The minerals such as quartz, microcline feldspar, orthoclase feldspar, kaolinite, calcite, gibbsite, montmorillonite, smectite, palygorskite and organic carbon are identified from FTIR analysis. Few minerals like zircon, monazite and hornblende are identified only in XRD analysis. The relative distribution of major minerals is determined by calculating extinction coefficient. The calculated values show that the amount of quartz is greater than microcline feldspar and very much greater than kaolinite in all the sites. The content of quartz and microcline feldspar is decreases, and kaolinite gradually increases towards the river mouth. Multivariate Statistical analyses were carried out between the parameters obtained from radioactivity analysis and other analyses to know the existing relations. Obtained results are discussed and suggested that the natural radioactivity level of the present sediments is mainly controlled by clay content and lesser extent to magnetic susceptibility.